Self-propagating braze

Patent metadata

Field	Value
Publication number	US-2016280609-A1
Application number	US-201615045156-A
Country	US
Kind code	A1
Filing date	Feb 16, 2016
Priority date	Mar 23, 2015
Publication date	Sep 29, 2016
Grant date	—

Abstract

A method may include positioning a first ceramic or ceramic matrix composite (CMC)part and a second ceramic or CMC part adjacent to each other to define a joint between adjacent portions of the first ceramic or CMC part and the second ceramic or CMC part. The method also may include introducing a carbon-containing filler at the joint; introducing molten silicon-containing braze material at the joint; and allowing silicon metal from the molten silicon-containing braze material to react with the carbon-containing filler to form silicon carbide and join the first ceramic or CMC part and the second ceramic or CMC part at the joint. In some examples, no external heat source directly heats the joint during the reaction of the molten silicon-containing braze material with the carbon-containing filler.

First claim

What is claimed is:

1 . A method comprising:
positioning a first ceramic or ceramic matrix composite (CMC) part and a second ceramic or CMC part adjacent to each other to define a joint between adjacent portions of the first ceramic or CMC part and the second ceramic or CMC part; introducing a carbon-containing filler at the joint; introducing molten silicon-containing braze material at the joint; and allowing silicon metal from the molten silicon-containing braze material to react with carbon from the carbon-containing filler to form silicon carbide and join the first ceramic or CMC part and the second ceramic or CMC part at the joint, wherein no external heat source directly heats the joint during the reaction of the molten silicon-containing braze material with the carbon-containing filler.

2 . The method of claim 1 , further comprising:
preheating at least one of the first ceramic or CMC part or the second ceramic or CMC part to a temperature between about 900° C. and about 1,000° C. prior to introducing molten silicon-containing braze material at the joint.

3 . The method of claim 1 , wherein:
introducing molten silicon-containing braze material at the joint comprises introducing molten silicon-containing braze material through a silicon injection port to the joint; and the silicon injection port is heated to a temperature between about 1327° C. and about 1427° C.

4 . The method of claim 3 , further comprising thermally masking at least one of the first ceramic or CMC part, the second ceramic or CMC part, or the joint to reduce radiative heating of the at least one of the first ceramic or CMC part, the second ceramic or CMC part, or the joint from the silicon injection port and the silicon injection port heat source.

5 . The method of claim 1 , wherein introducing molten silicon-containing braze material at the joint comprises introducing melting silicon-containing braze material using a tungsten inert gas (TIG) welding heat source and allowing the molten silicon-containing braze material to flow into the joint.

6 . The method of claim 1 , wherein the carbon-containing filler comprises at least one of:
a carbon yielding organic binder system; a powder comprising graphite flakes; a powder comprising carbon particles; or carbon fibers.

7 . The method of claim 1 , wherein the carbon-containing filler further comprises a reinforcement phase, and wherein the reinforcement phase comprises at least one of:
silicon carbide particles; chopped silicon carbide fibers; unidirectional silicon carbide fibers; or woven silicon fibers.

8 . The method of claim 1 , further comprising:
positioning a getter adjacent to the joint on an opposite side of the joint from wherein the silicon-containing braze material is introduced, and wherein the getter comprises graphite and is porous.

9 . The method of claim 1 , wherein the reaction between the silicon metal and the carbon is exothermic and generates heat that heats the molten silicon-containing braze material.

10 . An assembly comprising:
a first ceramic or ceramic matrix composite (CMC) part; a second ceramic or CMC part adjacent to the first ceramic or CMC part, wherein the first and second ceramic or CMC parts define a joint between adjacent portions of the first ceramic or CMC part and the second ceramic or CMC part; a silicon injection port comprising an exit aperture positioned adjacent to the joint; a silicon injection port heat source positioned to heat at least one of the silicon injection port or a silicon-containing braze material disposed in the silicon injection port; and a carbon-containing filler at the joint, wherein molten silicon-containing braze material is introduced to the joint through the silicon injection port, wherein silicon metal from the molten silicon-containing braze material reacts with carbon from the carbon-containing filler to form silicon carbide and join the first ceramic or CMC part and the second ceramic or CMC part at the joint, and wherein no external heat source directly heats the joint during the reaction of the molten silicon-containing braze material with the carbon-containing filler.

11 . The assembly of claim 10 , further comprising:
at least one heat source configured and positioned to preheat at least one of the first ceramic or CMC part or the second ceramic or CMC part to a temperature between about 900° C. and about 1,000° C. prior to the molten silicon-containing braze material being introduced to the joint.

12 . The assembly of claim 10 , wherein the silicon injection port heat source is configured to heat the silicon-containing braze material disposed within the silicon injection port to a temperature between about 1327° C. and about 1427° C.

13 . The assembly of claim 10 , further comprising a thermal masking material positioned to reduce radiative heating of at least one of the first ceramic or CMC part, the second ceramic or CMC part, or the joint from the silicon injection port and the silicon injection port heat source.

14 . The assembly of claim 10 , wherein the carbon-containing, filler comprises at least one of:
a carbon yielding organic binder system; a powder comprising graphite flakes; a powder comprising carbon particles; or carbon fibers.

15 . The assembly of claim 10 , wherein the carbon-containing filler further comprises a reinforcement phase, and wherein the reinforcement phase comprises at least one of:
silicon carbide particles; chopped silicon carbide fibers; unidirectional silicon carbide fibers; or woven silicon fibers.

16 . The assembly of claim 10 , further comprising:
a getter adjacent to the joint on an opposite side of the joint from the silicon injection port, wherein the getter comprises graphite and is porous.

17 . A system comprising:
a silicon injection port comprising an exit aperture positioned adjacent to a joint, wherein the joint is defined between respective surfaces of a first ceramic or ceramic matrix composite (CIVIC) part and a second ceramic or CMC part; a silicon injection port heat source positioned to heat at least one of the silicon injection port or a silicon-containing braze material disposed in the silicon injection port to result in the silicon-containing braze material being a molten silicon-containing braze material; and at least one heat source configured and positioned to preheat at least one of the first ceramic or CMC part or the second ceramic or CIVIC part to a temperature between about 900° C. and about 1,000° C. prior to the molten silicon-containing braze material being introduced to the joint, wherein a carbon-containing filler is positioned at the joint, wherein molten silicon-containing braze material is introduced to the joint through the silicon injection port, wherein silicon metal from the molten silicon-containing braze material reacts with carbon from the carbon-containing filler to form silicon carbide and join the first ceramic or CIVIC part and the second ceramic or CMC part at the joint, and wherein no external heat source directly heats the joint during the reaction of the molten silicon-containing braze material with the carbon-containing filler.

18 . The system of claim 17 , wherein silicon injection port comprises at least one of silicon carbide or silicon-rich silicon carbide and a protective inner coating.

19 . The system of claim 17 , further comprising a thermal masking material positioned to reduce radiative heating of at least one of the first ceramic or CMC part, the second ceram

Assignees

• Rolls Royce Corp

Inventors

• Ritchey Andrew James

Classifications

• C04B2237/60

  Forming at the joining interface or in the joining layer specific reaction phases or zones, e.g. diffusion of reactive species from the interlayer to the substrate or from a substrate to the joining interface, carbide forming at the joining interface · CPC title

• B32B18/00

  Layered products essentially comprising ceramics, e.g. refractory products · CPC title

• B32B7/12

  using interposed adhesives or interposed materials with bonding properties · CPC title

• C04B2237/525

  by heating · CPC title

• C04B2237/083

  Carbide interlayers, e.g. silicon carbide interlayers · CPC title