Multilayer molding

Patent metadata

Field	Value
Publication number	US-2016176170-A1
Application number	US-201414909290-A
Country	US
Kind code	A1
Filing date	Aug 7, 2014
Priority date	Aug 9, 2013
Publication date	Jun 23, 2016
Grant date	—

Abstract

A resin-made multilayer molding includes two or more resin layers, at least one resin layer is configured from a mixed resin (B) containing, at a ratio (C)/(D)=99/1 to 10/90 by weight, a polyamide resin (C) obtained by polymerizing a diamine component containing 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component containing 70 mol % or more of adipic acid, and a polyester resin (D) containing a dicarboxylic acid unit and a diol unit, 1-80 mol % of the diol unit having a cyclic acetal skeleton; and at least one resin layer in contact with a layer configured from the mixed resin (B) is configured from a resin containing 70 wt % or more of a thermoplastic polyester resin (A) obtained by polymerizing a dicarboxylic acid component containing 80 mol % or more of terephthalic acid and a diol component containing 80 mol % or more of ethylene glycol.

First claim

1 . A resin-made multilayer molding including two or more resin layers, wherein at least one resin layer of the multilayer molding is configured from a mixed resin (B) containing, at a ratio (C)/(D)=99/1 to 10/90 by weight, a polyamide resin (C) obtained by polymerizing a diamine component containing 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component containing 70 mol % or more of adipic acid, and a polyester resin (D) containing a dicarboxylic acid unit and a diol unit, 1 to 80 mol % of the diol unit having a cyclic acetal skeleton; and at least one resin layer in contact with a layer configured from the mixed resin (B) is configured from a resin containing 70 wt % or more of a thermoplastic polyester resin (A) obtained by polymerizing a dicarboxylic acid component containing 80 mol % or more of terephthalic acid and a diol component containing 80 mol % or more of ethylene glycol.

2 . The resin-made multilayer molding according to claim 1 , which includes three or more resin layers, wherein the resin layers forming both the surfaces of the multilayer molding are configured from a resin containing 70 wt % or more of a thermoplastic polyester resin (A) obtained by polymerizing a dicarboxylic acid component containing 80 mol % or more of terephthalic acid and a diol component containing 80 mol % or more of ethylene glycol.

3 . The multilayer molding according to claim 1 , wherein the diol unit having the cyclic acetal skeleton of the polyester resin (D) is a diol unit derived from a diol represented by general formula (1):

wherein R 1 and R 2 each independently represent a divalent hydrocarbon group selected from the group consisting of a C 1-10 divalent aliphatic hydrocarbon group, a C 3-10 divalent alicyclic hydrocarbon group and a C 6-10 divalent aromatic hydrocarbon group,
or general formula (2):

wherein: R 1 is the same as above; and R 3 represents a hydrocarbon group selected from the group consisting of a C 1-10 aliphatic hydrocarbon group, a C 3-10 alicyclic hydrocarbon group and a C 6-10 aromatic hydrocarbon group.

4 . The multilayer molding according to claim 1 , wherein the diol unit having the cyclic acetal skeleton of the polyester resin (D) is a diol unit derived from 3,9-bis(1,1-dimethyl-2-hydroxyethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane or a diol unit derived from 5-methylol-5-ethyl-2-(1,1-dimethyl-2-hydroxyethyl)-1,3-dioxane.

5 . The multilayer molding according to claim 1 , wherein the diol unit other than the diol unit having the cyclic acetal skeleton of the polyester resin (D) is a diol unit derived from at least one diol selected from the group consisting of ethylene glycol, diethylene glycol, trimethylene glycol, 1,4-butanediol and 1,4-cyclohexanedimethanol.

6 . The multilayer molding according to claim 1 , wherein 1 to 100 mol % of the dicarboxylic acid unit of the polyester resin (D) is a unit derived from a dicarboxylic acid having a benzene skeleton and 0 to 99 mol % of the dicarboxylic acid unit of the polyester resin (D) is a unit derived from a dicarboxylic acid having a naphthalene skeleton.

