Method of manufacturing liquid crystal display
US-2015346559-A1 · Dec 3, 2015 · US
US2016178969A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016178969-A1 |
| Application number | US-201414907872-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jul 24, 2014 |
| Priority date | Jul 30, 2013 |
| Publication date | Jun 23, 2016 |
| Grant date | — |
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The present invention provides a method for manufacturing a liquid crystal display device including a photo-alignment film and capable of sufficiently improving the display quality. The method for manufacturing a liquid crystal display device of the present invention is a method for manufacturing a liquid crystal display device including a photo-alignment film. The method for manufacturing a liquid crystal display device successively includes a step (1) of forming on a substrate a film from a photo-alignment-film material that contains a solvent and a polymer including a photo-functional group that is capable of causing at least one chemical reaction selected from the group consisting of photodimerization, photoisomerization, and photo-Fries rearrangement; a step (2) of pre-heating the film to evaporate the solvent; a step (3) of irradiating the pre-heated film with polarized light; and a step (4) including an operation of main-heating the polarized-light-irradiated film at multiple temperatures from a lower temperature to a higher temperature. The liquid crystal display device is of an in-plane switching mode or a fringe field switching mode in each of which a pre-tilt angle is substantially 0°.
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1 . A method for manufacturing a liquid crystal display device including a photo-alignment film, the method for manufacturing a liquid crystal display device successively comprising: a step (1) of forming on a substrate a film from a photo-alignment-film material that contains a solvent and a polymer including a photo-functional group that is capable of causing at least one chemical reaction selected from the group consisting of photodimerization, photoisomerization, and photo-Fries rearrangement; a step (2) of pre-heating the film to evaporate the solvent; a step (3) of irradiating the pre-heated film with polarized light; and a step (4) including an operation of main-heating the polarized-light-irradiated film at multiple temperatures from a lower temperature to a higher temperature, the liquid crystal display device being of an in-plane switching mode or a fringe field switching mode in each of which a pre-tilt angle is substantially 0°. 2 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the main heating in the step (4) is performed at a temperature of 90° C. or higher. 3 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the pre-heating in the step (2) is performed at a temperature of 90° C. or lower. 4 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the liquid crystal display device aligns liquid crystal molecules having negative anisotropy of dielectric constant by the photo-alignment film. 5 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the main heating in the step (4) includes an operation performed so as to include multiple temperature-constant periods at different temperatures. 6 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the main heating in the step (4) is performed at a temperature of 90° C. or higher and 140° C. or lower for one minute or longer, and at a temperature of 180° C. or higher. 7 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the main heating in the step (4) is performed using multiple heaters set to different temperatures. 8 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the main heating in the step (4) is performed using a single heater and the temperature of the heater is successively changed to a different temperature. 9 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the main heating in the step (4) is performed by transferring the substrate in a heater that includes a region having a temperature gradient. 10 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the photo-functional group is at least one functional group selected from the group consisting of a cinnamate group, a chalcone group, a coumarin group, a stilbene group, a phenyl ester group, and an azobenzene group. 11 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the polymer including the photo-functional group includes a backbone that has at least one structure selected from the group consisting of polyamic acids, polyimides, acrylic structures, methacrylic structures, maleimide, and polysiloxanes. 12 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the photo-alignment-film material further contains a polyamic acid. 13 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein the photo-functional group is capable of causing at least photodimerization, the step (4) includes two main heating operations at different temperatures and, between the first and second main heating operations, a step (4a) of irradiating the film after the first main heating with light. 14 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein a material of the polymer contained in the photo-alignment-film material includes in a main chain or a side chain a structure represented by any of the following formulas (1) to (3): wherein X represents a direct bond, O, COO, OCO, CO, or C≡C. 15 . The method for manufacturing a liquid crystal display device according to claim 1 , wherein a material of the polymer contained in the photo-alignment-film material includes one or both of a carboxyl group and an amide group in a main chain or a side chain.
by light irradiation, e.g. linearly polarised light photo-polymerisation · CPC title
by organic films, e.g. polymeric films · CPC title
for fringe field switching [FFS] where the common electrode is not patterned · CPC title
for applying an electric field parallel to the substrate, i.e. in-plane switching [IPS] · CPC title
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