Polyamide multifilament fiber and tire cord including said fiber

Patent metadata

Field	Value
Publication number	US-2016339746-A1
Application number	US-201515108067-A
Country	US
Kind code	A1
Filing date	Jan 6, 2015
Priority date	Jan 8, 2014
Publication date	Nov 24, 2016
Grant date	—

Abstract

Provided are: a polyamide multifilament fiber comprising a polycondensate of a diamine and a dicarboxylic acid including an alicyclic dicarboxylic acid, and fulfilling conditions (a), (b), and (c); a cord including the fiber; a fabric comprising said cord; and a tire applying said fabric to the cap ply thereof, (a): the ratio of alicyclic dicarboxylic acid to dicarboxylic acid being at least 50 mol %. (b): the total fineness of the polyamide multifilament fiber being at least 100 dtex. (c): the cross ratio (maximum diameter/minimum diameter) of the polyamide multifilament fiber being no more than 1.7 ). This polyamide multifilament fiber is high-Tg and high strength and has excellent spinning strength and fiber uniformity. The tire cord using same has excellent rubber adhesion properties and is capable of applying good dimensional stability to the tire at high temperatures.

First claim

1 . A polyamide multifilament yarn comprising a polycondensate of a dicarboxylic acid component having an alicyclic dicarboxylic acid, and a diamine, which satisfies the following requirements:
(a) the ratio of the alicyclic dicarboxylic acid to the entire dicarboxylic acid component is 50 mol % or more; (b) the total fineness of the polyamide multifilament yarn is 100 dtex or more; and, (c) the cross ratio (maximum diameter/minimum diameter) of the polyamide multifilament yarn is 1.7 or less.

2 . The polyamide multifilament yarn according to claim 1 , wherein the sulfuric acid relative viscosity of the polyamide multifilament yarn is 1.5 to 4.0.

3 . The polyamide multifilament yarn according to claim 1 or 2 , which, contains 1,10-decanediamine for the diamine component, and wherein the ratio of the 1,10-decanediamine to the entire diamine component is 20 mol % or more.

4 . The polyamide multifilament yarn according to any of claims 1 to 3 , which contains a diamine having 5 or 6 carbon atoms for the diamine component, and wherein the ratio of the diamine having 5 or 6 carbon atoms to the entire diamine component is 20 mol % or more.

5 . The polyamide multifilament yarn according to claim 4 , wherein the diamine having 5 or 6 carbon atoms is 2-methylpentamethylenediamine.

6 . The polyamide multifilament yarn according to claim 4 , wherein the diamine having 5 or 6 carbon atoms is hexamethylenediamine.

7 . The polyamide multifilament yarn according to any of claims 1 to 6 , wherein the glass transition temperature (Tg) thereof is 90° C. to 190° C.

8 . The polyamide multifilament yarn according to any of claims 1 to 7 , wherein the melting point (Tm) thereof is 270° C. to 350° C.

9 . The polyamide multifilament yarn according to any of claims 1 to 8 , wherein U % is 3.0 or less.

10 . The polyamide multifilament yarn according to any of claims 1 to 9 , wherein Δn is 0.04 or more.

11 . The polyamide multifilament fiber according to any of claims 1 to 10 , wherein the number of filaments is 30 filaments of more.

12 . The polyamide multifilament yarn according to any of claims 1 to 11 , wherein filament fineness thereof is 7.0 dtex or less.

13 . The polyamide multifilament yarn according to any of claims 1 to 12 , wherein the fiber strength thereof is 4 cN/dtex or more.

14 . The polyamide multifilament yarn according to any of claims 1 to 13 , which contains 1,4-cyclohexanedicarboxylic acid for the aliphatic dicarboxylic acid, and wherein the ratio of the trans isomer derived from the 1,4-cyclohexanedicarboxylic acid is 50% to 100%.

15 . The polyamide multifilament yarn according to any of claims 1 to 14 , wherein the value of the ratio of the storage elastic modulus at 120° C. (E′(120° C.)) to the storage elastic modulus at 25° C. (E′(25° C.)) (E′(120° C.)/E′(25° C.)) is 0.6 to 0.9.

16 . The polyamide multifilament yarn according to any of claims 1 to 15 , wherein the peak temperature of the loss tangent (tan δ) is 150° C. to 200° C.

17 . The polyamide multifilament yarn according to any of claims 1 to 16 , which is treated with, a resorcin-formalin-latex resin.

18 . A tire cord comprising the polyamide multifilament yarn according to any of claims 1 to 17 .

19 . A twisted cord composed of the polyamide multifilament yarn according to any of claims 1 to 16 .

20 . The twisted cord according to claim 19 , which is treated with a resorcin-formalin-latex resin.

21 . A twisted cord composed of the polyamide multifilament yarn according to claim 17 .

22 . A cord fabric composed of the polyamide multifilament yarn according to any of claims 1 to 16 or the twisted cord according to claim 19 .

23 . The cord fabric according to claim 22 , which is treated with a resorcin-formalin-latex resin.

24 . A cord fabric composed of the polyamide multifilament yarn according to claim 17 or the cord according to claim 20 or 21 .

25 . A tire comprising the polyamide multifilament yarn according to any of claims 1 to 17 , the cord according to any of claims 18 to 21 , or the cord fabric according to any of claims 22 to 24 .

26 . The tire according to claim 25 , wherein the polyamide multifilament yarn according to any of claims 1 to 17 , the cord according to any of claims 18 to 21 , or the cord fabric according to any of claims 22 to 24 is applied to a cap ply.

Assignees

• Asahi Chemical Ind

Inventors

• Sato Yusuke
• Nayuki Ryo

Classifications

• D02G3/48

  Tyre cords {(tyre reinforcements B60C9/00; metal cords for reinforcing rubber or plastic articles D07B1/0606)} · CPC title

• D01F6/60

  from polyamides (from polyamino acids or polypeptides D01F6/68) · CPC title

• C08G69/265

  from at least two different diamines or at least two different dicarboxylic acids · CPC title

• B60C2009/0078

  Modulus · CPC title

• B60C2009/0092

  Twist structure · CPC title