Method and device for pyrolysis of biomass to produce syngas

Patent metadata

Field	Value
Publication number	US-2016272902-A1
Application number	US-201615167997-A
Country	US
Kind code	A1
Filing date	May 28, 2016
Priority date	Nov 29, 2013
Publication date	Sep 22, 2016
Grant date	—

Abstract

A method for pressurized pyrolysis of biomass in a pressurized pyrolysis furnace, including: 1) crushing and screening biomass; collecting biomass having desired particle sizes; and delivering the biomass having desired particle sizes to a pulse-type feeding system; 2) transporting the biomass to a pyrolysis furnace via the pulse-type feeding system; synchronously initiating microwave and a plasma torch, the microwave producing a microwave field in the pyrolysis furnace, working gas of the plasma torch being ionized for the first time to produce plasma jet entering the pyrolysis furnace; and 3) allowing the syngas generated in 2) to continue moving upwards and introducing the syngas out from the top of the pyrolysis furnace; chilling the syngas; introducing the syngas to a cyclone separator to separate residues; and then cooling and purifying the syngas using a cooling device and a purifying device, respectively, to produce clean syngas.

First claim

The invention claimed is:

1 . A method for pressurized pyrolysis of biomass in a pressurized pyrolysis furnace, the method comprising:
1) crushing and screening biomass; collecting biomass having desired particle sizes; and delivering the biomass having desired particle sizes to a pulse-type feeding system; 2) transporting the biomass to a pyrolysis furnace via the pulse-type feeding system in a dense-phase static pressure mode in the presence of seal air; synchronously initiating microwave and a plasma torch, the microwave producing a microwave field in the pyrolysis furnace, working gas of the plasma torch being initially ionized to produce plasma jet entering the pyrolysis furnace; in the pyrolysis furnace, biomass particles absorbing microwave and being heated from outside to inside instantaneously, and then being activated; under the action of rising syngas and microwave energy, the biomass particles being dried instantaneously and pyrolyzed to yield syngas, small amount of ash residue and coke, the ash residue and the coke constituting a fixed bed layer moving down; under the electromagnetic coupling of the microwave field, the plasma jet constantly ionizing gas around charged ions to form a secondary ionic field, thus accelerating the heat and mass transfer efficiency of the biomass particles; at the bottom of the fixed bed layer, the plasma jet completely converting the coke or other carbonaceous materials into syngas; with the fixed bed layer moving down, rising syngas heating the fixed bed layer and providing carbon dioxide as raw material gas for pyrolysis, and ash residue free of carbon continuing moving down; the ash residue containing free of carbon being in a liquid state and accumulating at the bottom of the pyrolysis furnace, discharging accumulated liquid ash residue regularly or continuously to maintain a preset slag level; and 3) allowing the syngas generated in 2) to continue moving upwards and introducing the syngas out from the top of the pyrolysis furnace; chilling the syngas using circulating syngas in a pipe; introducing the syngas to a cyclone separator to separate residues; and then cooling and purifying the syngas using a cooling device and a purifying device, respectively, to produce clean syngas.

2 . The method of claim 1 , wherein
a temperature of the syngas at an outlet of the pyrolysis furnace ranges from 1100° C. to 1300° C.; a pyrolysis temperature in the pyrolysis furnace exceeds 1200° C.; a temperature of a slag pool at the bottom of the pyrolysis furnace is maintained at between 1300° C. and 2000° C.; limestone is added as a fluxing agent to lower a fusion point temperature of slag; the pyrolysis furnace comprises microwave inlets which are arranged annularly and equidistantly in a multi-layer way; and a power of a single microwave inlet is below 300 kw; the syngas stays in the pyrolysis furnace for 8 to 15 seconds, and an absolute pressure in the pyrolysis furnace ranges from 0.1 megapascal to 5 megapascal.

3 . The method of claim 1 , wherein in 3), a total input energy of the microwave and the plasma torch per unit time accounts for 15% to 30% of a total input energy of the biomass; when the working gas of the plasma torch is oxygen, a mass of the coke accounts for less than 10% of that of the biomass, and a total power energy consumed by the microwave and the plasma torch accounts for between 5% and 10% of a total energy of the biomass.

