A polyolefin composition

Patent metadata

Field	Value
Publication number	US-2016194464-A1
Application number	US-201314653352-A
Country	US
Kind code	A1
Filing date	Dec 27, 2013
Priority date	Dec 27, 2012
Publication date	Jul 7, 2016
Grant date	—

Abstract

The instant invention provides a polyolefin composition suitable for packaging applications, films, multilayer structures and packaging devices made therefrom. The polyolefin composition according to the present invention comprises: an ethylene/α-olefin interpolymer composition comprising (a) from 50 to 75 percent by weight of a first ethylene/α-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cm 3 , a melt index (I 2 ) in the range of from 0.2 to 1 g/10 minutes, and (b) from 25 to 50 percent by weight of a second ethylene/α-olefin copolymer fraction, and wherein said ethylene/α-olefin interpolymer composition has a density in the range of 0.910 to 0.924 g/cm 3 , a melt index (I 2 ) in the range of from 0.5 to 2 g/10 minutes, a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5, a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (M w /M n ) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second and 190° C. in the range of from 6 to 43.

First claim

1 . A polyolefin composition suitable for packaging applications comprising:
an ethylene/α-olefin interpolymer composition comprising (a) from 50 to 75 percent by weight of a first ethylene/α-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cm 3 , a melt index (I 2 ) in the range of from 0.2 to 1 g/10 minutes, and (b) from 25 to 50 percent by weight of a second ethylene/α-olefin copolymer fraction, wherein said ethylene/α-olefin interpolymer composition has a density in the range of 0.910 to 0.924 g/cm 3 , a melt index (I 2 ) in the range of from 0.5 to 2 g/10 minutes, a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5, a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (M w /M n ) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second and 190° C. in the range of from 6 to 43, wherein said ethylene/α-olefin interpolymer composition has at least 2 peaks on elution profile via crystallization elution fractionation (CEF) procedure, wherein each peak comprises at least 25 weight percent of the total area of the elution profile, wherein the separation of the 2 peak positions are in the range of from 20 to 40° C., wherein a higher elution temperature peak is at an elution temperature greater than 90° C., and wherein a lower elution temperature peak is at an elution temperature in the range of from 50 to 80° C., and wherein the width of the higher elution temperature peak at 50 percent peak height is less than 4° C., and wherein the width of the higher elution temperature peak at 10 percent peak height is less than 9° C., and wherein the width of the lower elution temperature peak at 50 percent peak height is less than 8° C., and wherein the width of the lower elution temperature peak at 10 percent peak height is less than 25° C.

2 . The polyolefin composition of claim 1 , wherein said ethylene/α-olefin interpolymer composition characterized by one or more of the followings:
a. has a vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene/α-olefin interpolymer composition; and/or
b. has a tan delta at 0.1 radian/second, determined at 190° C., in the range of from 6 to 43; and/or
c. has CDC in the range of from 50 to 500.

3 . The polyolefin composition of claim 1 further comprising one or more ethylene polymers, or one or more propylene based polymers, or combinations thereof.

4 . A film comprising the polyolefin composition of claim 1 .

5 . A sheet comprising the polyolefin composition of claim 1 .

6 . The polyolefin composition of claim 1 , wherein said polyolefin composition is characterized by at least two of the followings:
a. having a Dart impact A of at least 1000 g, measured according to ASTM D1709, when said polyolefin composition is formed into a monolayer blown film having a thickness of 1 mil; b. having a Dart impact B of at least 400 g, measured according to ASTM D1709, when said polyolefin composition is formed into a monolayer blown film having a thickness of 1 mil; and/or c. having a normalized machine direction Elmendorf tear of at least 250 g/mil, measured according to ASTM D1922, when said polyolefin composition is formed into a monolayer blown film having a thickness of 1 mil.

7 . The polyolefin composition of claim 6 , wherein said polyolefin composition further comprises 5 to 20 percent by weight of low density polyethylene (LDPE), and wherein the Dart Impact A is greater than 275 g, preferably greater than 300 g measured according to ASTM D1709, when said polyolefin composition is formed into a monolayer blown film having a thickness of 1 mil.

8 . A packaging device comprising the film of claim 4 .

Assignees

• Dow Global Technologies Llc

Inventors

• Demirors Mehmet
• Kapur Mridula
• Jian Pradeep
• Fontaine Philip P
• Ginger Douglas S
• Gillespie David T
• Bilgen Mustafa

Classifications

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L23/06

  Polyethylene · CPC title

• C08F2500/03

  Narrow molecular weight distribution, i.e. Mw/Mn < 3 · CPC title

• C08J2423/08

  Copolymers of ethene (C08J2423/16 takes precedence) · CPC title