Toner for electrostatic charge image development

Patent metadata

Field	Value
Publication number	US-2016246198-A1
Application number	US-201615048233-A
Country	US
Kind code	A1
Filing date	Feb 19, 2016
Priority date	Feb 25, 2015
Publication date	Aug 25, 2016
Grant date	—

Abstract

Provided is a toner for electrostatic charge image development which satisfies both low temperature fixability and an excellent storage stability and realizes excellent chargeability, fixing separation property, and flowability. According to the present invention, there is provided a toner for electrostatic charge image development comprising toner particles which comprises a binder resin including a crystalline polyester resin and a release agent, in which the crystalline polyester resin has a lamellar structure and the lamellar structure is present only on the inside of the toner particle when a cross-section of the toner particle subjected to ruthenium staining is observed with a transmission electron microscope.

First claim

1 . A toner for electrostatic charge image development comprising toner particles which comprise a binder resin including a crystalline polyester resin and a release agent, wherein
the crystalline polyester resin has a lamellar structure and the lamellar structure is present only on the inside of the toner particle when a cross-section of the toner particle subjected to ruthenium staining is observed with a transmission electron microscope.

2 . The toner for electrostatic charge image development according to claim 1 , wherein the content of the toner particles including the lamellar structure of the crystalline polyester resin only on the inside of the toner particle is 90% or more of the total toner particles.

3 . The toner for electrostatic charge image development according to claim 1 , wherein a domain diameter of the lamellar structure is 0.1 to 2 μm.

4 . The toner for electrostatic charge image development according to claim 1 , wherein the content of the toner particles having a domain diameter of the lamellar structure in the range of 0.1 to 2 μm are 80% or more of the total toner particles.

5 . The toner for electrostatic charge image development according to claim 1 , wherein the ratio of the cross-sectional area of the lamellar structure to the cross-sectional area of the toner particle in the cross-section of the ruthenium-stained toner particle is 1 to 20%.

6 . The toner for electrostatic charge image development according to claim 1 , wherein the ratio of the cross-sectional area of the lamellar structure to the cross-sectional area of the toner particle in the cross-section of the ruthenium-stained toner particle is 5 to 15%.

7 . The toner for electrostatic charge image development according to claim 1 , the added amount of the crystalline polyester resin is 1% by mass or more and less than 50% by mass of the total binder resin.

8 . The toner for electrostatic charge image development according to claim 1 , wherein the crystalline polyester resin is a hybrid crystalline polyester resin formed by chemically bonding a crystalline polyester resin unit and an amorphous resin unit other than a polyester resin.

9 . The toner for electrostatic charge image development according to claim 8 , wherein the content ratio of the hybrid crystalline polyester resin to the total binder resin is 1% by mass or more and less than 50% by mass.

10 . The toner for electrostatic charge image development according to claim 8 , wherein the melting point of the hybrid crystalline polyester resin is 55° C. or higher and 90° C. or lower.

11 . The toner for electrostatic charge image development according to claim 8 , wherein the content of the crystalline polyester resin unit is 80% by mass or more and less than 98% by mass with respect to the total amount of the hybrid crystalline polyester resin.

12 . The toner for electrostatic charge image development according to claim 1 , wherein the release agent comprises an ester wax or a hydrocarbon wax.

13 . The toner for electrostatic charge image development according to claim 1 , wherein a melting point of the release agent is 60 to 100° C.

14 . The toner for electrostatic charge image development according to claim 1 , wherein an acid value of the release agent is 0.1 to 10 mgKOH/g.

15 . A method for producing the toner for electrostatic charge image development according to claim 1 , the method comprising:
a step of preparing a mixed dispersion liquid by putting (a) a fine particle dispersion liquid comprising the release agent and (b) a fine particle dispersion liquid of the crystalline polyester resin in an aqueous medium; and a step of forming toner base particles by aggregating fine particles comprising the release agent and the crystalline polyester resin fine particles by raising the temperature of the mixed dispersion liquid.

Assignees

• Konica Minolta Inc

Inventors

• Fujisaki Natsuko
• Oshiba Tomomi
• Nomiya Makoto

Classifications

• G03G9/0825

  characterised by their structure; characterised by non-homogenuous distribution of components (microcapsular toners G03G9/093) · CPC title

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/08755 Primary

  Polyesters · CPC title

• G03G9/08782

  Waxes · CPC title

• G03G9/08786

  Graft polymers · CPC title