4 . The method of claim 2 , wherein in 3), a total input energy of the microwave and the plasma torch per unit time accounts for 15% to 30% of a total input energy of the biomass; when the working gas of the plasma torch is oxygen, a mass of the coke accounts for less than 10% of that of the biomass, and a total power energy consumed by the microwave and the plasma torch accounts for between 5% and 10% of a total energy of the biomass.

5 . The method of claim 3 , wherein in 3), the syngas from the cyclone separator is cooled gradually and washed with water, or is chilled with water.

6 . The method of claim 4 , wherein in 3), the syngas from the cyclone separator is cooled gradually and washed with water, or is chilled with water.

7 . The method of claim 3 , wherein in 2), the liquid slag accumulated at the bottom of the pyrolysis furnace is discharged regularly or continuously to maintain the slag level; after passing through a slag lock equipped with a water cooling or water chilling device, the liquid slag is recycled at room temperature.

8 . The method of claim 4 , wherein in 2), the liquid slag accumulated at the bottom of the pyrolysis furnace is discharged regularly or continuously to maintain the slag level; after passing through a slag lock equipped with a water cooling or water chilling device, the liquid slag is recycled at room temperature.

9 . The method of claim 3 , wherein the working gas of the plasma torch is carbon dioxide and/or water vapor and/or oxygen and/or purified syngas; the plasma jet formed by the first ionization of the working gas comprises active particles comprising ions, electrons and free radicals.

10 . The method of claim 4 , wherein the working gas of the plasma torch is carbon dioxide and/or water vapor and/or oxygen and/or purified syngas; the plasma jet formed by the first ionization of the working gas comprises active particles comprising ions, electrons and free radicals.

11 . The method of claim 3 , wherein the pulse-type feeding system is loaded using a conveying gas which is nitrogen, vapor, carbon dioxide or purified syngas.

12 . The method of claim 4 , wherein the pulse-type feeding system is loaded using a conveying gas which is nitrogen, vapor, carbon dioxide or purified syngas.

13 . A device for pressurized pyrolysis of biomass, comprising: a pyrolysis furnace, a pulse-type feeding system, and a cyclone separator;
wherein
the pyrolysis furnace comprises a syngas outlet at a top thereof, two feeding ports arranged on both sides of a middle part thereof, a plurality of microwave inlets and interfaces of a plasma torch at a lower part thereof, and a slag outlet at a bottom thereof;
the microwave inlets of the pyrolysis furnace are arranged annularly and equidistantly in a multi-layer way;
a power of a single microwave inlet is below 300 kw; the interfaces of the plasma torch are located below the microwave inlets, and are arranged annularly and equidistantly;
the pulse-type feeding system is connected to feeding ports of the pyrolysis furnace via a feeding pipe; the pulse-type feeding system is connected to a conveying gas pipe and a feeding controller is provided to control the opening and closing of the conveying gas pipe; and
the syngas outlet at the top of the pyrolysis furnace is connected to the cyclone separator; the slag outlet at the bottom of the pyrolysis furnace is connected to a slag lock; an ash outlet of the cyclone separator is connected to an ash lock; the cyclone separator is connected to a cooling device; the cooling device is connected to a purifying device; a circulating chilling device is arranged between the syngas outlet and the cyclone separator.

14 . The device of claim 13 , wherein at least two slag locks are arranged in series outside the slag outlet at the bottom of the pyrolysis furnace; and at least two ash locks are arranged in series outside the ash outlet at the bottom of the cyclone separator.

15 . The device of claim 13 , wherein a decarburization tower is arranged following the purifying device; and the decarburization tower comprises a carbon dioxide outlet which is connected to the conveying gas pipe of the pulse-type fee

Assignees

• Wuhan Kaidi Eng Tech Res Inst

Inventors

• Zhang Yanfeng
• Zhang Liang
• Chen Yilong

Classifications

• C10B53/02 Primary

  of cellulose-containing material (production of pyroligneous acid C10C5/00) · CPC title

• Y02E50/10

  Biofuels, e.g. bio-diesel · CPC title

• C10K1/026

  by centrifugal forces (cyclones B04C) · CPC title

• C10J2300/0916

  Biomass · CPC title

• C10J3/84

  with means for removing dust or tar from the gas · CPC title