Cured product

Patent metadata

Field	Value
Publication number	US-2016336248-A1
Application number	US-201515112387-A
Country	US
Kind code	A1
Filing date	Jan 28, 2015
Priority date	Jan 28, 2014
Publication date	Nov 17, 2016
Grant date	—

Abstract

The present application relates to a cured product and the use thereof. When the cured product, for example, is applied to a semiconductor device such as an LED or the like, the decrease in brightness may be minimized even upon the long-term use of the device, and since the cured product has excellent cracking resistance, the device having high long-term reliability may be provided. The cured product has excellent processability, workability, and adhesive properties or the like, and does not cause whitening and surface stickiness, etc. Further, the cured product exhibits excellent heat resistance at high temperature, gas barrier properties, etc. The cured product may be, for example, applied as an encapsulant or an adhesive material of a semiconductor device.

First claim

What is claimed is:

1 . A cured product, which is a reaction product of a mixture comprising an aliphatic unsaturated bond functional polyorganosiloxane and a compound having hydrogen atoms bound to silicon atoms, and which comprises an epoxy group bound to silicon atoms, wherein a ratio (E/Si) of the number of moles of the epoxy group (E) to the total number of moles of silicon atoms (Si) is in a range of 0.001 to 0.15.

2 . The cured product of claim 1 , wherein the ratio of (E/Si) the number of moles (E) of the epoxy group to the total number of moles of silicon atoms (Si) is in a range of 0.001 to 0.1.

3 . The cured product of claim 1 , wherein the ratio of (E/Si) the number of moles (E) of the epoxy group to the total number of moles of silicon atoms (Si) is in a range of 0.001 to 0.05.

4 . The cured product of claim 1 , comprising an unit of the following Formula 1, wherein a ratio (C/Si) of the number of moles of carbon atoms (C) which are present in A of the following Formula 1 to the total number of moles of silicon atoms (Si) is in a range of 0.15 to 0.55:
(R 2 SiO 1/2 A 1/2 )  [Formula 1]
where, in Formula 1, each R is independently hydrogen, an epoxy group, an alkoxy group, or a monovalent hydrocarbon group, and A is an alkylene group having 1 to 4 carbon atoms.

5 . The cured product of claim 4 , wherein the ratio (C/Si) of the number of moles of carbon atoms (C) which are present in A of Formula 1 to the total number of moles of silicon atoms (Si) is in a range of 0.15 to 0.5.

6 . The cured product of claim 4 , wherein the ratio (C/Si) of the number of moles of carbon atoms (C) which are present in A of Formula 1 to the total number of moles of silicon atoms (Si) is in a range of 0.15 to 0.45.

7 . The cured product of claim 1 , comprising an aryl group bound to the silicon atoms, wherein a ratio (Ar/Si) of the number of moles of the aryl group (Ar) to the total number of moles of silicon atoms (Si) is in a range of 0.2 to 1.2.

8 . The cured product of claim 1 , comprising a trifunctional siloxane unit bound to an aryl group, wherein a ratio (T/Si) of the number of moles of the trifunctional siloxane unit (T) to the total number of moles of silicon atoms (Si) is in a range of 0.3 to 0.6.

9 . The cured product of claim 1 , comprising a difunctional siloxane unit, wherein a ratio (D/Si) of the number of moles of the difunctional siloxane unit (D) to the total number of moles of silicon atoms (Si) is 0.6 or less.

10 . The cured product of claim 1 , comprising a siloxane unit of the following Formula 3:
(R 1 R 2 2 SiO 1/2 )  [Formula 3]
where, in Formula 3, R 1 is an alkenyl group, and R 2 is a monovalent hydrocarbon group.

11 . The cured product of claim 10 , wherein a ratio (V/Si) of the number of moles of the siloxane unit (V) of Formula 3 to the total number of moles of total silicon atoms (Si) is 0.1 or less.

12 . The cured product of claim 1 , wherein the aliphatic unsaturated bond functional polyorganosiloxane shows an average unit of the following Formula 4:
P a Q b SiO (4-a-b)/2   [Formula 4]
where, in Formula 4, P is an alkenyl group, Q is an epoxy group, an alkoxy group, or a monovalent hydrocarbon group, a and b are numbers such that a+b is in a range of 1 to 2.2, and a/(a+b) is in a range of 0.001 to 0.15.

13 . The cured product of claim 1 , wherein the compound having the hydrogen atoms bound to the silicon atoms shows an average unit of the following Formula 5:
H c Q d SiO (4-c-d)/2   [Formula 5]
where, in Formula 5, Q is an epoxy group, an alkoxy group, or a monovalent hydrocarbon group, c and d are numbers such that c+d is in a range of 1 to 2.8, and c/(c+d) is in a range of 0.001 to 0.34.

14 . The cured product of claim 1 , wherein the compound having the hydrogen atoms bound to the silicon atoms is a compound of the following Formula 6:

where, in Formula 6, each R is independently hydrogen, an epoxy group, or a monovalent hydrocarbon group, at least one R is an aryl group, n is a number in a range of 1 to 2.

15 . The cured product of claim 1 , wherein a ratio (H/Ak) of the number of moles (Ak) of an aliphatic unsaturated bond of the aliphatic unsaturated bond functional polyorganosiloxane to the number of moles of the hydrogen atoms of the compound having the hydrogen atoms bound to the silicon atoms (H) is in a range of 1.05 to 1.3 in a mixture.

16 . A semiconductor device encapsulated by an encapsulant comprising the cured product of claim 1 .

17 . An optical semiconductor device encapsulated by an encapsulant comprising the cured product of claim 1 .

18 . A liquid crystal display device comprising the optical semiconductor device of claim 17 .

19 . A lighting device comprising the optical semiconductor device of claim 17 .

Assignees

• Lg Chemical Ltd

Inventors

• Ko Min Jin
• Kim Kyung Mi
• Jung Jae Ho
• Choi Bum Gyu
• Kim Min Kyoun

Classifications

• H10W74/476 Primary

  Organic materials comprising silicon · CPC title

• C08G77/38

  Polysiloxanes modified by chemical after-treatment · CPC title

• C08K5/5435

  containing oxygen in a ring · CPC title

• C08K2201/008

  Additives improving gas barrier properties · CPC title

• C08L83/04

  Polysiloxanes · CPC title