Carbon long fiber reinforced thermoplastic resin composition and molded article manufactured using the same

Patent metadata

Field	Value
Publication number	US-2016222208-A1
Application number	US-201514967705-A
Country	US
Kind code	A1
Filing date	Dec 14, 2015
Priority date	Feb 2, 2015
Publication date	Aug 4, 2016
Grant date	—

Abstract

The present invention relates to a thermoplastic resin composition and a molded article manufactured using the thermoplastic resin composition. Particularly, the thermoplastic resin composition may be reinforced with the carbon fiber. Accordingly, the thermoplastic resin composition may be obtained by mixing a carbon fiber, a silane-based coupling agent and a thermoplastic elastomer to a polyamide-6 polymer having low specific gravity, such that weight thereof may be reduced and economical efficiency may be improved. Further, parts assembly efficiency and stability of the injection molded product from the thermoplastic resin composition of the present invention may be improved by minimizing deformation after injection molding due to improved rigidity, durability and dimensional stability thereof. The thermoplastic resin composition may be used for parts of vehicle exterior material such as a panorama sunroof frame.

First claim

What is claimed is:

1 . A thermoplastic resin composition, comprising:
a polyamide-6 polymer in an amount of about 45 to 93 wt %: a carbon-fiber in an amount of about 5 to 40 wt %; a silane-based coupling agent in an amount of about 1 to 5 wt %; and a thermoplastic elastomer in an amount of about 1 to 10 wt %. wherein the carbon fiber has a mean section diameter of about 5 to 15 μm and a length of about 5 to 15 mm, wherein the thermoplastic elastomer has a melt index of about 10 to 40 g/10 min at a temperature of about of about 230° C. and at a load of about 2.16 kg.

2 . The thermoplastic resin composition of claim 1 , wherein the polyamide-6 polymer has a number average molecular weight of about 20,000 to 70,000.

3 . The thermoplastic resin composition of claim 1 , wherein the carbon-fiber is made from polyacrylonitrile (PAN), Pitch or a mixture thereof.

4 . The thermoplastic resin composition of claim 1 , wherein the carbon-fiber comprises a sizing material in an amount of about 0.1 to 3 wt % based on the total weight of the carbon fiber.

5 . The thermoplastic resin composition of claim 4 , wherein the sizing material is at least one selected from the group consisting of a urethane resin, an acryl resin, a styrene resin and an epoxy resin.

6 . The thermoplastic resin composition of claim 1 , wherein the silane-based coupling agent is a compound expressed by the following Chemical Formula,

wherein,
each R and R′ are the same or different to each other, and are a hydrogen atom or an optionally substituted alkyl group suitably containing 1 to 30 carbon atoms, and
Y is selected from the group consisting of vinyl group, amino group, methacryl group, epoxy group and mercapto group, each group suitably contains 1 to 20 carbon atoms.

7 . The thermoplastic resin composition of claim 1 , wherein the thermoplastic elastomer is an ethylene-α-olefin copolymer having a carbon number (α) of 4 or greater, a styrene-diene copolymer or a mixture thereof.

8 . The thermoplastic resin composition of claim 1 , further comprising an antioxidant selected from the group consisting of a phenol-based antioxidant, a phosphite-based antioxidant and a thiopropionate synergist.

9 . A molded article that comprises a thermoplastic resin composition of claim 1 .

10 . The molded article of claim 9 , which is a panorama sunroof frame for a vehicle.

11 . A vehicle comprising a molded article of claim 9 .

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Gs Caltex

Inventors

• Park Sang Sun
• Yu Kyung Min
• Jeong Kie Youn
• Kim Seok Hwan
• Lee Hyung Tak
• Boo Woong Jae
• Seo Jong Tae

Classifications

• C08L77/06 Primary

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• C08K7/06

  Elements · CPC title

• C08L77/02 Primary

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08L77/10 takes precedence) · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08K5/5435

  containing oxygen in a ring · CPC title