High energy density redox flow device

Patent metadata

Field	Value
Publication number	US-2016218375-A1
Application number	US-201514840810-A
Country	US
Kind code	A1
Filing date	Aug 31, 2015
Priority date	Jun 12, 2008
Publication date	Jul 28, 2016
Grant date	—

Abstract

Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

First claim

What is claimed is:

1 - 23 . (canceled)

24 . An electrochemical cell comprising:
an anode; a semi-solid cathode including an electrode composition comprising a suspension of ion storage compound particles capable of taking up or releasing ions; and an ion-permeable membrane disposed between the anode and the semi-solid cathode; wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

25 . The electrochemical cell of claim 24 , wherein the ion storage compound particles have a bidisperse size distribution in which the two maxima differ in size by at least a factor of 5.

26 . The electrochemical cell of claim 24 , wherein the particles have morphology that is at least equiaxed.

27 . The electrochemical cell of claim 24 , wherein the particle packing fraction is at least 50 vol %.

28 . The electrochemical cell of claim 24 , wherein the electrode composition further comprises an electronically conductive material.

29 . The electrochemical cell of claim 28 , wherein the electronically conductive material forms a percolative conductive pathway.

30 . The electrochemical cell of claim 28 , wherein the electronically conductive material comprises an electronically conductive polymer.

31 . The electrochemical cell of claim 28 , wherein the electronically conductive material is selected from the group consisting of metals, metal carbides, metal nitrides, metal oxides, and allotropes of carbon including carbon black, graphitic carbon, carbon fibers, carbon microfibers, vapor-grown carbon fibers (VGCF), fullerenic carbons including “buckyballs”, carbon nanotubes (CNTs), multiwall carbon nanotubes (MWNTs), single wall carbon nanotubes (SWNTs), graphene sheets or aggregates of graphene sheets, and materials comprising fullerenic fragments and mixtures thereof.

32 . An electrochemical cell comprising:
an anode; a semi-solid cathode including an electrode composition comprising a suspension of ion storage compound particles capable of taking up or releasing ions; and an ion-permeable membrane disposed between the anode and the semi-solid cathode; wherein the volume percentage of the ion storage compound particles is between 5% and 70%, and wherein the ion storage compound particles have a polydisperse size distribution and the particle packing fraction is at least 50 vol %.

33 . The electrochemical cell of claim 32 , wherein the finest particles in the polydisperse size distribution present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

34 . The electrochemical cell of claim 32 , wherein the ion storage compound particles have a bidisperse size distribution in which the two maxima differ in size by at least a factor of 5.

35 . The electrochemical cell of claim 32 , wherein the particles have morphology that is at least equiaxed.

36 . The electrochemical cell of claim 32 , wherein the electrode composition further comprises an electronically conductive material.

37 . The electrochemical cell of claim 36 , wherein the electronically conductive material forms a percolative conductive pathway.

38 . The electrochemical cell of claim 36 , wherein the electronically conductive material comprises an electronically conductive polymer.

39 . The electrochemical cell of claim 36 , wherein the electronically conductive material is selected from the group consisting of metals, metal carbides, metal nitrides, metal oxides, and allotropes of carbon including carbon black, graphitic carbon, carbon fibers, carbon microfibers, vapor-grown carbon fibers (VGCF), fullerenic carbons including “buckyballs”, carbon nanotubes (CNTs), multiwall carbon nanotubes (MWNTs), single wall carbon nanotubes (SWNTs), graphene sheets or aggregates of graphene sheets, and materials comprising fullerenic fragments and mixtures thereof.

40 . An electrochemical cell comprising:
an anode; a cathode; and an ion-permeable membrane disposed between the anode and the cathode; wherein at least one of the anode and the cathode includes a semi-solid electrode composition comprising a suspension of ion storage compound particles capable of taking up or releasing ions, and wherein the ion storage compound particles have a polydisperse size distribution and the particle packing fraction is at least 50 vol %.

41 . The electrochemical cell of claim 40 , wherein the ion storage compound particles in the semi-solid electrode is at least 10% by mass.

42 . The electrochemical cell of claim 40 , wherein the volume percentage of the ion storage compound particles is between 5% and 70%.

43 . The electrochemical cell of claim 40 , wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

44 . The electrochemical cell of claim 40 , wherein the semi-solid electrode composition further comprises an electronically conductive material.

45 . The electrochemical cell of claim 44 , wherein the electronically conductive material forms a percolative conductive pathway.

46 . The electrochemical cell of claim 44 , wherein the electronically conductive material is selected from the group consisting of metals, metal carbides, metal nitrides, metal oxides, and allotropes of carbon including carbon black, graphitic carbon, carbon fibers, carbon microfibers, vapor-grown carbon fibers (VGCF), fullerenic carbons including “buckyballs”, carbon nanotubes (CNTs), multiwall carbon nanotubes (MWNTs), single wall carbon nanotubes (SWNTs), graphene sheets or aggregates of graphene sheets, and materials comprising fullerenic fragments and mixtures thereof.

Assignees

• 24M Technologies Inc

Inventors

• Chiang Yet-Ming
• Carter W Craig
• Duduta Mihai
• Limthongkul Pimpa

Classifications

• H01M8/0228

  in the form of layered or coated products · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M8/0221

  Organic resins; Organic polymers · CPC title

• H01M8/0206

  Metals or alloys · CPC title

• H01M8/0215

  Glass; Ceramic materials · CPC title