Process for the preparation of perfluoroalkylcyano- or perfluoroalkylcyanofluoroborates
US-9175021-B2 · Nov 3, 2015 · US
US2016333138A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016333138-A1 |
| Application number | US-201515111937-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jan 22, 2015 |
| Priority date | Feb 6, 2014 |
| Publication date | Nov 17, 2016 |
| Grant date | — |
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An epoxy resin composition excellent in storage stability and curability is provided. Particularly, a compound of general formula (I) and an epoxy resin composition containing the compound as a curing agent are provided. In formula (I), R1 is a hydrocarbon group optionally containing a nitrogen atom and capable of forming a cyclic structure optionally having a substituent; R2 is a hydrogen atom, an alkyl group, or an aryl group or is taken together with R1 to form an unsaturated bond; R3 is a hydrogen atom, an alkyl group, or an aryl group; and X is a dicyanamide ion or a thiocyanate ion.
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1 . A compound represented by general formula (I): wherein R1 represents a hydrocarbon group optionally containing a nitrogen atom and capable of forming a cyclic structure optionally having a substituent; R2 represents a hydrogen atom, an alkyl group, or an aryl group or is taken together with R1 to form an unsaturated bond; R3 represents a hydrogen atom, an alkyl group, or an aryl group; and X represents a dicyanamide ion or a thiocyanate ion. 2 . The compound of claim 1 , being represented by any one of general formulae (I-1) through (I-5): wherein R2′, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, and R15 each independently represent a hydrogen atom, an alkyl group, or an aryl group; and X represents a dicyanamide ion or a thiocyanate ion. 3 . An epoxy resin composition comprising (A) an epoxy resin and (B) a compound represented by general formula (I): wherein R1 represents a hydrocarbon group optionally containing a nitrogen atom and capable of forming a cyclic structure optionally having a substituent; R2 represents a hydrogen atom, an alkyl group, or an aryl group or is taken together with R1 to form an unsaturated bond; R3 represents a hydrogen atom, an alkyl group, or an aryl group; and X represents a dicyanamide ion or a thiocyanate ion. 4 . The epoxy resin composition of claim 3 , wherein the compound (B) comprises at least one of compounds represented by general formulae (I-1) through (I-5): wherein R2′, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, and R15 each independently represent a hydrogen atom, an alkyl group, or an aryl group; and X represents a dicyanamide ion or a thiocyanate ion. 5 . The epoxy resin composition of claim 3 , being a one-pack type thermosetting epoxy resin composition. 6 . The epoxy resin composition of claim 4 , being a one-pack type thermosetting epoxy resin composition.
with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring nitrogen atoms · CPC title
having two nitrogen atoms in the ring · CPC title
having one double bond between ring members or between a ring member and a non-ring member · CPC title
Radicals containing only hydrogen and carbon atoms · CPC title
with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2 · CPC title
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