Automotive compounds featuring low surface tack

Patent metadata

Field	Value
Publication number	US-2016200905-A1
Application number	US-201314651096-A
Country	US
Kind code	A1
Filing date	Dec 17, 2013
Priority date	Dec 19, 2012
Publication date	Jul 14, 2016
Grant date	—

Abstract

The present invention relates to a polymer composition comprising a heterophasic propylene copolymer, a mineral filler and a light stabilizers comprising a fatty acid derivative and a benzoate derivative. The polymer composition according to the present invention is applicable for automotive articles whereupon the undesired effect of stickiness is reduced significantly compared to automotive articles comprising conventional light stabilizers.

First claim

1 . Polymer Composition (C), comprising:
(a) a heterophasic propylene copolymer (HECO), (b) a mineral filler (F), (c) a 1,2,2,6,6-pentamethyl-4-piperidylester derivative of formula (I),

wherein
the molecular weight is below 1000 g/mol and R 1 is a linear or branched C 5 to C 25 alkyl residue, and
(d) a benzoate derivative of formula (II),

wherein
R 2 is a linear or branched C 5 to C 25 alkyl residue and
R 3 and R 4 are independently from each other Methyl, Ethyl, linear and/or branched C 3 to C 12 alkyl residues.

2 . Polymer composition (C) according to claim 1 , wherein R 1 of formula (I) is C 11 to C 18 alkyl and the benzoate derivative of formula (II) is n-hexadecyl-3,5-di-tert-butyl-4-hydroxybenzoate.

3 . Polymer composition (C) according to claim 1 , wherein said polymer composition (C) comprises:
(a) the heterophasic propylene copolymer (HECO) in an amount of 30 to 80 wt. %, (b) the mineral filler (F) in an amount no higher than 40 wt. %, and (c) the 1,2,2,6,6-pentamethyl-4-piperidylester derivative of formula (I) and the benzoate derivative of formula (II) combined in an amount of 0.01 to 5 wt. %, based on the total composition.

4 . Polymer composition (C) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises:
(a) a polypropylene matrix (M) being a propylene homopolymer or a propylene copolymer, and (b) an elastomeric propylene copolymer (E).

5 . Polymer composition (C) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has:
(a) a melt flow rate MFR 2 (230° C.), measured according to ISO 1133, in the range of 1.0 to 50 g/10 min, (b) a comonomer content in the range of 3.0 to 25 wt. %, based on the total heterophasic propylene copolymer (HECO), and (c) a xylene soluble content (XCS) in the range of 10 to 50 wt. %, based on the total heterophasic propylene copolymer (HECO).

6 . Polymer composition (C) according to claim 1 , wherein the matrix (M) of the heterophasic propylene copolymer (HECO) has a melt flow rate MFR 2 (230° C.), measured according to ISO 1133, in the range of 30 to 90 g/10 min.

7 . Polymer composition (C) according to claim 1 , wherein the mineral filler (F) is talc.

8 . Polymer composition (C) according to claim 1 , wherein said polymer composition comprises a polypropylene (PP), wherein said propylene (PP) has a melt flow rate MFR 2 (230° C.), measured according to ISO 1133, in the range of 3 to 50 g/10 min.

9 . Polymer composition (C) according to claim 1 , wherein said polymer composition comprises a high density polyethylene (HDPE), said high density polyethylene (HDPE) has:
(a) a melt flow rate MFR 2 (190° C.), measured according to ISO 1133, in the range of 2 to 30 g/10 min and/or (b) a density, measured according to ISO 1183, of at least 930 kg/m 3 .

10 .- 13 . (canceled)

14 . Automotive article comprising a polymer composition (C) according to claim 1 .

15 . Process for producing a polymer composition (C) according to claim 1 , comprising the step of mixing the heterophasic propylene copolymer (HECO), the mineral filler (F), the 1,2,2,6,6-pentamethyl-4-piperidylester derivative of formula (I), the benzoate derivative of formula (II) and optionally the high density polyethylene (HDPE) and/or the polypropylene (PP) in an extruder.

Assignees

• Borealis Ag

Inventors

• Kastner Erwin
• Lederer Klaus

Classifications

• C08L23/10 Primary

  Homopolymers or copolymers of propene · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08L2207/062

  HDPE · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08L23/14 Primary

  Copolymers of propene (C08L23/16 takes precedence) · CPC title