Marble-like composite materials and methods of preparation thereof

Patent metadata

Field	Value
Publication number	US-2016236984-A1
Application number	US-201615049110-A
Country	US
Kind code	A1
Filing date	Feb 21, 2016
Priority date	Oct 4, 2012
Publication date	Aug 18, 2016
Grant date	—

Abstract

The invention provides novel marble-like composite materials and methods for preparation thereof. The marble-like composite materials can be readily produced from widely available, low cost raw materials by a process suitable for large-scale production. The precursor materials include calcium silicate and calcium carbonate rich materials, for example, wollastonite and limestone. Various additives can be used to fine-tune the physical appearance and mechanical properties of the composite material, such as pigments (e.g., black iron oxide, cobalt oxide and chromium oxide) and minerals (e.g., quartz, mica and feldspar). These marble-like composite materials exhibit veins, swirls and/or waves unique to marble as well as display compressive strength, flexural strength and water absorption similar to that of marble.

First claim

What is claimed is:

1 . An article of manufacture made from a composite material comprising:
a plurality of bonding elements, wherein each bonding element comprises:
a core comprising primarily calcium silicate,
a silica-rich first or inner layer, and
a calcium carbonate-rich second or outer layer;
a plurality of filler particles having a median particle size in the range from about 5 μm to about 7 mm; and one or more pigments selected from iron oxide, cobalt oxide and chromium oxide, wherein the plurality of bonding elements and the plurality of filler particles together form one or more bonding matrices with the one or more pigments substantially unevenly dispersed therein so as to exhibit patterns of swirls, veins and waves, and the bonding elements and the filler particles are substantially evenly dispersed in the one or more bonding matrices and bonded together,
whereby the article exhibits substantially marble-like textures, patterns and physical properties.

2 - 4 . (canceled)

5 . The article of claim 1 , wherein
the plurality of bonding elements have a median particle size in the range from about 5 μm to about 30 μm; and the plurality of filler particles have a median particle size in the range from about 100 μm to about 3 mm.

6 . The article of claim 5 , wherein the filler particles are made from a calcium carbonate-rich material selected from quartz, mica and feldspar.

7 . (canceled)

8 . The article of claim 1 , wherein
the plurality of bonding elements are chemically transformed from ground wollastonite comprising one or more of aluminum, magnesium and iron; and the filler particles comprise ground limestone.

9 . The article of claim 1 , wherein the plurality of bonding elements are chemically transformed from a precursor calcium silicate other than wollastonite.

10 . (canceled)

11 . (canceled)

12 . The article of claim 8 , wherein the weight ratio of bonding elements:filler particles is about 15-50:50-85.

13 . (canceled)

14 . The article of claim 8 , wherein the plurality of bonding elements are prepared by chemical transformation from ground wollastonite by reacting it with CO 2 via a controlled hydrothermal liquid phase sintering process.

15 . (canceled)

16 . The article of claim 14 , having a compressive strength from about 100 MPa to about 300 MPa and a flexural strength from about 15 MPa to about 40 MPa.

17 . The article of claim 16 , having water absorption of less than about 10%.

18 - 20 . (canceled)

21 . A process for preparing a composite material, comprising:
mixing a particulate composition and a liquid composition to form a slurry mixture, wherein the particulate composition comprises:
a ground calcium silicate having a median particle size in the range from about 1 μm to about 100 μm, and
a first ground calcium carbonate having a median particle size in the range from about 3 μm to about 7 mm,
and wherein the liquid composition comprises:
water, and
a water-soluble dispersant;
casting the slurry mixture in a mold; and curing the casted mixture at a temperature in the range from about 20° C. to about 150° C. for about 1 hour to about 80 hours under an atmosphere of water and CO 2 having a pressure in the range from ambient atmospheric pressure to about 60 psi above ambient and having a CO 2 concentration ranging from about 10% to about 90% to produce a composite material exhibiting a marble-like texture and pattern.

22 . The process of claim 21 , wherein the particulate composition further comprises
a second ground calcium carbonate having substantially smaller or larger median particle size than the first ground limestone.

23 . The process of claim 22 , further comprising, before curing the casted mixture:
drying the casted mixture.

24 . The process of claim 21 , wherein the particulate composition further comprises a pigment.

25 . The process of claim 21 , wherein curing the casted mixture is performed at a temperature in the range from about 60° C. to about 110° C. for about 15 hours to about 70 hours under a vapor comprising water and CO 2 and having a pressure in the range from about ambient atmospheric pressure to about 30 psi above ambient atmospheric pressure.

26 . The process of claim 25 , wherein curing the casted mixture is performed at a temperature in the range from about 80° C. to about 100° C. for about 20 hours to about 60 hours under a vapor comprising water and CO 2 and having a pressure in the range from about ambient atmospheric pressure to about 30 psi above ambient atmospheric pressure.

27 . The process of claim 26 , wherein curing the casted mixture is performed at a temperature equal to or lower than about 60° C. for about 15 to about 50 hours under a vapor comprising water and CO 2 and having an ambient atmospheric pressure.

28 . The process of claim 24 , wherein
the ground calcium silicate comprises ground wollastonite, the first ground calcium carbonate comprises a first ground limestone, and the second ground calcium carbonate comprises a second ground limestone.

29 . The process of claim 28 , wherein
the ground wollastonite has a median particle size from about 5 μm to about 50 μm, a bulk density from about 0.6 g/mL to about 0.8 g/mL (loose) and about 1.0 g/mL to about 1.2 g/mL (tapped), a surface area from about 1.5 m 2 /g to about 2.0 m 2 /g, the first ground limestone has a median particle size from about 40 μm to about 90 μm, a bulk density from about 0.7 g/mL to about 0.9 g/mL (loose) and about 1.3 g/mL to about 1.6 g/mL (tapped), the second ground limestone has a median particle size from about 20 μm to about 60 μm, a bulk density from about 0.6 g/mL to about 0.8 g/mL (loose) and about 1.1 g/mL to about 1.4 g/mL (tapped), and a pigment comprising a metal oxide,
and wherein the liquid composition comprises:
water, and
a water-soluble dispersant comprising a polymer salt having a concentration from about 0.1% to about 2% w/w of the liquid composition.

30 . The process of claim 29 , wherein
the metal oxide is an iron oxide, and the polymer salt is an acrylic homopolymer salt.

31 . The process of claim 22 , wherein the particulate composition comprises about 50% to about 70% w/w of ground calcium silicate, about 20% to about 40% w/w of the first ground calcium carbonate, and about 10% to about 30% w/w of the second ground calcium carbonate.

32 - 41 . (canceled)

Assignees

• Solidia Technologies Inc

Inventors

• Riman Richard E
• Zambrzycki Dawid

Classifications

• C04B2111/00019

  Carbon dioxide sequestration · CPC title

• C04B28/26 Primary

  Silicates of the alkali metals · CPC title

• C04B28/10 Primary

  Lime cements or magnesium oxide cements · CPC title

• Y02P40/18

  Carbon capture and storage [CCS] · CPC title

• C04B28/188

  the Ca-silicates being present in the starting mixture · CPC title