Method for producing methacrylic polymer composition, and molded article

Patent metadata

Field	Value
Publication number	US-2016185884-A1
Application number	US-201314649076-A
Country	US
Kind code	A1
Filing date	Nov 29, 2013
Priority date	Dec 3, 2012
Publication date	Jun 30, 2016
Grant date	—

Abstract

A method for producing a methacrylic polymer composition, which comprises
a first polymerization step wherein a raw material composition A comprising a raw material monomer A containing no less than 50% by weight of methyl methacrylate, a polymerization initiator A, and a chain transfer agent A is supplied into a first complete mixing type reactor through a supply port of the reactor, and the raw material composition A is subjected to a continuous bulk polymerization in the first complete mixing type reactor, and a resulting intermediate composition is withdrawn through an effluent port of the first complete mixing type reactor; and a second polymerization step wherein a raw material composition B comprising a raw material monomer B containing no less than 50% by weight of methyl methacrylate, a polymerization initiator B, and a chain transfer agent B, and the intermediate composition withdrawn in the first polymerization step are supplied into a second complete mixing type reactor through a supply port of the reactor, and the raw material composition B and the intermediate composition are further subjected to a continuous bulk polymerization in the second complete mixing type reactor, and a resulting methacrylic polymer composition is withdrawn through an effluent port of the second complete mixing type reactor;

wherein the formulae (I), (II), (III), (IV) and (V) are satisfied.

First claim

1 . A method for producing a methacrylic polymer composition, which comprises
a first polymerization step wherein a raw material composition A comprising a raw material monomer A containing no less than 50% by weight of methyl methacrylate, a polymerization initiator A, and a chain transfer agent A is supplied into a first complete mixing type reactor through a supply port of the reactor, and the raw material composition A is subjected to a continuous bulk polymerization in the first complete mixing type reactor, and a resulting intermediate composition is withdrawn through an effluent port of the first complete mixing type reactor; and a second polymerization step wherein a raw material composition B comprising a raw material monomer B containing no less than 50% by weight of methyl methacrylate, a polymerization initiator B, and a chain transfer agent B, and the intermediate composition withdrawn in the first polymerization step are supplied into a second complete mixing type reactor through a supply port of the reactor, and the raw material composition B and the intermediate composition are further subjected to a continuous bulk polymerization in the second complete mixing type reactor, and a resulting methacrylic polymer composition is withdrawn through an effluent port of the second complete mixing type reactor; wherein the following formulae (I), (II), (III), (IV) and (V) are satisfied:
120≦ T 1≦160  (I)

140≦ T 2≦180  (II)

20≦ T 2− T 1≦60  (III)

1.7≦[ S 2]/[ S 1]  (IV)

1≦ Q 1/ Q 2≦50  (V)

wherein T1 is a temperature (° C.) in the first complete mixing type reactor in the first polymerization step, T2 is a temperature (° C.) in the second complete mixing type reactor in the second polymerization step, [S1] is a concentration (% by weight) of the chain transfer agent A in the raw material composition A supplied into the first complete mixing type reactor, [S2] is a concentration (% by weight) of the chain transfer agent B relative to the total amount of the raw material composition B and the intermediate composition, both of which are supplied into the second complete mixing type reactor, Q1 is a flow rate (cm 3 /min) of the intermediate composition supplied into the second complete mixing type reactor, and Q2 is a flow rate (cm 3 /min) of the raw material composition B supplied in the second complete mixing type reactor.

2 . The method according to claim 1 , wherein the following formulae (VI) and (VII) are further satisfied:
40≦ x≦ 60  (VI)
θ1+θ2≦180  (VII)
wherein
x is a polymerization conversion (% by weight) of the methacrylic polymer composition withdrawn through the effluent port of the second complete mixing type reactor,
θ1 is an average residence time (min) in the first complete mixing type reactor in the first polymerization step, and
θ2 is an average residence time (min) in the second complete mixing type reactor in the second polymerization step.

3 . The method according to claim 1 , wherein each of the effluent ports of the first and second complete mixing type reactors is located on a top of each of the reactors.

4 . The method according to claim 1 , wherein the continuous bulk polymerizations in the first polymerization step and the second polymerization step are conducted under adiabatic conditions.

5 . A molded article prepared from a methacrylic polymer composition produced by the method according to claim 1 .

6 . A molded article prepared from a methacrylic polymer composition produced by the method according to claim 2 .

7 . A molded article prepared from a methacrylic polymer composition produced by the method according to claim 3 .

8 . A molded article prepared from a methacrylic polymer composition produced by the method according to claim 4 .

Assignees

• Sumitomo Chemical Co

Inventors

• Yamamori Akihiro
• Wake Takao
• Yamazaki Kazuhiro

Classifications

• C08F20/14 Primary

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F2/001

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title

• C08F2/02

  Polymerisation in bulk · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title