Detecting stannous ions

Patent metadata

Field	Value
Publication number	US-2016178595-A1
Application number	US-201414580497-A
Country	US
Kind code	A1
Filing date	Dec 23, 2014
Priority date	Dec 23, 2014
Publication date	Jun 23, 2016
Grant date	—

Abstract

A method of detecting stannous ions that includes providing a zincon-containing indicator having a colour, contacting the indicator with a sample, and detecting any resulting change in the colour of the indicator, wherein a change in the colour of the indicator from the colour to colourless indicates that stannous ions are present in the sample. The method is useful for the analysis of oral care compositions. Also provided is the use of zinc on as an indicator for detecting stannous ions.

First claim

1 . A method of detecting stannous ions in a sample, which method comprises:
(i) providing an amount of an indicator comprising zincon or a salt thereof having a UV/visible absorbance spectrum; (ii) contacting the indicator with a sample such that if stannous ions are present in the sample, stannous ions react with the indicator; and (iii) detecting a change in the UV/visible absorbance spectrum of the indicator to determine whether stannous ions are present in the sample.

2 . The method of claim 1 , wherein step (iii) comprises detecting a change in the colour of the indicator.

3 . The method of claim 1 , wherein the sample comprises an oral care composition.

4 . The method of claim 3 , wherein the oral care composition comprises a toothpaste.

5 . The method of claim 1 , wherein step (ii) comprises forming a liquid comprising the indicator, the sample, and water.

6 . The method of claim 5 , wherein the amount of the indicator present in the liquid is no greater than 500 ppm by weight of the liquid.

7 . The method of claim 6 , wherein the amount of the indicator present in the liquid is in the range of 30 to 60 ppm by weight of the liquid.

8 . The method of claim 5 , comprising titrating the sample with a solution of the indicator.

9 . The method of claim 5 , wherein the Liquid has a pH in the range of 5 to 10.

10 . The method of claim 9 , wherein the liquid has a pH in the range of 6.3 to 7.3.

11 . The method of claim 9 , wherein the liquid has a pH in the range 7 to 10.

12 . The method of claim 11 , wherein the sample includes zinc ions.

13 . The method of claim 12 , wherein stannous ions are present in the sample, and wherein the method further comprises:
oxidizing the stannous ions after step (iii) to form stannic ions; and allowing the zinc ions to react with the indicator.

14 . The method of claim 13 , subsequently comprising measuring the concentration of the zinc by colourimetry.

15 - 17 . (canceled)

Assignees

• Colgate Palmolive Co

Inventors

• Jaracz Stanislav
• Prencipe Michael

Classifications

• G01N33/20 Primary

  Metals · CPC title

• G01N21/78 Primary

  producing a change of colour · CPC title

• G01N21/77

  by observing the effect on a chemical indicator · CPC title

• G01N21/79

  Photometric titration · CPC title

• A61Q11/00

  Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses · CPC title