Fluorine-based surface treating agent for vapor deposition and article finished with the surface treating agent by vapor deposition
US-9340705-B2 · May 17, 2016 · US
US2016333221A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016333221-A1 |
| Application number | US-201415103740-A |
| Country | US |
| Kind code | A1 |
| Filing date | Dec 11, 2014 |
| Priority date | Dec 13, 2013 |
| Publication date | Nov 17, 2016 |
| Grant date | — |
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The invention relates to a process that enables the creation of nanometric structures by self-assembly of block copolymers, at least one of the blocks of which is crystallizable or has at least one liquid crystal phase.
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1 . A nanostructured assembly process using a composition comprising a block copolymer, at least one of the blocks of which is crystallizable or has at least one liquid crystal phase, wherein the process comprises the following steps: dissolving the block copolymer in a solvent to form a solution, depositing the solution on a surface, annealing. 2 . The process as claimed in claim 1 , wherein the block copolymer is a diblock copolymer. 3 . The process as claimed in claim 1 , wherein the block copolymer has a crystallizable block. 4 . The process as claimed in claim 1 , wherein at least one of the blocks has a liquid crystal phase and the block which has a liquid crystal phase is lyotropic. 5 . The process as claimed in claim 1 , wherein at least one of the blocks has a liquid crystal phase and the block which has a liquid crystal phase is thermotropic. 6 . The process as claimed in claim 1 , wherein orientation of the block copolymer is carried out during a time of between 1 and 20 minutes, limits included. 7 . The process as claimed in claim 1 , wherein orientation of the block copolymer is carried out at a temperature of between 333 K and 603 K. 8 . The process as claimed in claim 1 , wherein orientation of the block copolymer is carried out under a controlled atmosphere comprising solvent vapors, or a solvent atmosphere/temperature combination. 9 . The use of the process as claimed in claim 1 in the field of surface nanostructuring for electronics. 10 . A mask of block copolymers obtained using the process as claimed in claim 1 .
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