Hot Dip Galvanized and Galvannealed Steel Sheet Having Excellent Elongation Properties, And Method For Manufacturing The Same

Patent metadata

Field	Value
Publication number	US-2016186282-A1
Application number	US-201514757453-A
Country	US
Kind code	A1
Filing date	Dec 23, 2015
Priority date	Dec 24, 2014
Publication date	Jun 30, 2016
Grant date	—

Abstract

There is provided a hot-dip galvanized steel sheet and a hot-dip galvannealed steel sheet, which have excellent elongation properties, and methods for manufacturing the hot-dip galvanized steel sheet and the hot-dip galvannealed steel sheet. The present disclosure relates to a hot-dip galvanized steel sheet in which a hot-dip galvanized layer is formed on a surface of a base steel sheet, the hot-dip galvanized steel sheet having excellent elongation properties and being characterized by the composition and the microstructure thereof.

First claim

What is claimed is:

1 . A hot-dip galvanized steel sheet in which a hot-dip galvanized layer is formed on a surface of a base steel sheet, the hot-dip galvanized steel sheet having excellent elongation properties, wherein
the base steel sheet: contains 0.02-0.08% of carbon (C), 1.3-2.1% of manganese (Mn), 0.3% or less of silicon (Si) (excluding 0%), 1.0% or less of chromium (Cr) (excluding 0%), 0.1% or less of phosphorous (P) (excluding 0%), 0.01% or less of sulfur (S) (excluding 0%), 0.01% or less of nitrogen (N) (excluding 0%), 0.02-0.06% of aluminum (sol. Al), 0.2% or less of molybdenum (Mo) (excluding 0%), 0.003% or less of boron (B) (excluding 0%), and a remainder of Fe and other inevitable impurities, in wt %; has a microstructure including 90% or more of ferrite, and a remainder of martensite and 3% or less of bainite, as defined by Equation 1; contains a percentage of martensite (M %) having an average particle diameter of 5 μm or less occupying space in ferrite grain boundaries (including grain boundary triple points) of 90% or higher, as defined by Equation 2; and at ¼t based on the thickness (t) of the sheet, the ratio of a C concentration (a) in the ferrite phase to a C concentration (b) in the martensite phase, i.e., (a)/(b), is 0.7 or less, and the ratio of an Mn concentration (c) in the ferrite phase to an Mn concentration (d) in the martensite phase, i.e., (c)/(d), is 0.8 or less,
B (%)={ BA /( MA+BA )}×100  [Equation 1]

where BA is the area occupied by bainite, and MA is the area occupied by martensite,
M (%)={ M gD /( M gb +M in )}×100  [Equation 2]

where M gb is the amount of martensite in ferrite grain boundaries, and M in is the amount of martensite within ferrite grains, the martensite having an average particle diameter of 5 μm or less.

2 . The hot-dip galvanized steel sheet of claim 1 , wherein, in the base steel sheet, the ferrite phase has an average grain size of 4 μm or greater, and the area occupied by the ferrite phase having an average grain size of 7 μm or greater in the entire ferrite phase is 10% or higher.

3 . A hot-dip galvannealed steel sheet in which a hot-dip galvannealed layer is formed on a surface of abase steel sheet, the hot-dip galvannealed steel sheet having excellent elongation properties, wherein
the base steel sheet: contains 0.02-0.08% of carbon (C), 1.3-2.1% of manganese (Mn), 0.3% or less of silicon (Si) (excluding 0%), 1.0% or less of chromium (Cr) (excluding 0%), 0.1% or less of phosphorous (P) (excluding 0%), 0.01% or less of sulfur (S) (excluding 0%), 0.01% or less of nitrogen (N) (excluding 0%), 0.02-0.06% of aluminum (sol. Al), 0.2% or less of molybdenum (Mo) (excluding 0%), 0.003% or less of boron (B) (excluding 0%), and a remainder of Fe and other inevitable impurities, in wt %; has a microstructure including 90% or more of ferrite, and a remainder of martensite and 3% or less of bainite as defined by Equation 1; contains a percentage of martensite (M %) having an average particle diameter of 5 μm or less occupying space in ferrite grain boundaries (including grain boundary triple points) of 90% or higher, as defined by Equation 2; and at ¼t based on the thickness (t) of the sheet, the ratio of a C concentration (a) in the ferrite phase to a C concentration (b) in the martensite phase, i.e., (a)/(b), is 0.7 or less, and the ratio of an Mn concentration (c) in the ferrite phase to an Mn concentration (d) in the martensite phase, i.e., (c)/(d), is 0.8 or less,
B (%)={ BA /( MA+BA )}×100  [Equation 1]

