Method and device for measuring unoccupied states of solid
US-9664564-B2 · May 30, 2017 · US
US2016187250A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016187250-A1 |
| Application number | US-201514922250-A |
| Country | US |
| Kind code | A1 |
| Filing date | Oct 26, 2015 |
| Priority date | Dec 25, 2014 |
| Publication date | Jun 30, 2016 |
| Grant date | — |
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An optical filter 4 is placed in an optical path between a light source unit 1 using a deep ultraviolet LED as a light source and a sample cell 2. The optical filter 4 is a shortpass filter that allows passage of light of a main peak located within a deep ultraviolet region while blocking light of an unwanted peak located within a visible region. The temporal change in the amount of light of the unwanted peak is considerably greater than that of the main peak. The optical filter 4 blocks the former light whose amount considerably changes with time. As a result, the influence of the noise and drift originating from the LED on the detection signal obtained in a detector 3 is dramatically reduced, so that the analytical accuracy is improved.
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1 . An optical analyzer for analyzing a target sample by casting light from a light source into or onto the sample and introducing light obtained from the sample in response to the cast light into a detector, wherein: a light-emitting semiconductor device is used as the light source and an optical filter is provided in an optical path from the light source to the detector, the optical filter blocking light within a range of wavelengths longer than a wavelength of a peak having a highest intensity in an emission spectrum of the light source, within a range of wavelengths shorter than the wavelength of the highest-intensity peak or within a range of wavelengths longer and shorter than the wavelength of the highest-intensity peak, and each of the ranges of wavelengths including a peak at which a temporal change in an amount of light is larger than that at the highest-intensity peak. 2 . The optical analyzer according to claim 1 , wherein: the optical filter has such a characteristic as to block light at a peak appearing within a range of wavelengths longer than the wavelength of the highest-intensity peak in the emission spectrum of the light source. 3 . The optical analyzer according to claim 1 , wherein: the optical filter has such a characteristic as to allow passage of light within a predetermined wavelength width centering on the wavelength of the highest-intensity peak and being narrower than a full width at half maximum of the highest-intensity peak and to block light within wavelength regions outside the aforementioned wavelength width. 4 . The optical analyzer according to claim 2 , wherein: the optical filter has such a characteristic as to allow passage of light within a predetermined wavelength width centering on the wavelength of the highest-intensity peak and being narrower than a full width at half maximum of the highest-intensity peak and to block light within wavelength regions outside the aforementioned wavelength width. 5 . An optical analyzer for analyzing a target sample by casting light from a light source into or onto the sample and introducing light obtained from the sample in response to the cast light into a detector, wherein: a light-emitting semiconductor device is used as the light source and an optical filter is provided in an optical path from the light source to the detector, the optical filter having such a characteristic as to allow passage of light having a wavelength within a range centering on a wavelength of a peak having a highest intensity in an emission spectrum of the light source and having an intensity equal to or higher than 70% of the highest intensity and to block passage of light having a wavelength outside the aforementioned range.
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