Filtration module

Patent metadata

Field	Value
Publication number	US-2016326022-A1
Application number	US-201615214649-A
Country	US
Kind code	A1
Filing date	Jul 20, 2016
Priority date	Feb 21, 2012
Publication date	Nov 10, 2016
Grant date	—

Abstract

The present invention provides a filtration module having at least one membrane layer and a spacer layer, wherein the spacer includes: a polymeric matrix; and a biocide physically embedded into or attached to the polymeric matrix. Moreover, the invention provides a method for reducing the concentration of bacteria in water, by contacting water with the filtration module.

First claim

What is claimed is:

1 . A filtration module comprising two membrane layers and a spacer layer, said spacer layer is sandwiched between said two membrane layers, wherein said spacer layer is in direct contact with said two membrane layers, wherein said spacer layer comprises (i) a polymer; and (ii) a biocide deposited on at least one upper layer surface of said polymer, wherein:
(a) said two membrane layers are devoid of said biocide, and (b) at least 50% of an area of said upper layer surface of the polymer is covered by said biocide.

2 . The filtration module of claim 1 , wherein at least 90% of said area of the upper layer surface of said polymer is covered by said biocide.

3 . The filtration module of claim 1 , wherein said biocide is at concentration that ranges from about 4% to about 30%, by total weight of said spacer layer.

4 . The filtration module of claim 1 , wherein said biocide is a metal or a metal oxide.

5 . The filtration module of claim 4 , wherein said metal or said metal oxide are in the form of nanosized particles.

6 . The filtration module of claim 4 , wherein said metal is silver.

7 . The filtration module of claim 4 , wherein said metal oxide is zinc oxide (ZnO).

8 . The filtration module of claim 1 , wherein said biocide is physically deposited on said at least one upper layer surface of said spacer.

9 . The filtration module of claim 1 , wherein said biocide comprises a quaternary ammonium salt.

10 . The filtration module of claim 1 , wherein said biocide comprises a quaternary ammonium salt and a metal or a metal oxide.

11 . The filtration module of claim 1 , having a tubular shape.

12 . The filtration module of claim 1 , wherein an outer circumference of said filtration module consists of a membrane layer.

13 . The filtration module of claim 1 , wherein said filtration module is adapted for filtering water.

14 . The filtration module of claim 1 , wherein said polymer comprises polypropylene.

15 . The filtration module of claim 1 , wherein said polymer comprises polymethyl methacrylate (PMMA).

16 . The filtration module of claim 1 , wherein said two membrane layers are characterized by a pore size of 0.2 μm-500 μm.

17 . A method for reducing the concentration of bacteria in water, comprising a step of contacting said water with the filtration module of claim 1 .

18 . The method of claim 17 , wherein said filtration module comprises a tubular shape and two permeable or a semi-permeable membrane layers, wherein an outer circumference of said module consists a membrane layer.

19 . The method of claim 17 , wherein said filtration module comprises a tubular shape and a coiled bilayer, said bilayer comprises a single permeable or semi-permeable membrane layer directly contacting the spacer layer, wherein an outer circumference of said module consists of said membrane layer.

20 . The method of claim 17 , wherein said filtration module comprises a tubular shape and a coiled bilayer, said bilayer comprises a single permeable or semi-permeable membrane layer directly contacting a single spacer layer, wherein at least 90% of the area of the upper layer surface of said polymer is covered by said biocide.

Assignees

• Technion Res & Dev Foundation

Inventors

• Dosoretz Carlos
• Ronen Avner
• Semiat Raphael

Classifications

• C02F2303/20

  Prevention of biofouling · CPC title

• C02F1/44 Primary

  by dialysis, osmosis or reverse osmosis {(general membrane separation processes B01D61/00, membrane modules B01D63/00, electrodialysis C02F1/4693, combination of membrane modules and bioreactors C02F3/1268)} · CPC title

• B01D63/10

  Spiral-wound membrane modules · CPC title

• B01D2313/143

  on the feed side · CPC title

• C02F1/50

  by addition or application of a germicide or by oligodynamic treatment {(C02F1/4606, C02F1/467, C02F1/76 take precedence)} · CPC title