where BA is the area occupied by bainite, and MA is the area occupied by martensite,
M (%)={ M gb /( M gb +M in )}×100  [Equation 2]

where M gb is the amount of martensite in ferrite grain boundaries, and M in is the amount of martensite within ferrite grains, the martensite having an average particle diameter of 5 μm or less.

4 . The hot-dip galvannealed steel sheet of claim 3 , wherein, in the base steel sheet, the ferrite phase has an average grain size of 4 μm or greater, and the area occupied by the ferrite phase having an average grain size of 7 μm or greater in the entire ferrite phase is 10% or higher.

5 . A method for manufacturing a hot-dip galvanized steel sheet having excellent elongation properties, the method comprising:
preparing a steel slab having compositional components of claim 1 , and thereafter reheating the steel slab; performing finish hot-rolling on the reheated steel slab in a temperature range of Ar3+50° C.-950° C., and thereafter coiling the finish hot-rolled steel sheet at 450-700° C.; performing cold-rolling on the coiled hot-rolled steel sheet with a reduction ratio of 40-80%, and thereafter performing continuous annealing on the cold-rolled steel sheet in a temperature range of 760-850° C.; performing a first cooling on the continuous annealed steel sheet to a temperature range of 630-670° C. at an average cooling rate of 2-8° C./s, and thereafter performing a second cooling on the first cooled steel sheet to a temperature range of Ms+20° C. to Ms+50° C. at an average cooling rate of 3-10° C./s; and performing hot-dip galvanizing on the second cooled steel sheet in a temperature range of 440-480° C., and thereafter cooling the hot-dip galvanized steel sheet to a temperature of Ms-100° C. or lower at an average cooling rate of 4° C./s or higher.

6 . The method of claim 5 , wherein a base steel sheet of the hot-dip galvanized steel sheet,
has a microstructure including 90% or more of ferrite, and a remainder of martensite and 3% or less of bainite, as defined by Equation 1; contains a percentage of martensite (M %) having an average particle diameter of 5 μm or less occupying space in ferrite grain boundaries (including grain boundary triple points) of 90% or higher, as defined by Equation 2; and at ¼t based on the thickness (t) of the sheet, the ratio of a C concentration (a) in the ferrite phase to a C concentration (b) in the martensite phase, i.e., (a)/(b), is 0.7 or less, and the ratio of an Mn concentration (c) in the ferrite phase to an Mn concentration (d) in the martensite phase, i.e., (c)/(d), is 0.8 or less,
B (%)={ BA /( MA+BA )}×100  [Equation 1]

where BA is the area occupied by bainite, and MA is the area occupied by martensite,
M (%)={ M gb /( M gb +M in )}×100  [Equation 2]

where M gb is the amount of martensite in ferrite grain boundaries, and M in is the amount of martensite within ferrite grains, the martensite having an average particle diameter of 5 μm or less.

7 . The method of claim 5 , wherein, in abase steel sheet of the hot-dip galvanized steel sheet, the ferrite phase has an average grain size of 4 μm or greater, and the area occupied by the ferrite phase having an average grain size of 7 μm or greater in the entire ferrite phase is 10% or higher.

Assignees

• Posco

Inventors

• Han Sang Ho
• Han Seong Ho

Classifications

• C21D8/02

  during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title

• C23C30/005

  on hard metal substrates · CPC title

• C22C38/001

  containing N · CPC title

• C21D8/0226

  Hot rolling · CPC title

• C23C28/021

  including at least one metal alloy layer · CPC title