Pesticidal compositions and related methods

Patent metadata

Field	Value
Publication number	US-2016208281-A1
Application number	US-201615053855-A
Country	US
Kind code	A1
Filing date	Apr 5, 2016
Priority date	Oct 22, 2013
Publication date	Jul 21, 2016
Grant date	—

Abstract

A process of applying a pesticidal composition to an area to control a pest, wherein the pesticidal composition comprises at least one compound selected from a compound of formula I, or any agriculturally acceptable salt thereof, wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , Q, Z, L, L a , and x are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests.

First claim

We claim:

1 . A process comprising applying a pesticidal composition to an area to control a pest, in an amount sufficient to control such pest, wherein the pesticidal composition comprises a compound of formula I or any agriculturally acceptable salt thereof:

wherein:
(a) R 1 , R 2 , and R 4 are independently selected from hydrogen, F, Cl, Br, I, substituted or unsubstituted C 1 -C 6 alkyl, or substituted or unsubstituted C 1 -C 6 haloalkyl,
wherein each said R 1 , R 2 , and R 4 , when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 1 -C 6 haloalkyl, C 3 -C 10 cycloalkyl, or C 3 -C 10 halocycloalkyl, (each of which that may be substituted, may optionally be substituted with R 10 );
(b) R 3 is selected from hydrogen, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6 alkyl, substituted or unsubstituted C 2 -C 6 alkenyl, substituted or unsubstituted C 1 -C 6 alkoxy, substituted or unsubstituted C 3 -C 10 cycloalkyl, substituted or unsubstituted C 1 -C 6 haloalkyl, substituted or unsubstituted C 6 -C 20 aryl, substituted or unsubstituted C 1 -C 20 heterocyclyl, OR 10 , C(═X 1 )R 10 , C(═X 1 )OR 10 , C(═X 1 )N(R 10 ) 2 , N(R 10 ) 2 , N(R 10 )C(═X 1 )R 10 , SR 10 , S(O) n OR 10 , or R 10 S(O) n R 10 ,
wherein each said R 3 , when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 1 -C 6 haloalkyl, C 2 -C 6 haloalkenyl, C 1 -C 6 haloalkyloxy, C 2 -C 6 haloalkenyloxy, C 3 -C 10 cycloalkyl, C 3 -C 10 cycloalkenyl, C 3 -C 10 halocycloalkyl, C 3 -C 10 halocycloalkenyl, OR 10 , S(O) n OR 10 , C 6 -C 20 aryl, or C 1 -C 20 heterocyclyl, (each of which that may be substituted, may optionally be substituted with R 10 );
(c) R 5 is selected from H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6 alkyl, substituted or unsubstituted C 2 -C 6 alkenyl, substituted or unsubstituted C 1 -C 6 alkoxy, C 3 -C 10 cycloalkyl, substituted or unsubstituted C 6 -C 20 aryl, substituted or unsubstituted C 1 -C 20 heterocyclyl, OR 10 , C(═X 1 )R 10 , C(═X 1 )OR 10 , C(═X 1 )N(R 10 ) 2 , N(R 10 ) 2 , N(R 10 )C(═X 1 )R 10 , SR 10 , S(O) n OR 10 , or R 10 S(O) n R 10 ,
wherein each said R 5 , when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 1 -C 6 haloalkyl, C 2 -C 6 haloalkenyl, C 1 -C 6 haloalkyloxy, C 2 -C 6 haloalkenyloxy, C 3 -C 10 cycloalkyl, C 3 -C 10 cycloalkenyl, C 3 -C 10 halocycloalkyl, C 3 -C 10 halocycloalkenyl, OR 10 , S(O) n OR 10 , C 6 -C 20 aryl, or C 1 -C 20 heterocyclyl, (each of which that may be substituted, may optionally be substituted with R 10 );
(d) R 6 is H, F, Cl, Br, I, substituted or unsubstituted C 1 -C 6 alkyl, or C 1 -C 6 haloalkyl,
wherein each said R 6 , when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 1 -C 6 haloalkyl, C 2 -C 6 haloalkenyl, C 1 -C 6 haloalkyloxy, C 2 -C 6 haloalkenyloxy, C 3 -C 10 cycloalkyl, C 3 -C 10 cycloalkenyl, C 3 -C 10 halocycloalkyl, or C 3 -C 10 halocycloalkenyl;
(e) R 7 is selected from hydrogen, substituted or unsubstituted C 1 -C 6 alkyl, substituted or unsubstituted C 2 -C 6 alkenyl, substituted or unsubstituted C 2 -C 6 alkynyl, substituted or unsubstituted C 1 -C 6 alkoxy, substituted or unsubstituted C 3 -C 10 cycloalkyl, C 1 -C 6 alkyl C 2 -C 6 alkynyl wherein the alkyl and alkynyl is independently substituted or unsubstituted, substituted or unsubstituted C 6 -C 20 aryl, substituted or unsubstituted C 1 -C 20 heterocyclyl, C 1 -C 6 alkyl C 6 -C 20 aryl wherein the alkyl and aryl is independently substituted or unsubstituted), C 1 -C 6 alkyl-(C 3 -C 10 cyclohaloalkyl) wherein the alkyl and cyclohaloalkyl is independently substituted or unsubstituted, or C 1 -C 6 alkyl-(C 3 -C 10 cycloalkyl) wherein the alkyl and cycloalkyl is independently substituted or unsubstituted,
