Crosslinkable coating composition and method of producing the same

Patent metadata

Field	Value
Publication number	US-2016160076-A1
Application number	US-201615042036-A
Country	US
Kind code	A1
Filing date	Feb 11, 2016
Priority date	Jun 18, 2013
Publication date	Jun 9, 2016
Grant date	—

Abstract

The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.

First claim

1 - 10 . (canceled)

11 . A process for producing a crosslinkable coating composition comprising:
a. selecting one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups, and wherein said one or more polyacids comprise less than 75 percent by weight of one or more 1,2-phthalic acid and derivatives thereof, and wherein the condensation reaction product has (i) at least 20 percent by weight a fatty acid component, (ii) a hydroxyl number of greater than 100 mg KOH/g, and wherein said one or more polycarbamates are substantially isocyanate free; b. selecting one or more crosslinking agents, wherein said one or more crosslinking agents are polyaldehydes; c. selecting one or more acid catalysts; d. optionally selecting one or more organic solvents; e. contacting a, c, and d first to produce a first component; f. contacting said first component with b; and g. thereby producing said crosslinkable coating composition, wherein said crosslinkable coating composition has methyl ethyl ketone (MEK) (measured after 24 hour of ambient cure) of 30 or greater, and a pendulum hardness (measured after 24 hour of ambient cure) in the range greater than 60.

12 . A process for producing a crosslinkable coating composition comprising:
a. selecting one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups, and wherein said one or more polyacids comprise less than 75 percent by weight of one or more 1,2-phthalic acid and derivatives thereof, and wherein the condensation reaction product has (i) at least 20 percent by weight a fatty acid component, (ii) a hydroxyl number of greater than 100 mg KOH/g, and wherein said one or more polycarbamates are substantially isocyanate free; b. selecting one or more crosslinking agents, wherein said one or more crosslinking agents are polyaldehydes; c. selecting one or more acid catalysts; d. optionally selecting one or more organic solvents; e. contacting a, b, and d first to produce a first component; f. contacting said first component with c; and g. thereby producing said crosslinkable coating composition, wherein said crosslinkable coating composition has methyl ethyl ketone (MEK) (measured after 24 hour of ambient cure) of 30 or greater, and a pendulum hardness (measured after 24 hour of ambient cure) in the range greater than 60.

13 . The process for producing a crosslinkable coating composition of claim 11 , wherein the one or more units having 4 or more hydroxyl groups is one or more selected from the group consisting of pentaerythritol and dipentaerythritol.

14 . The process for producing a crosslinkable coating composition of claim 12 , wherein the one or more units having 4 or more hydroxyl groups is one or more selected from the group consisting of pentaerythritol and dipentaerythritol.

Assignees

• Dow Global Technologies Llc

Inventors

• Spilman Gary E
• Anderson Jeff R
• Argyropoulos John N
• Foley Paul

Classifications

• C09D167/00 Primary

  Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain (based on polyester-amides C09D177/12; based on polyester-imides C09D179/08); Coating compositions based on derivatives of such polymers · CPC title

• C09D179/00

  Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00 · CPC title

• C09D167/08

  Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids · CPC title

• C09D175/06 Primary

  from polyesters · CPC title