7 . The multilayer molding according to claim 1 , wherein the dicarboxylic acid unit of the polyester resin (D) is a dicarboxylic acid unit derived from at least one dicarboxylic acid selected from the group consisting of terephthalic acid, isophthalic acid, 1,4-naphthalenedicarboxylic acid, 1,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid and 2,7-naphthalenedicarboxylic acid.

8 . The multilayer molding according to claim 1 , wherein the polyamide resin (C) is a solid phase polymerized polyamide resin obtained by melt-polycondensing the diamine component containing 70 mol % or more of m-xylylenediamine and the dicarboxylic acid component containing 70 mol % or more of adipic acid and further subjecting the obtained polyamide resin to solid phase polymerization.

9 . The multilayer molding according to claim 1 , wherein the mixed resin (B) further contains 0.01 to 0.10 wt % of at least one metal element selected from the group consisting of a transition metal belonging to Group VIII of the periodic table, manganese, copper and zinc.

10 . The multilayer molding according to claim 1 , wherein the weight ratio of the mixed resin (B) relative to the total weight of the multilayer molding is 1 to 30 wt %.

11 . The multilayer molding according to claim 1 , comprising: an outer surface layer; an inner surface layer; and at least one core layer positioned between the outer surface layer and the inner surface layer, which is produced using an injection molding machine having a surface layer-side injection cylinder and a core side injection cylinder, and which is a hollow vessel obtained by blow-molding a multilayer parison, which is obtained by injecting the resin containing 70 wt % or more of the thermoplastic polyester resin (A) from the surface layer-side injection cylinder to form the outer surface layer and the inner surface layer and injecting the mixed resin (B) from the core side injection cylinder to form the at least one core layer.

12 . The multilayer molding according to claim 11 , which is a hollow vessel obtained by blow-molding a parison having a three-layer structure, which is formed by filling a mold cavity by: injecting the resin containing 70 wt % or more of the thermoplastic polyester resin (A) from the surface layer-side injection cylinder; then injecting the mixed resin (B) from the core side injection cylinder and injecting the thermoplastic polyester resin (A) from the surface layer-side injection cylinder at the same time; and then injecting the thermoplastic polyester resin (A) from the surface layer-side injection cylinder.

13 . The multilayer molding according to claim 11 , which is a hollow vessel obtained by blow-molding a parison having a five-layer structure, which is formed by filling a mold cavity by: injecting the resin containing 70 wt % or more of the thermoplastic polyester resin (A) from the surface layer-side injection cylinder; then injecting the mixed resin (B) from the core side injection cylinder; and then injecting the thermoplastic polyester resin (A) from the surface layer-side injection cylinder.

14 . The multilayer molding according to claim 11 , which is a hollow vessel obtained by heating the surface of the parison to 80 to 120° C., followed by blow molding thereof.

15 . The multilayer molding according to claim 1 , comprising: both surface layers; and at least one core layer positioned between the both surface layers, which is produced using a multilayer sheet-forming machine having at least one surface layer-side extrusion cylinder and at least one core side extrusion cylinder, and which is a multilayer sheet having a thickness of 100 to 2000 μm obtained by: extruding the resin containing 70 wt % or more of the thermoplastic polyester resin (A) from the surface layer-side extrusion cylinder, or the surface layer-side extrusion cylinder and at least one of the core side extrusion cylinder to form a resin layer; and extruding the mixed resin (B) from at least one of the core side extrusion cylinder to form the at least one core layer in contact with the resin layer made of resin containing the thermoplastic polyester resin (A).

16 . The multilayer molding according to claim 15 , which is a multilayer sheet having a three-layer structure obtained by extruding the resin containing 70

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Sato Kazunobu
• Iwasaki Atsuko
• Miyabe Takanori
• SUNADA Tomoe
• ARAI Hirokatsu

Classifications

• B29C49/0411

  Means for defining the wall or layer thickness · CPC title

• B29C49/16

  using pressure difference {for pre-stretching}, e.g. pre-blowing · CPC title

• B29C49/04

  Extrusion blow-moulding · CPC title

• B29C49/22

  using multilayered preforms or parisons · CPC title

• B32B2250/24

  All layers being polymeric · CPC title