Soft Magnetic Composites for Electric Motors

Patent metadata

Field	Value
Publication number	US-2016307679-A1
Application number	US-201415101056-A
Country	US
Kind code	A1
Filing date	Dec 22, 2014
Priority date	Dec 26, 2013
Publication date	Oct 20, 2016
Grant date	—

Abstract

A soft magnetic composite comprising an iron or iron alloy ferromagnetic material coated with an oxide material. An interface between the ferromagnetic material and the layer of oxide contains antiphase domain boundaries. Two processes for producing a soft magnetic composite are also provided. One process includes depositing an oxide layer onto an iron or iron alloy ferromagnetic material by molecular beam epitaxy at a partial oxygen pressure of from 1×10 −5 Torr to 1×10 −7 Torr to form a coated composite. The other process includes milling an iron or iron alloy ferromagnetic material powder and an oxide powder by high-energy milling to form a mixture; compacting the mixture and curing in an inert gas atmosphere at a temperature from 500° C. to 1200° C. to form a soft magnetic composite.

First claim

1 . A soft magnetic composite comprising:
a ferromagnetic material selected from the group consisting of iron and iron alloys; and an oxide, wherein the ferromagnetic material is coated by the oxide, and an interface between the ferromagnetic material and the oxide contains antiphase domain boundaries.

2 . The soft magnetic composite of claim 1 , wherein the iron alloy is selected from the group consisting of iron-silicon alloy, iron-aluminum alloy, iron-silicon-aluminum alloy, ion-nickel alloy, iron-cobalt alloy, iron-cobalt-nickel alloy, and combinations thereof.

3 . The soft magnetic composite of claim 1 , wherein the oxide is selected from the group consisting of MgO, Fe 3 O 4 , NiFe 2 O 4 , MnFe 2 O 4 , CoFe 2 O 4 , CuFe 2 O 4 , CoZnOFe 2 O 3 , MnZnOFe 2 O 3 , and NiZnOFe 2 O 3 .

4 . The soft magnetic composite of claim 1 , wherein the layer of oxide has a thickness from about 10 nm to about 5 μm.

5 . The soft magnetic composite of claim 1 , wherein a surface of the ferromagnetic material has a layer of Fe 2 O 3 .

6 . The soft magnetic composite of claim 5 , wherein the layer of Fe 2 O 3 has a thickness in a range of from about 1 nm and about 5 nm.

7 . A process for producing a soft magnetic composite, said process comprising steps of:
depositing an oxide layer onto a ferromagnetic material core selected from the group consisting of iron and iron alloys by molecular beam epitaxy at a partial oxygen pressure of from about 1×10 −5 Torr to about 1×10 −7 Torr to form coating particles and compacting the coated particles to form a composite.

8 . The process of claim 7 , wherein the iron alloys is selected from the group consisting of iron-silicon alloy, iron-aluminum alloy, iron-silicon-aluminum alloy, ion-nickel alloy, iron-cobalt alloy, iron-cobalt-nickel alloy, or combinations thereof.

9 . The process of claim 7 , wherein the oxide is selected from the group consisting of MgO, Fe 3 O 4 , NiFe 2 O 4 , MnFe 2 O 4 , CoFe 2 O 4 , CuFe 2 O 4 , CoZnOFe 2 O 3 , MnZnOFe 2 O 3 , and NiZnOFe 2 O 3 .

10 . The process of claim 7 , wherein partial oxygen pressure is in a range of from about 5×10 −6 Torr to about 5×10 −7 Torr.

11 . The process of claim 7 , wherein the oxide layer has a thickness of from about 10 nm to about 5 μm.

12 . The process of claim 7 , further comprising the step of annealing the composite at a temperature from about 250 to about 1200° C.

13 . The process of claim 12 , wherein the annealing step is conducted for a period from about 15 minutes to about 4 hours.

14 . A soft magnetic composite produced by the process of claim 7 .

15 . A process for producing soft magnetic composite, said process comprising steps of:
milling a ferromagnetic material powder selected from iron powder and an iron ally powder and an oxide powder to form ferromagnetic particles coated with oxide; compacting the ferromagnetic particles coated with oxide to form a compact; and annealing the compact at a temperature from about 400 to about 1200° C. to form a soft magnetic composite.

16 . The process of claim 15 , wherein the ferromagnetic material powders have a particle size from about 10 to about 1000 μm.

17 . The process of claim 15 , wherein the oxide powders have a particle size from about 10 nm to about 50 μm.

18 . The process of claim 15 , wherein the ferromagnetic material powder has a particle size in a range of from about 150 μm to about 420 μm, and the oxide powder has a particle size in a range of from about 50 nm to about 100 nm.

19 . The process of claim 15 , wherein a ratio of ferromagnetic material powder particle size to oxide powder particle size is from about 5 to about 40000.

20 . The process of claim 15 , wherein the milling step includes at least one polymeric resin selected from the group consisting of thermoplastic resins, thermosetting resins, combinations thereof.

21 - 30 . (canceled)

Assignees

• Taheri Mitra Lenore
• Sunday Katie Jo
• Spurgeon Steven Richard
• May Steven Joseph
• Univ Drexel

Inventors

• Taheri Mitra Lenore
• Sunday Katie Jo
• Spurgeon Steven Richard
• May Steven Joseph

Classifications

• B22F1/16

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• B22F1/05

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F1/02

  Operations & Transport · mapped topic

• B22F2009/041

  by mechanical alloying, e.g. blending, milling · CPC title

• B22F2301/35

  Iron · CPC title