Reinforcing fiber fabric substrate, preform, and fiber-reinforced composite material

Patent metadata

Field	Value
Publication number	US-2016289406-A1
Application number	US-201415037596-A
Country	US
Kind code	A1
Filing date	Nov 13, 2014
Priority date	Nov 29, 2013
Publication date	Oct 6, 2016
Grant date	—

Abstract

A reinforcing fiber fabric substrate has a binder containing a thermosetting resin [A] and a curing catalyst [B] at a basis weight of 0.1 g/m2-4 g/m2 on at least the surface of a reinforcing fiber fabric constructed of reinforcing fiber strands, wherein the reinforcing fiber fabric substrate has a heating temperature (T) in the 80-180° C. range, and the adhesive strength becomes 0.5 N/25 mm or higher at the heating temperature (T) between preform layers molded by laminating this reinforcing fiber fabric substrate at the heating temperature (T).

First claim

1 - 22 . (canceled)

23 . A reinforcing fiber fabric base comprising:
a reinforcing fiber fabric composed of reinforcing fiber strands; and a binder comprising a thermosetting resin [A] and a curing catalyst [B] and applied at least on the surface of the reinforcing fiber fabric at an area coating weight of 0.1 to 4 g/m 2 , wherein the reinforcing fiber fabric base has such a property that a heating temperature T at which the bond strength between layers in a preform, which is produced by laminating the reinforcing fiber fabric bases and then molding the resultant laminate at the heating temperature T, becomes 0.5 N/25 mm or more is present at 80 to 180° C.

24 . The reinforcing fiber fabric base according to claim 23 , wherein the thermosetting resin [A] contains a bifunctional epoxy resin.

25 . The reinforcing fiber fabric base according to claim 24 , wherein the bifunctional epoxy resin is a solid bifunctional epoxy resin and the thermosetting resin [A] additionally contains a polyfunctional epoxy resin.

26 . The reinforcing fiber fabric base according to claim 25 , wherein the solid bifunctional epoxy resin and the polyfunctional epoxy resin are contained in amounts of 20 to 80 parts by mass and 20 to 80 parts by mass, respectively, in 100 parts by mass of the thermosetting resin [A].

27 . The reinforcing fiber fabric base according to claim 25 , wherein the polyfunctional epoxy resin is a solid polyfunctional epoxy resin.

28 . The reinforcing fiber fabric base according to claim 24 , wherein the bifunctional epoxy resin is a bisphenol-type epoxy resin.

29 . The reinforcing fiber fabric base according to claim 25 , wherein the polyfunctional epoxy resin is a non-glycidylamine-type epoxy resin.

30 . The reinforcing fiber fabric base according to claim 23 , wherein the curing catalyst [B] is at least one curing catalyst selected from an organic phosphorous compound, imidazole or a derivative thereof the aforementioned compounds.

31 . The reinforcing fiber fabric base according to claim 23 , wherein the binder has a glass transition temperature of 40 to 80° C.

32 . The reinforcing fiber fabric base according to claim 23 , wherein the binder has a property such that, when the binder is heated at a heating temperature T of 80 to 180° C. for a heating time t of 1 to 30 minutes, a combination of the heating temperature T and the heating time t causes curing of the binder such that the binder has a lowest viscosity of 10 to 10,000 Pa·s and, subsequently, viscosity of the binder increases to 10,000,000 Pa·s or more within the time t.

33 . The reinforcing fiber fabric base according to claim 23 , wherein the bond strength obtained when the area coating weight of the binder is 1 g/m 2 is 60% or more of that obtained when the area coating weight of the binder is 4 g/m 2 .

34 . The reinforcing fiber fabric base according to claim 23 , wherein the binder is in a particulate form.

35 . The reinforcing fiber fabric base according to claim 34 , wherein the binder has an average particle diameter of 50 to 300 μm.

36 . The reinforcing fiber fabric base according to claim 34 , wherein a particle diameter distribution index of the average particle diameter of the binder is 1 to 1.8.

37 . The reinforcing fiber fabric base according to claim 23 , wherein a number n of filaments in reinforcing fiber strands that constitute the reinforcing fiber fabric and an area fiber density W[g/m 2 ] of the reinforcing fiber fabric satisfies Formula (1):
0 ≦W− 0.011 n≦ 160   (1).

38 . The reinforcing fiber fabric base according to claim 23 , wherein a number n of filaments in the reinforcing fiber strands that constitute the reinforcing fiber fabric and an area fiber density W[g/m 2 ] of the reinforcing fiber fabric satisfies Formula (2):
0 ≦W− 0.011 n≦ 140   (2).

39 . The reinforcing fiber fabric base according to claim 23 , wherein the reinforcing fiber strands are carbon fiber strands.

40 . A resin composition used as a binder in a reinforcing fiber fabric base as recited in claim 23 .

41 . A preform produced by laminating multiple pieces of reinforcing fiber fabric bases as recited in claim 23 and then setting the shape of the resultant laminate.

42 . A method of producing a preform comprising:
laminating multiple pieces of reinforcing fiber fabric bases each of which comprises a reinforcing fiber fabric composed of reinforcing fiber strands and a binder comprising a thermosetting resin [A] and a curing catalyst [B] and applied at least on the surface of the reinforcing fiber fabric at an area coating weight of 0.1 to 4 g/m 2 ; and heating the resultant laminate at a heating temperature T of 80 to 180° C. for a heating time t of 1 to 30 minutes to cure the binder such that the binder has a lowest viscosity of 10 to 10,000 Pa·s and, subsequently, viscosity of the binder increases to 10,000,000 Pa·s or more within the time t, thereby producing the preform.

43 . A fiber-reinforced composite material produced by impregnating a preform as recited in claim 41 with a liquid thermosetting resin and then curing the resultant product.

Assignees

• Toray Industries

Inventors

• Hirano Masanori
• Tomioka Nobuyuki
• Honda Shiro

Classifications

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• C08J2363/02

  Polyglycidyl ethers of bis-phenols · CPC title

• D06M15/55

  Epoxy resins · CPC title

• C08J2363/04

  Epoxynovolacs · CPC title

• C08J2463/04

  Epoxynovolacs · CPC title