wherein each said R 7 , when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl C 1 -C 6 haloalkyl, C 2 -C 6 haloalkenyl, C 1 -C 6 haloalkyloxy, C 2 -C 6 haloalkenyloxy, C 3 -C 10 cycloalkyl, C 3 -C 10 cycloalkenyl, C 3 -C 10 halocycloalkyl, C 3 -C 10 halocycloalkenyl, OR 10 , S(O) n OR 10 , C 6 -C 20 aryl, or C 1 -C 20 heterocyclyl, R 10 aryl, (each of which that may be substituted, may optionally be substituted with R 10 );
(f) R 8 is selected from substituted or unsubstituted C 1 -C 6 alkyl, substituted or unsubstituted C 2 -C 6 alkenyl, substituted or unsubstituted C 1 -C 6 alkoxy, substituted or unsubstituted C 3 -C 10 cycloalkyl, substituted or unsubstituted C 3 -C 10 halocycloalkyl substituted or unsubstituted C 3 -C 10 cycloalkenyl, substituted or unsubstituted C 6 -C 20 aryl, or substituted or unsubstituted C 1 -C 20 heterocyclyl,
wherein each said R 8 , when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6 alkyl, substituted or unsubstituted C 2 -C 6 alkenyl, substituted or unsubstituted C 1 -C 6 haloalkyl, substituted or unsubstituted C 2 -C 6 haloalkenyl, substituted or unsubstituted C 1 -C 6 haloalkyloxy, substituted or unsubstituted C 2 -C 6 haloalkenyloxy, substituted or unsubstituted C 3 -C 10 cycloalkyl, substituted or unsubstituted C 3 -C 10 cycloalkenyl, substituted or unsubstituted C 3 -C 10 halocycloalkyl, substituted or unsubstituted C 3 -C 10 halocycloalkenyl, oxo, OR 10 , S(O) n R 10 , substituted or unsubstituted C 6 -C 20 aryl, or substituted or unsubstituted C 1 -C 20 heterocyclyl, (each of which, when substituted, is substituted with R 10 );
(g) L is N(R 9 );
(h) L a is selected from R 9 , OR 9 , N(R 9 ) 2 , N(R 9 )(R 11 ), N(R 9 )(OR 11 ), NR 9 )C(═X 1 )R 9 , N(R 9 )C(═X 1 )(R 11 ), C(R 9 ) 3 , C(R 9 )(R 11 )(R 12 ), or SR 9 ;
optionally L and L a are connected in a cyclic arrangement, which forms 3-8 membered heterocycles or carbocycles including L and L a ,
wherein the cyclic arrangement contains none or at least one of O, S, or N heteroatoms, and the cyclic arrangement is unsubstituted or substituted,
wherein, when substituted, the cyclic arrangement has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6 alkyl, substituted or unsubstituted C 2 -C 6 alkenyl, substituted or unsubstituted C 2 -C 6 alkynyl, substituted or unsubstituted C 1 -C 6 haloalkyl, substituted or unsubstituted C 2 -C 6 haloalkenyl, substituted or unsubstituted C 1 -C 6 haloalkyloxy, substituted or unsubstituted C 2 -C 6 haloalkenyloxy, substituted or unsubstituted C 3 -C 10 cycloalkyl, substituted or unsubstituted C 3 -C 10 cycloalkenyl, substituted or unsubstituted C 3 -C 10 halocycloalkyl, substituted or unsubstituted C 3 -C 10 halocycloalkenyl, N(R 9 )S(O) n R 11 , oxo, OR 9 , S(O) n OR 9 , R 9 S(O) n R 11 , S(O) n R 9 , substituted or unsubstituted C 6 -C 20 aryl, or substituted or unsubstituted C 1 -C 20 heterocyclyl (each of which, when substituted, is substituted with R 10 );
(i) R 9 , R 11 , R 12 , and R 13 are independently selected from hydrogen, CN, NO 2 , substituted or unsubstituted C 1 -C 6 alkyl, substituted or unsubstituted C 2 -C 6 alkenyl, substituted or unsubstituted C 1 -C 6 alkoxy, substituted or unsubstituted C 3 -C 10 cycloalkyl, substituted or unsubstituted C 3 -C 10 halocycloalkyl, substituted or unsubstituted C 3 -C 10 cycloalkenyl, substituted or unsubstituted C 6 -C 20 aryl, or substituted or

Assignees

• Dow Agrosciences Llc

Inventors

• Zhang Yu
• Kubota Asako
• Niyaz Noormohamed M
• Barton Thomas
• Trullinger Tony K
• Lowe Christian T
• Leplae Paul R
• Buysse Ann M
• Walsh Martin J
• Garizi Negar
• Hunter Ricky
• Knueppel Daniel

Classifications

• C05G3/60

  Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants · CPC title

• A01N43/80

  five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2 · CPC title

• A01N43/78

  1,3-Thiazoles; Hydrogenated 1,3-thiazoles · CPC title

• A01N43/92

  having rings with one or more halogen atoms as ring hetero atoms · CPC title

• A01N43/76

  1,3-Oxazoles; Hydrogenated 1,3-oxazoles · CPC title