Regeneration of a hydrogen impurity trap using the heat exiting a hydride tank

Patent metadata

Field	Value
Publication number	US-2016206989-A1
Application number	US-201414916778-A
Country	US
Kind code	A1
Filing date	Aug 8, 2015
Priority date	Sep 6, 2013
Publication date	Jul 21, 2016
Grant date	—

Abstract

The storing and destocking of hydrogen in a hydride tank ( 10 ) comprises purification performed in at least one trap ( 1, 1 A, 1 B) filtering the impurities contained in the hydrogen entering the tank to be stored and regeneration of said at least one trap, using the heat carried by the hydrogen exiting the tank after it has been destocked.

First claim

1 . Process for storing and destocking hydrogen in a hydride tank, comprising:
purifying hydrogen from impurities, the purifying being performed on at least one trap that filters the impurities contained in the hydrogen entering the tank in order to be stored, and regenerating said at least one trap, using the heat carried by the hydrogen exiting the tank after its destocking.

2 . The process according to claim 1 , wherein the regeneration is stopped after a predefined time of performing the regeneration or when the moisture content of the stream of hydrogen exiting said at least one trap is below a predefined threshold.

3 . The process according to claim 1 , comprising the cycle of the following successive actions:
said purification, absorbing, by the hydrides of the tank, the purified hydrogen exiting said at least one trap, desorption of desorbing the hydrogen by hydrides of the tank, said regeneration in which the heat carried out of the tank by the hydrogen destocked at the time of the desorption is used to heat the material of said at least one trap (1) that is capable of reversibly retaining during the purification the impurities contained in the hydrogen prior to said absorption.

4 . The process according to claim 3 , wherein the regeneration comprises exchanging heat between all or part of the stream of hydrogen which has undergone said desorption and said material of the trap.

5 . The process according to claim 3 , wherein the regeneration comprises evacuating from the trap the impurities filtered and retained beforehand by said material.

6 . The process according to claim 5 , wherein the regeneration comprises:
separating a total stream of hydrogen which has undergone said desorption into first and second separate streams, using only said first stream to perform said evacuation, and exchanging heat between only said second stream and said material so that the heat generated during the desorption and carried by said second stream is used to heat said material in a manner allowing said evacuation to be performed by the first stream.

7 . The process according to claim 6 , wherein said using only said first stream comprises flushing said material with said first stream with direct contact with said material.

8 . The process according to claim 6 , comprising expelling said first stream and the impurities released from said material during said evacuating to the external atmosphere, performed after said evacuation.

9 . The process according to claim 6 , comprising cooling said first stream and the impurities released from said material during said evacuation to condense the liquid water, followed by mixing said first cooled stream and said second stream.

10 . The process according to claim 5 , wherein the regeneration comprises:
supplying a stream of neutral gas, originating from a source of neutral gas, using said stream of neutral gas to perform said evacuation, and exchanging heat between the total stream of hydrogen that has undergone said desorption and said material so that the heat generated during the desorption and carried by said total stream is used to heat said material in a manner allowing said evacuation to be performed.

11 . The process according to claim 10 , wherein said using said stream of neutral gas comprises flushing said material with said stream of neutral gas with direct contact with said material and said process comprises expelling said stream of neutral gas and the impurities released from said material during said evacuating to the external atmosphere, performed after said evacuation.

12 . The process according to claim 3 , wherein the cycle comprises, after the regeneration, cooling said at least one trap, performed before performing a following cycle.

13 . The process according to claim 12 , wherein said cooling said at least one trap comprises the following successive actions:
cooling the hydrogen exiting the reactor after the desorption, performed on a cooling element, exchanging heat between the hydrogen which has undergone said cooling and said material of said at least one trap, so that the hydrogen takes heat from said material, and evacuating from said at least one trap heat taken from said material during said heat exchange, performed by evacuating from said at least one trap the hydrogen that has undergone said heat exchange.

14 . The process according to claim 12 , wherein said purification is performed alternately on first and second different traps operating synchronously so that the cooling of the first trap is performed during the purification performed by the second trap and so that the cooling of the second trap is performed during the purification performed by the first trap.

15 . Installation for storing and destocking hydrogen, comprising:
a hydride tank in which hydrogen enters to be stored and from which the hydrogen exits to be destocked, at least one trap for filtering out impurities contained in the hydrogen entering the tank to be stored, and at least one of (i) software and (ii) hardware which perform a process according to claim 1 , including a device which ensures that the regeneration of said at least one trap uses the heat carried by the hydrogen exiting the tank after it has been destocked.

16 . The installation according to claim 15 , wherein said at least one trap comprises a material that is capable of reversibly retaining the impurities contained in the hydrogen prior to storage of said hydrogen in the tank and wherein said device comprises a heat exchange element for heat exchange between all or part of the total stream of hydrogen exiting the tank and said material of the trap.

17 . The installation according to claim 16 , wherein said device comprises elements for flushing said material with a gaseous stream with direct contact with said material so that said gaseous stream evacuates from the trap impurities filtered and retained beforehand by said material.

18 . The installation according to claim 17 , comprising elements for ensuring that said gaseous stream is constituted by a fraction of the total stream of hydrogen exiting the tank.

19 . The installation according to claim 15 , wherein the hybrid tank comprises magnesium-based hydrides.

20 . The process according to claim 4 , wherein the heat exchange is contactless.

Assignees

• Commissariat Energie Atomique

Inventors

• Chaise Albin

Classifications

• B01D53/0446

  Means for feeding or distributing gases · CPC title

• B01D2259/40052

  Recycled product or process gas · CPC title

• B01D2253/116

  Molecular sieves other than zeolites · CPC title

• C01B3/0005

  Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes · CPC title

• B01D2259/40088

  by heating · CPC title