Artificial-photosynthesis array

Patent metadata

Field	Value
Publication number	US-2016281244-A1
Application number	US-201615178641-A
Country	US
Kind code	A1
Filing date	Jun 10, 2016
Priority date	Dec 13, 2013
Publication date	Sep 29, 2016
Grant date	—

Abstract

Provided is an artificial-photosynthesis array configured of artificial-photosynthesis modules which have been arranged in one or more rows and which receive light and decompose a supplied aqueous electrolyte solution to thereby obtain hydrogen gas and oxygen gas. The artificial-photosynthesis modules each includes an electrolytic chamber for hydrogen where hydrogen gas is generated and an electrolytic chamber for oxygen where oxygen gas is generated, the chambers being isolated from each other. The electrolytic chambers for hydrogen and electrolytic chambers for oxygen of the artificial-photosynthesis modules are alternately connected so that the electrolytic chamber for hydrogen of each artificial-photosynthesis module is connected to the electrolytic chamber for oxygen of another module and the electrolytic chamber for oxygen of each artificial-photosynthesis module is connected to the electrolytic chamber for hydrogen of another module.

First claim

What is claimed is:

1 . An artificial-photosynthesis array comprising:
a hydrogen gas generating part that generates hydrogen gas from an aqueous electrolyte solution; an oxygen gas generating part that generates oxygen gas from the aqueous electrolyte solution; a photoelectric conversion unit for supplying electrical energy from light and supplying electrical energy for generating the hydrogen gas in the hydrogen gas generating part and electrical energy for generating the oxygen gas in the oxygen gas generating part, the hydrogen gas generating part, the oxygen gas generating part, the photoelectric conversion unit being provided on a plane and being electrically connected together; an electrolytic chamber for hydrogen that contains the hydrogen gas generating part, the supplied aqueous electrolyte solution, and the generated hydrogen gas; and an electrolytic chamber for oxygen that contains the oxygen gas generating part, the supplied aqueous electrolyte solution, and the generated oxygen gas, wherein the electrolytic chamber for hydrogen and the electrolytic chamber for oxygen include a plurality of artificial-photosynthesis modules that are isolated from each other so that the generated hydrogen gas and the generated oxygen gas do not mix with each other, wherein the electrolytic chamber for hydrogen is connected to the electrolytic chamber for oxygen of another artificial-photosynthesis module adjacent thereto, and the electrolytic chamber for oxygen is connected to the electrolytic chamber for hydrogen of another artificial-photosynthesis module adjacent thereto, wherein the artificial-photosynthesis module is inclined in a direction in which the hydrogen gas generating part and the oxygen gas generating part of another artificial-photosynthesis module are lined up, and wherein the aqueous electrolyte solution is supplied to the electrolytic chamber for hydrogen and the electrolytic chamber for oxygen of each of the artificial-photosynthesis modules at a predetermined flow rate.

2 . The artificial-photosynthesis array according to claim 1 ,
wherein the hydrogen gas generating part and the oxygen gas generating part are provided on the same plane.

3 . The artificial-photosynthesis array according to claim 1 ,
wherein the hydrogen gas generating part and the oxygen gas generating part are provided on mutually different planes.

4 . The artificial-photosynthesis arrays according to claim 1 ,
wherein the hydrogen gas generating part and the oxygen gas generating part are arranged to be inclined with respect to the flow of the supplied aqueous electrolyte solution.

5 . The artificial-photosynthesis arrays according to claim 2 ,
wherein the hydrogen gas generating part and the oxygen gas generating part are arranged to be inclined with respect to the flow of the supplied aqueous electrolyte solution.

6 . The artificial-photosynthesis arrays according to claim 3 ,
wherein the hydrogen gas generating part and the oxygen gas generating part are arranged to be inclined with respect to the flow of the supplied aqueous electrolyte solution.

7 . The artificial-photosynthesis arrays according to claim 1 ,
wherein a plurality of photoelectric conversion elements of the photoelectric conversion unit are connected in series.

8 . The artificial-photosynthesis arrays according to claim 2 ,
wherein a plurality of photoelectric conversion elements of the photoelectric conversion unit are connected in series.

9 . The artificial-photosynthesis arrays according to claim 3 ,
wherein a plurality of photoelectric conversion elements of the photoelectric conversion unit are connected in series.

10 . The artificial-photosynthesis array according to claim 7 ,
wherein each of the photoelectric conversion elements includes an inorganic semiconductor film having a pn junction.

11 . The artificial-photosynthesis array according to claim 10 ,
wherein the inorganic semiconductor film includes a CIGS compound semiconductor.

12 . The artificial-photosynthesis array according to claim 10 ,
wherein the inorganic semiconductor film includes a CZTS compound semiconductor.

13 . The artificial-photosynthesis array according to claim 1 ,
wherein the hydrogen gas generating part is covered with a functional layer, and the functional layer is insoluble in a weak acidic solution and a weak alkaline solution, and has all of light permeability, water impermeability, and conductivity.

14 . The artificial-photosynthesis array according to claim 2 ,
wherein the hydrogen gas generating part is covered with a functional layer, and the functional layer is insoluble in a weak acidic solution and a weak alkaline solution, and has all of light permeability, water impermeability, and conductivity.

15 . The artificial-photosynthesis array according to claim 3 ,
wherein the hydrogen gas generating part is covered with a functional layer, and the functional layer is insoluble in a weak acidic solution and a weak alkaline solution, and has all of light permeability, water impermeability, and conductivity.

16 . The artificial-photosynthesis array according to claim 4 ,
wherein the hydrogen gas generating part is covered with a functional layer, and the functional layer is insoluble in a weak acidic solution and a weak alkaline solution, and has all of light permeability, water impermeability, and conductivity.

17 . The artificial-photosynthesis array according to claim 13 ,
wherein the functional layer has a co-catalyst provided on the surface thereof, and the co-catalyst is made of Pt, a substance containing Pt, or Rh.

18 . The artificial-photosynthesis array according to claim 1 ,
wherein the photoelectric conversion unit is covered with a protective layer, and the protective layer is insoluble in a weak acidic solution and a weak alkaline solution, and has all of light permeability, water impermeability, and insulation.

19 . The artificial-photosynthesis array according to claim 2 ,
wherein the photoelectric conversion unit is covered with a protective layer, and the protective layer is insoluble in a weak acidic solution and a weak alkaline solution, and has all of light permeability, water impermeability, and insulation.

20 . The artificial-photosynthesis array according to claim 3 ,
wherein the photoelectric conversion unit is covered with a protective layer, and the protective layer is insoluble in a weak acidic solution and a weak alkaline solution, and has all of light permeability, water impermeability, and insulation.

Assignees

• Fujifilm Corp
• Japan Tech Res Ass Of Artificial Photosynthetic Chemical Process
• Univ Tokyo

Inventors

• Sato Naotoshi
• Domen Kazunari
• Tsukahara Jiro

Classifications

• H10F77/128

  comprising only Group I-II-IV-VI kesterite materials, e.g. Cu2ZnSnSe4 or Cu2ZnSnS4 · CPC title

• H10F77/126

  comprising only Group I-III-VI chalcopyrite materials, e.g. CuInSe2, CuGaSe2 or CuInGaSe2 [CIGS] · CPC title

• H10F19/00

  Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules · CPC title

• H10F10/167 Primary

  comprising Group I-III-VI materials, e.g. CdS/CuInSe2 [CIS] heterojunction photovoltaic cells · CPC title

• H01L31/0326

  Electricity · mapped topic