Erosion resistant hard composite materials
US-2015354283-A1 · Dec 10, 2015 · US
US2016236988A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016236988-A1 |
| Application number | US-201415030134-A |
| Country | US |
| Kind code | A1 |
| Filing date | Oct 22, 2014 |
| Priority date | Oct 22, 2013 |
| Publication date | Aug 18, 2016 |
| Grant date | — |
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A CBN sintered body contains CBN, a binder phase and inevitable impurities. An amount of CBN by volume is between 50%-80%. A total amount of binder phase and inevitable impurities by volume is between 20%-50%. The binder phase contains an Al compound and a Ti compound. The Al compound contains Al and one or more of N, O and B. The Ti compound contains Ti and one or more of C, N and B. When an X-ray diffraction intensity at a (100) plane of the AlN is I 1 and an X-ray diffraction intensity at a (104) plane of the Al 2 O 3 is I 2 , I 1 /I 2 is between 6 and 40. When a total area of the cubic boron nitride and the Al compound is S1, and an area of a region at which the CBN and the Al compound are continuously contacted is S2, S2/S1 is between 0.98 and 1.00.
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1 - 8 . (canceled) 9 . A cubic boron nitride sintered body comprising: cubic boron nitride, a binder phase and inevitable impurities, an amount of the cubic boron nitride is 50% by volume or more and 80% by volume or less, a total amount of the binder phase and the inevitable impurities is 20% by volume or more and 50% by volume or less, the binder phase contains an Al compound and a Ti compound, the Al compound contains an Al element and at least one element selected from the group consisting of N, O and B, the Ti compound contains a Ti element and at least one element selected from the group consisting of C, N and B, the Al compound contains AlN and Al 2 O 3 , when an X-ray diffraction intensity at a (100) plane of the AlN is given by I 1 , and an X-ray diffraction intensity at a (104) plane of the Al 2 O 3 is given by I 2 , then I 1 /I 2 is 6 or more and 40 or less, and when a total area of the cubic boron nitride and the Al compound is given by 51, and an area of a region at which the cubic boron nitride and the Al compound are continuously contacted is given by S2, then S2/S1 is 0.98 or more and 1.00 or less. 10 . The cubic boron nitride sintered body according to claim 9 , wherein: the Ti compound contains TiB 2 , and when an X-ray diffraction intensity at a (101) plane of the TiB 2 is given by I 3 , then I 3 /I 1 is 0.5 or more and 2.0 or less. 11 . The cubic boron nitride sintered body according to claim 9 , wherein an area of the Al compound is given by S A , and an area of the Ti compound is given by S T , then S T /S A is 1 or more and 3 or less. 12 . The cubic boron nitride sintered body according to claim 9 , wherein an average grain diameter of the cubic boron nitride is 0.3 μm or more and 1.5 μm or less. 13 . The cubic boron nitride sintered body according to claim 9 , wherein: the Ti compound contains TiB 2 ; when an X-ray diffraction intensity at a (101) plane of the TiB 2 is given by I 3 , then I 3 /I 1 is 0.5 or more and 2.0 or less; an area of the Al compound is given by S A , and an area of the Ti compound is given by S T , then S T /S A is 1 or more and 3 or less; and an average grain diameter of the cubic boron nitride is 0.3 μm or more and 1.5 μm or less. 14 . A coated cubic boron nitride sintered body comprising: the cubic boron nitride sintered body according to claim 9 ; and a film formed on a surface of the cubic boron nitride sintered body. 15 . The coated cubic boron nitride sintered body according to claim 14 , wherein the film comprises: at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Al and Si, and at least one element selected from the group consisting of C, N, O and B. 16 . The coated cubic boron nitride sintered body according to claim 14 , wherein the film is a single layer film or a laminated film containing two or more layers. 17 . The coated cubic boron nitride sintered body according to claim 14 , wherein an average film thickness of the film is 0.5 μm or more and 20 μm or less. 18 . The coated cubic boron nitride sintered body according to claim 14 , wherein: an average film thickness of the whole film is 0.5 μm or more and 20 μm or less; and the film comprises: at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Al and Si, and at least one element selected from the group consisting of C, N, O and B. 19 . The coated cubic boron nitride sintered body according to claim 18 , wherein: the film is a laminated film containing two or more layers.
submicron sized, i.e. from 0,1 to 1 micron · CPC title
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