Using porous grains in powder-in-tube (pit) process

Patent metadata

Field	Value
Publication number	US-2016257572-A1
Application number	US-201514640649-A
Country	US
Kind code	A1
Filing date	Mar 6, 2015
Priority date	Mar 6, 2015
Publication date	Sep 8, 2016
Grant date	—

Abstract

The embodiments disclosed herein seek to ameliorate the high costs associated with the use of ultra-pure silica by using a lower-cost starting material and purifying the lower-cost starting material to an acceptable level of purity during the preform manufacturing process. In one embodiment, instead of using fully densified silica particulate, the disclosed process uses mesoporous silica grains that have a substantially monodisperse size distribution as the starting materials for a powder-in-tube preform manufacturing process.

First claim

What is claimed is:

1 . A powder-in-tube preform manufacturing process, comprising:
sealing a thin-walled silica tube with a grain-sealed bottom, the grain-sealed bottom being gas-permeable, the silica tube having a wall thickness of approximately 2.5 millimeters (mm), the silica tube having an inner diameter that is between approximately 25 mm to approximately 90 mm, the silica tube having a tube length of approximately 1.2 meters (m); inserting a core rod into the silica tube, the inserted core rod being substantially centered within the silica tube; filling the silica tube with mesoporous silica grains, the mesoporous silica grains being substantially monodisperse in size, the mesoporous silica grains being smaller than refractory particles; applying a vapor-phase purification process to the mesoporous silica grains, the vapor-phase purification process being applied at a temperature that is less than approximately 1300 degrees Celsius (° C.); applying a vacuum to the silica tube to decrease the pressure within the silica tube; sintering the mesoporous silica grains in the presence of the vacuum and at a temperature that is greater than approximately 1700° C.; and consolidating the silica tube substantially concurrently with the sintering of the mesoporous silica grains.

2 . The process of claim 1 , wherein the size of the mesoporous silica grain is between approximately 15 microns and approximately 550 microns.

3 . The process of claim 2 , wherein the size of the mesoporous silica grain is approximately 250 microns.

4 . A preform manufacturing process, comprising:
filling a silica tube with substantially homogeneous mesoporous silica grains; applying a vapor-phase purification process to the mesoporous silica grains; sintering the mesoporous silica grains; and consolidating the silica tube.

5 . The process of claim 4 , the mesoporous silica grains having a grain size of approximately 250 microns.

6 . The process of claim 4 , the consolidating of the silica tube being substantially concurrent with the sintering of the mesoporous silica grains.

7 . The process of claim 4 , the step of applying the vapor-phase purification process comprising:
applying a purification temperature that is less than approximately 1300 degrees Celsius (° C.).

8 . The process of claim 4 , further comprising:
applying a vacuum to the silica tube to decrease the pressure within the silica tube.

9 . The process of claim 8 , the sintering of the mesoporous silica grains comprising:
sintering the mesoporous silica grains in the presence of the vacuum.

10 . The process of claim 4 , the sintering of the mesoporous silica grains comprising:
sintering the mesoporous silica grains at a temperature that is greater than approximately 1700° C.

11 . A preform manufacturing system, comprising:
substantially homogeneous mesoporous silica grains; a silica tube holding the mesoporous silica grains; an input port to introduce gases into the silica tube; an output vent to evacuate impurities from the silica tube; and a heating element to heat the mesoporous silica grains.

12 . The system of claim 11 , the mesoporous silica grains having a grain size of approximately 250 microns.

13 . The system of claim 11 , the heating element being a torch.

14 . The system of claim 11 , the heating element being a furnace.

15 . The system of claim 11 , the input port to further depressurize the silica tube.

16 . The system of claim 11 , the output vent to further depressurize the silica tube.

17 . The system of claim 11 , the silica tube being a thin-walled tube.

18 . The system of claim 17 , the thin-walled tube having a wall thickness of approximately 2.5 millimeters.

Assignees

• Ofs Fitel Llc

Inventors

• Trevor Dennis J

Classifications

• C04B14/04

  Silica-rich materials; Silicates · CPC title

• C01B33/12 Primary

  Silica; Hydrates thereof, e.g. lepidoic silicic acid · CPC title

• C03B37/01297 Primary

  by melting glass powder in a mould · CPC title