Aqueous composite particle dispersion

Patent metadata

Field	Value
Publication number	US-2016333189-A1
Application number	US-201515110655-A
Country	US
Kind code	A1
Filing date	Jan 9, 2015
Priority date	Jan 10, 2014
Publication date	Nov 17, 2016
Grant date	—

Abstract

Disclosed is an aqueous dispersion of composite particles comprising an aqueous medium including water and the composite particles dispersed in the aqueous medium. The composite particle has a particle (A) and a polymer layer (B) with which at least a part of a surface of the particle (A) is encapsulated. The particle (A) is at least any one particle of an inorganic solid particle, or a silica-encapsulated particle having a core particle and a silica layer with which at least a part of the surface of the core particle is encapsulated. The zeta potential of the composite particles in the aqueous dispersion of composite particles at 60° C. is −70 mV to −160 mV at any pH in the range from 7 to 11.

First claim

1 . An aqueous dispersion of composite particles comprising:
an aqueous medium including water; and composite particles dispersed in the aqueous medium, wherein the composite particles has a particle (A), and a polymer layer (B) encapsulating at least a part of a surface of the particle (A); the particle (A) is at least any one particle of an inorganic solid particle, or a silica-encapsulated particle having a core particle and a silica layer encapsulating at least a part of a surface of the core particle; and a zeta potential of the composite particles in the aqueous dispersion of composite particles at 60° C. is −70 mV to −160 mV at any pH in the range from 7 to 11.

2 . The aqueous dispersion of composite particles according to claim 1 , wherein
the polymer layer (B) includes a polymer having an ionic monomer unit derived from an ionic ethylenically unsaturated monomer, and a content of the ionic monomer unit is 0.01 to 2.5% by mass based on a mass of the polymer.

3 . The aqueous dispersion of composite particles according to claim 2 ,
wherein the polymer in the polymer layer (B) further has a non-ionic monomer unit derived from a non-ionic ethylenically unsaturated monomer.

4 . The aqueous dispersion of composite particles according to claim 1 ,
wherein a zeta potential of the composite particle in the aqueous dispersion of composite particles at 25° C. after being dialyzed is −60 mV to −150 mV at any pH in the range from 7 to 11.

5 . The aqueous dispersion of composite particles according to claim 1 ,
wherein a mass ratio of the polymer layer (B)/the particle (A) is 0.01 to 10.

6 . The aqueous dispersion of composite particles according to claim 1 ,
wherein the zeta potential of the composite particles in the aqueous dispersion of composite particles at 60° C. is a value measured with respect to a dispersion for measurement obtained by diluting the aqueous dispersion of composite particles having a pH of 7 to 11 with an aqueous KCl solution; and when the pH of the aqueous dispersion of composite particles is less than 7, the dispersion for measurement is prepared by adding an aqueous NaOH solution to thereby adjust the pH within the range from 7 to 11 and thereafter diluting the aqueous dispersion of composite particles with an aqueous KCl solution.

7 . The aqueous dispersion of composite particles according to claim 4 , wherein
the zeta potential of the composite particles in the aqueous dispersion of composite particles at 25° C. after dialysis is a value measured with respect to a dispersion for measurement obtained by dialyzing the aqueous dispersion of composite particles diluted with an aqueous 1 mM NaOH solution and diluting the aqueous dispersion of composite particles having a pH of 7 to 11 after being dialyzed with an aqueous KCl solution; and when the pH of the aqueous dispersion of composite particles after being dialyzed is less than 7, the dispersion for measurement is prepared by adding an aqueous NaOH solution to thereby adjust the pH within the range from 7 to 11 and thereafter diluting the aqueous dispersion of composite particles with an aqueous KCl solution.

8 . The aqueous dispersion of composite particles according to claim 1 , further comprising two or more surfactants including a surfactant (a) and a surfactant (b).

9 . The aqueous dispersion of composite particles according to claim 8 ,
wherein the surfactant (a) includes a multi-chain hydrophilic group type compound having two or more hydrophobic groups and at least one hydrophilic group.

