Cured product of polyphenylene ether-containing resin composition

Patent metadata

Field	Value
Publication number	US-2016289446-A1
Application number	US-201415037936-A
Country	US
Kind code	A1
Filing date	Nov 19, 2014
Priority date	Nov 20, 2013
Publication date	Oct 6, 2016
Grant date	—

Abstract

The description of the present application describes a cured product that is obtained by compression molding a resin composition that contains a polyphenylene ether (A) and a cross-linking curable compound (B). A phase separated structure that comprises a dispersed phase and a continuous phase is observed in a 10,000× morphological image that is observed from the vertical direction of a compression surface of the cured product using a transmission electron microscope. In a 200,000× morphological image that is observed from the vertical direction of the compression surface of the cured product using a transmission electron microscope, the continuous phase has a co-continuous structure that includes an A phase that has the polyphenylene ether (A) as a principal component and a B phase that has the cross-linking curable compound (B) as a principal component, the proportion of the area of the co-continuous structure occupied by the A phase being 40%-90% of the area.

First claim

1 - 16 . (canceled)

17 . A cured product obtained by compression-molding a resin composition containing a polyphenylene ether (A) and a crosslinking curable compound (B), wherein
in a morphological image at 10,000× magnification as observed from a direction vertical to a compression surface by using a transmission electron microscope, a phase separation structure consisting of a dispersed phase and a continuous phase is observed, and in a morphological image at 200,000× magnification as observed from the direction vertical to the compression surface by using the transmission electron microscope, the continuous phase has a co-continuous structure including an A phase mainly containing the polyphenylene ether (A) and a B phase mainly containing the crosslinking curable compound (B), and the area proportion of the A phase in the continuous phase is from 50 to 80 area %.

18 . The cured product according to claim 17 , wherein in the morphological image at 200,000× magnification as observed from the direction vertical to the compression surface by using the transmission electron microscope, the structural period of the co-continuous structure is from 0.5 to 50 nm.

19 . The cured product according to claim 17 , wherein in the morphological image at 200,000× magnification as observed from the direction vertical to the compression surface by using the transmission electron microscope, the area proportion of the A phase in the continuous phase is from 55 to 70 area %.

20 . The cured product according to claim 17 , wherein in the morphological image at 10,000× magnification as observed from the direction vertical to the compression surface by using the transmission electron microscope, the area proportion of the dispersed phase is from 10 to 80 area %.

21 . The cured product according to claim 17 , wherein in a morphological image at 10,000× magnification as observed from the direction vertical to the compression surface by using the transmission electron microscope, a spherical dispersed phase having a long diameter ranging from 0.001 μm to less than 1.0 μm and a long diameter/short diameter ratio of 1.0 to 3.0 exists.

22 . The cured product according to claim 21 , wherein in a morphological image at 10,000× magnification as observed from the direction vertical to the compression surface by using a transmission electron microscope, the area proportion of the spherical dispersed phase is from 10 to 80 area %.

23 . The cured product according to claim 21 , wherein in a morphological image at 10,000× magnification as observed from the direction vertical to the compression surface by using a transmission electron microscope, a string-like dispersed phase having a long diameter of 1.0 to 18 μm, a short diameter of 0.001 to 2.0 μm, and a long diameter/short diameter ratio of 2.0 to 30 exists, in addition to the spherical dispersed phase.

24 . The cured product according to claim 23 , wherein in a morphological image at 10,000× magnification as observed from the direction vertical to the compression surface by using a transmission electron microscope, the area proportion of the spherical dispersed phase and the string-like dispersed phase is from 10 to 80 area %.

25 . The cured product according to claim 23 , wherein in a morphological image at 10,000× magnification as observed from the direction vertical to the compression surface by using a transmission electron microscope, the area proportion of the string-like dispersed phase is from 50 to 90 area % relative to the total of areas of the spherical dispersed phase and the string-like dispersed phase.

26 . The cured product according to claim 23 , wherein in a morphological image at 10,000× magnification as observed from the direction vertical to the compression surface by using a transmission electron microscope, the area proportion of the string-like dispersed phase is from 70 to 90 area % relative to the total of areas of the spherical dispersed phase and the string-like dispersed phase.

27 . The cured product according to claim 17 , wherein the content of the polyphenylene ether (A) is from 20 to 60 mass % based on 100 mass % of the mass of the cured product.

28 . The cured product according to claim 17 , wherein the resin composition further contains a hydrogenated block copolymer (C) obtained by hydrogenating a vinyl aromatic compound-conjugated diene compound block copolymer and an organic peroxide (D), in addition to the polyphenylene ether (A) and the crosslinking curable compound (B),
a content of a vinyl aromatic compound unit in the hydrogenated block copolymer (C) is from 5 to 50 mass %, a content of the hydrogenated block copolymer (C) is from 3 to 20 parts by mass based on 100 parts by mass of the total mass of the polyphenylene ether (A) and the crosslinking curable compound (B), a one-minute half-life temperature of the organic peroxide (D) is from 150 to 190° C., and the content of the organic peroxide (D) is from 1 to 5 parts by mass based on 100 parts by mass of the total mass of the polyphenylene ether (A) and the crosslinking curable compound (B).

29 . The cured product according to claim 28 , wherein the composition further contains an organic peroxide (F) having a one-minute half-life temperature ranging from more than 190° C. to 250° C. and the content of the organic peroxide (F) is from 1 to 3 parts by mass based on 100 parts by mass of the total mass of the polyphenylene ether (A) and the crosslinking curable compound (B).

30 . The cured product according to claim 17 , wherein the composition further contains a P atom-containing compound (E) compatible with both of the polyphenylene ether (A) and the crosslinking curable compound (B), in addition to the polyphenylene ether (A) and the crosslinking curable compound (B),
the content of the P atom-containing compound (E) is from 0.5 to 15 parts by mass based on 100 parts by mass of the total mass of the polyphenylene ether (A) and the P atom-containing compound (E), and the total content of the crosslinking curable compound (B) and the P atom-containing compound (E) is from 30 to 45 mass % based on 100 mass % of the total mass of the polyphenylene ether (A), the crosslinking curable compound (B) and the P atom-containing compound (E).

31 . An electronic circuit substrate containing the cured product according to claim 17 , which is selected from a resin film, a composite obtained by curing a resin of a prepreg as an impregnated composite of a base material and the resin, a resin-attached metal foil, and a laminate composed of two or more thereof.

Assignees

• Asahi Chemical Ind

Inventors

• Endo Masaaki
• Otani Shoji

Classifications

• H05K1/0353

  consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement · CPC title

• H05K1/024

  Dielectric details, e.g. changing the dielectric material around a transmission line · CPC title

• C08L71/12 Primary

  Polyphenylene oxides · CPC title

• C08K5/14

  Peroxides · CPC title

• C08K5/34924

  containing cyanurate groups; Tautomers thereof · CPC title