Low-foaming ink compositions including fluorosurfactants for indirect printing

Patent metadata

Field	Value
Publication number	US-2016237294-A1
Application number	US-201615143099-A
Country	US
Kind code	A1
Filing date	Apr 29, 2016
Priority date	Oct 16, 2014
Publication date	Aug 18, 2016
Grant date	—

Abstract

The present disclosure provides an ink comprising a fluorosurfactant-stabilized polymer latex, which is suitable for use in an indirect printing method.

First claim

What is claimed is:

1 . An ink for use in an indirect printing process comprising:
water; a co-solvent; and a fluorosurfactant-stabilized polymer latex comprising a polystyrene copolymer latex having a glass transition temperature of from 55° C. to about 63° C., and a fluorosurfactant, wherein the fluorosurfactant is an anionic phosphate ester and does not covalently bind to the polymer latex, wherein the fluorosurfactant comprises a partially or fully fluorinated alkyl group having from 1 to 12 carbon atoms and a perfluoro telomer, and further wherein the fluorosurfactant is present in the ink in an amount from about 0.0001 percent to about 0.1 percent by weight based on the total weight of the ink.

2 . The ink of claim 1 , wherein the fluorosurfactant is present in the ink in an amount from about 0.0375 percent to about 0.05 percent by weight based on the total weight of the ink.

3 . The ink of claim 2 , wherein the fluorosurfactant is present in the ink in an amount from about 0.001 percent to about 0.075 percent by weight based on the total weight of the ink.

4 . The ink of claim 1 further comprising a second surfactant.

5 . The ink of claim 1 , wherein the co-solvent has a solubility parameter in the range of from about 27 to about 37 MPa 1/2 .

6 . The ink of claim 1 , wherein the co-solvent is selected from the group consisting of 1,5-pentanediol, 2-pyrollidone, glycerol, and mixtures thereof.

7 . The ink of claim 1 , wherein the polystyrene copolymer latex comprises a latex emulsion comprising polymer particles generated from the emulsion polymerization of styrene and a monomer selected from the group consisting of n-butyl acrylate, methacrylic acid, β-carboxyethyl acrylate or mixtures thereof.

8 . The ink of claim 1 , wherein the polystyrene copolymer latex is present in an amount of about 3 to about 20 weight percent based on the total weight of the ink.

9 . The ink of claim 1 , wherein the polystyrene copolymer has a weight average molecular weight of from about 10,000 g/mol to about 40,000 g/mol.

10 . The ink of claim 1 , wherein the polystyrene copolymer has a volume average particle size of from about 50 nm to about 300 nm.

11 . The ink of claim 1 further comprising a colorant selected from the group consisting of pigment, dye, mixtures of pigment and dye, mixtures of pigments, and mixtures of dyes.

12 . The ink of claim 1 having a surface tension of from about 18 to about 35 mN/m at a jetting temperature of less that about 70° C.

13 . The ink of claim 1 having a viscosity of from about 2 centipoise to about 20 centipoise 30° C.

14 . A low foaming ink for use in an indirect printing process comprising:
water; a co-solvent; and a fluorosurfactant-stabilized polymer latex comprising a polystyrene copolymer latex having a glass transition temperature of from 55° C. to about 63° C. and an anionic phosphate ester fluorosurfactant, wherein the fluorosurfactant does not covalently bind to the polymer latex, wherein the fluorosurfactant comprises a partially or fully fluorinated alkyl group having from 1 to 12 carbon atoms and a perfluoro telomer, and further wherein the fluorosurfactant is present in the ink in an amount from about 0.0001 percent to about 0.1 percent by weight based on the total weight of the ink; and further wherein the ink has a surface tension of from about 18 to about 35 mN/m a jetting temperature of less that about 70° C.

15 . The ink of claim 14 , wherein the polystyrene copolymer latex comprises a latex emulsion comprising polymer particles generated from the emulsion polymerization of styrene and a monomer selected from the group consisting of n-butyl acrylate, methacrylic acid, β-carboxyethyl acrylate and mixtures thereof.

16 . An ink for use in an indirect printing process comprising:
water; a co-solvent; and
a fluorosurfactant-stabilized polymer latex comprising a polystyrene copolymer latex having a glass transition temperature of from 55° C. to about 63° C., and a fluorosurfactant, wherein the fluorosurfactant is an ammonia neutralized phosphate ester type or a diethanolamine neutralized phosphate ester type and does not covalently bind to the polymer latex, wherein the fluorosurfactant comprises a partially or fully fluorinated alkyl group having from 1 to 12 carbon atoms and a perfluoro telomer, and further wherein the fluorosurfactant is present in the ink in an amount from about 0.0001 percent to about 0.1 percent by weight based on the total weight of the ink.

17 . The ink of claim 16 , wherein the fluorosurfactant is present in the ink in an amount from about 0.001 percent to about 0.075 percent by weight based on the total weight of the ink.

18 . The ink of claim 17 , wherein the fluorosurfactant is present in the ink in an amount from about 0.0375 percent to about 0.05 percent by weight based on the total weight of the ink.

19 . The ink of claim 16 further comprising a second surfactant.

20 . The ink of claim 19 , wherein the second surfactant is selected from the group consisting of ionic surfactants, anionic surfactants, cationic surfactants, nonionic surfactants, zwitterionic surfactants, and mixtures thereof.

Assignees

• Xerox Corp

Inventors

• Farrugia Valerie M
• Song Guiqin
• Eliyahu Jenny

Classifications

• C09D11/38 Primary

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title

• C09D11/322

  Pigment inks · CPC title

• C09D11/328

  characterised by dyes · CPC title

• C09D11/108

  Hydrocarbon resins · CPC title

• C09D11/106

  containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title