10 . The aqueous dispersion of composite particles according to claim 8 ,
wherein the surfactant (b) includes at least one compound selected from the group consisting of an alkylsulfonate salt, an alkenylsulfonate salt, an alkylarylsulfonate salt, an alkenylarylsulfonate salt, an isethionate salt type alkyl fatty acid ester, an isethionate salt type alkenyl fatty acid ester, an alkyl diphenyl ether disulfonate salt, an alkyl sulfate salt, an alkenyl sulfate salt, an alkylaryl sulfate salt and an ethoxylated alkylphenol sulfate salt.

11 . A method of producing the aqueous dispersion of composite particle according to claim 2 , comprising:
a step of polymerizing a monomer including the ionic ethylenically unsaturated monomer in a dispersion including water, the particle (A) and a surfactant, to thereby form the polymer layer (B) encapsulating at least a part of a surface of the particle (A).

12 . The method according to claim 11 , wherein
the surfactant includes a surfactant (a) and a surfactant (b); and the step of forming the polymer layer (B) includes: preparing a dispersion including water, the particle (A) and the surfactant (a); and polymerizing the monomer after simultaneous or separate addition of the monomer and the surfactant (b) to the dispersion prepared, or with addition of the monomer and the surfactant (b) to the dispersion prepared.

13 . The method according to claim 12 ,
wherein the surfactant (a) includes a multi-chain hydrophilic group type compound having two or more hydrophobic groups and at least one hydrophilic group.

14 . The method according to claim 12 ,
wherein the surfactant (b) includes at least one compound selected from the group consisting of an alkylsulfonate salt, an alkenylsulfonate salt, an alkylarylsulfonate salt, an alkenylarylsulfonate salt, an isethionate salt type alkyl fatty acid ester, an isethionate salt type alkenyl fatty acid ester, an alkyl diphenyl ether disulfonate salt, an alkyl sulfate salt, an alkenyl sulfate salt, an alkylaryl sulfate salt and an ethoxylated alkylphenol sulfate salt.

15 . The method according to claim 12 ,
wherein a content of the surfactant (a) in the dispersion is 0.05 to 25% by mass based on a total amount of 100% by mass of the monomer, and an amount of the surfactant (b) to be added to the dispersion is 0.01 to 10% by mass based on a total amount of 100% by mass of the monomer.

16 . The method according to claim 11 ,
wherein the dispersion further includes a water-soluble initiator, the monomer is polymerized by emulsion polymerization, and a content of the water-soluble initiator in the dispersion is 0.01 to 1.0% by mass based on a total amount of 100% by mass of the monomer.

17 . The method according to claim 11 ,
wherein the dispersion further includes an oil-soluble initiator, the monomer is polymerized by emulsion polymerization or miniemulsion polymerization, and a content of the oil-soluble initiator in the dispersion is 0.01 to 0.1% by mass based on a total amount of 100% by mass of the monomer.

18 . The method according to claim 11 ,
wherein, while a mass ratio of the polymer layer (B)/the particle (A) is in the range from 0.01 to 0.5 in a process of polymerizing the monomer, the zeta potential of the composite particles in the dispersion at 60° C. is −70 mV to −160 mV at any pH in the range from 7 to 11.

19 . The method according to claim 11 ,
wherein, while a mass ratio of the polymer layer (B)/the particle (A) is in the range from 0.01 to 0.5 in a process of polymerizing the monomer, the polymer layer (B) includes 0.01 to 2.5% by mass of an ionic monomer unit derived from the ionic ethylenically unsaturated monomer based on a mass of 100% by mass of the polymer in the polymer layer (B).

Assignees

• Asahi Chemical Ind

Inventors

• Yamauchi Toyoaki
• Sasaki Megumi

Classifications

• C08F292/00

  Macromolecular compounds obtained by polymerising monomers on to inorganic materials · CPC title

• C09D5/022 Primary

  Emulsions, e.g. oil in water · CPC title

• C08F2/24

  with the aid of emulsifying agents · CPC title

• C09D133/12

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C09D7/62

  modified by treatment with other compounds · CPC title