Method for producing fluorine-containing olefin

Patent metadata

Field	Value
Publication number	US-2016176791-A1
Application number	US-201615056288-A
Country	US
Kind code	A1
Filing date	Feb 29, 2016
Priority date	Sep 6, 2013
Publication date	Jun 23, 2016
Grant date	—

Abstract

A method for producing at least one compound selected from the group consisting of a compound represented by the following formula (10), a compound represented by the following formula (11), a compound represented by the following formula (12), and a compound represented by the following formula (13), which the method containing reacting a compound represented by the following formula (2) with a compound represented by the following formula (7), in the presence of at least one compound selected from the group consisting of a compound represented by the following formula (1), a compound represented by the following formula (3), a compound represented by the following formula (4), a compound represented by the following formula (8), and a compound represented by the following formula (9).

First claim

1 . A method for producing at least one compound selected from the group consisting of a compound represented by the following formula (3), a compound represented by the following formula (4), a compound represented by the following formula (5), and a compound represented by the following formula (6), which the method comprising reacting a compound represented by the following formula (1) with a compound represented by the following formula (2):

in the formulae, the symbols represent the following meanings:
[L] represents a ligand;
A 1 and A 2 each independently represent a functional group selected from the group consisting of the following functional group (i), functional group (ii), functional group (iii), and functional group (iv), and these may bond to each other to form a ring, and in the case where one of A 1 and A 2 is a halogen atom, the other is a functional group selected from the group consisting of the functional group (i), the functional group (iii) and the functional group (iv); and
X 1 and X 2 each independently represent a functional group selected from the group consisting of the following functional group (i), the functional group (ii), functional group (v) and functional group (vi), and these may bond to each other to form a ring, and in the case where one of X 1 and X 2 is a hydrogen atom, the other is a functional group selected from the group consisting of the functional group (ii), the functional group (v) and the functional group (vi):
Functional group (i): a hydrogen atom;
Functional group (ii): a halogen atom;
Functional group (iii): a monovalent hydrocarbon group having a carbon number of from 1 to 20;
Functional group (iv): a monovalent hydrocarbon group having a carbon number of from 1 to 20 and containing one or more atoms selected from the group consisting of a halogen atom, an oxygen atom, a nitrogen atom, a sulfur atom, a phosphorus atom, and a silicon atom;
Functional group (v): a functional group selected from the group consisting of an alkyl group having a carbon number of from 1 to 12, an alkoxy group having a carbon number of from 1 to 12, an aryl group having a carbon number of from 5 to 20, an aryloxy group having a carbon number of from 5 to 20, a (per)halogenated alkyl group having a carbon number of from 1 to 12, a (per)halogenated alkoxy group having a carbon number of from 1 to 12, a (per)halogenated aryl group having a carbon number of from 5 to 20, and a (per)halogenated aryloxy group having a carbon number of from 5 to 20; and
Functional group (vi): the functional group (v) containing one or more atoms selected from the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, a phosphorus atom, and a silicon atom.

2 . A method for producing at least one compound selected from the group consisting of a compound represented by the following formula (8), a compound represented by the following formula (9), a compound represented by the following formula (10), and a compound represented by the following formula (11), which the method comprising reacting a compound represented by the following formula (3) with a compound represented by the following formula (7):

in the formulae, the symbols represent the following meanings:
[L] represents a ligand;
A 3 to A 6 each independently represent a functional group selected from the group consisting of the following functional group (i), functional group (ii), functional group (iii), and functional group (iv), A 3 and A 4 may bond to each other to form a ring, A 5 and A 6 may bond to each other to form a ring, in the case where one of A 3 and A 4 is a halogen atom, the other is a functional group selected from the group consisting of the functional group (i), the functional group (iii) and the functional group (iv), and in the case where one of A 5 and A 6 is a halogen atom, the other is a functional group selected from the group consisting of the functional group (i), the functional group (iii) and the functional group (iv):
Functional group (i): a hydrogen atom;
Functional group (ii): a halogen atom;
Functional group (iii): a monovalent hydrocarbon group having a carbon number of from 1 to 20; and
Functional group (iv): a monovalent hydrocarbon group having a carbon number of from 1 to 20 and containing one or more atoms selected from the group consisting of a halogen atom, an oxygen atom, a nitrogen atom, a sulfur atom, a phosphorus atom, and a silicon atom.

3 . A method for producing at least one compound selected from the group consisting of a compound represented by the following formula (8), a compound represented by the following formula (9), a compound represented by the following formula (12), and a compound represented by the following formula (13), which the method comprising reacting a compound represented by the following formula (4) with a compound represented by the following formula (7):

in the formulae, the symbols represent the following meanings:
[L] represents a ligand;
A 3 to A 6 each independently represent a functional group selected from the group consisting of the following functional group (i), functional group (ii), functional group (iii), and functional group (iv), A 3 and A 4 may bond to each other to form a ring, A 5 and A 6 may bond to each other to form a ring, in the case where one of A 3 and A 4 is a halogen atom, the other is a functional group selected from the group consisting of the functional group (i), the functional group (iii) and the functional group (iv), and in the case where one of A 5 and A 6 is a halogen atom, the other is a functional group selected from the group consisting of the functional group (i), the functional group (iii) and the functional group (iv); and
X 1 and X 2 each independently represent a functional group selected from the group consisting of the following functional group (i), functional group (ii), functional group (v), and functional group (vi), and these may bond to each other to form a ring, and in the case where one of X 1 and X 2 is a hydrogen atom, the other is a functional group selected from the group consisting of the functional group (ii), the functional group (v) and the functional group (vi):
Functional group (i): a hydrogen atom;
Functional group (ii): a halogen atom;
Functional group (iii): a monovalent hydrocarbon group having a carbon number of from 1 to 20;
Functional group (iv): a monovalent hydrocarbon group having a carbon number of from 1 to 20 and containing one or more atoms selected from the group consisting of a halogen atom, an oxygen atom, a nitrogen atom, a sulfur atom, a phosphorus atom, and a silicon atom;
Functional group (v): a functional group selected from the group consisting of an alkyl group having a carbon number of from 1 to 12, an alkoxy group having a carbon number of from 1 to 12, an aryl group having a carbon number of from 5 to 20, an aryloxy group having a carbon number of from 5 to 20, a (per)halogenated alkyl group having a carbon number of from 1 to 12, a (per)halogenated alkoxy group having a carbon number of from 1 to 12, a (per)halogenated aryl group having a carbon number of from 5 to 20, and a (per)halogenated aryloxy group having a carbon number of from 5 to 20; and
Functional group (vi): the functional group (v) containing one or more atoms selected from the group consisting of an oxygen atom,

Assignees

• Asahi Glass Co Ltd

Inventors

• Takahira Yusuke

Classifications

• C07C41/30 Primary

  by increasing the number of carbon atoms, e.g. by oligomerisation · CPC title

• C07C41/22

  by introduction of halogens; by substitution of halogen atoms by other halogen atoms · CPC title

• C07C17/37

  by disproportionation of halogenated hydrocarbons · CPC title

• B01J31/2404

  Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring · CPC title

• C07C17/272

  by addition reactions · CPC title