Epoxy resin compositions

Patent metadata

Field	Value
Publication number	US-2016159969-A1
Application number	US-201314907675-A
Country	US
Kind code	A1
Filing date	Jul 26, 2013
Priority date	Jul 26, 2013
Publication date	Jun 9, 2016
Grant date	—

Abstract

A novel modified epoxy compound that is capable of providing a coating composition with acceptable viscosity, short tack-free time and thy-hard time, and providing resultant coating films with good impact resistance; a process of preparing the modified epoxy compound; an epoxy resin composition comprising the modified epoxy compound; and a curable coating composition comprising the epoxy resin composition and a curing agent.

First claim

1 . A modified epoxy compound of Formula (I):

wherein each a is independently from 0 to 3; b is from 1 to 5; R 1 is a straight-chain or branched alkyl with 15 carbons containing 0 to 2 C═C bond(s); and R 2 is a straight-chain or branched alkyl with 15 carbons containing 0 to 3 C═C bond(s).

2 . The modified epoxy compound of claim 1 , wherein b is from 1 to 3.

3 . The modified epoxy compound of claim 1 , wherein R 1 is —C 15 H 25 —, —C 15 H 27 —, or —C 15 H 29 — group.

4 . A process of preparing the modified epoxy compound of claim 1 , comprising:
(i) modifying cardanol by a Friedel-Crafts reaction in the presence of an acid catalyst, and (ii) reacting the resultant compound with a third epoxy compound of Formula (III):

wherein a is independently from 0 to 3.

5 . An epoxy resin composition comprising, based on the total weight of the epoxy resin composition,
(a) from 5 to 60 weight percent of the modified epoxy compound of any one of claims 1 - 3 , (b) from 5 to 60 weight percent of a second epoxy compound of Formula (II),

wherein R 3 is a straight-chain alkyl with 15 carbons containing 0 to 3 C═C bond(s) selected from the group consisting of —C 15 H 31 , —C 15 H 29 , —C 15 H 27 , and —C 15 H 25 ;
and a is independently from 0 to 3; and
(c) from 30 to 90 weight percent of a third epoxy compound of Formula (III):

wherein a is independently from 0 to 3.

6 . The epoxy resin composition of claim 5 , wherein the epoxy resin composition comprises: (a) from 5 to 40 weight percent of the modified epoxy compound, (b) from 10 to 30 weight percent of the second epoxy compound, and (c) from 40 to 85 weight percent of the third epoxy compound.

7 . The epoxy resin composition of claim 5 , wherein the total combined concentration of the modified epoxy compound and the second epoxy compound is from 15 to 60 weight percent, based on the total weight of the epoxy resin composition.

8 . The epoxy resin composition of claim 5 , wherein the total combined concentration of the modified epoxy compound and the second epoxy compound is from 25 to 55 weight percent, based on the total weight of the epoxy resin composition.

9 . The epoxy resin composition of claim 5 , wherein the third epoxy compound has an epoxide equivalent weight of from 150 to 210.

10 . The epoxy resin composition of claim 5 , wherein the epoxy resin composition has an epoxide equivalent weight of from 200 to 300.

11 . A curable coating composition comprising (I) the epoxy resin composition of claim 5 , and (II) a curing agent.

12 . The curable coating composition of claim 11 , wherein the curing agent comprises a phenalkamine compound.

13 . The curable coating composition of claim 11 , further comprising solvent, an accelerator, a curing catalyst, an inorganic extender and/or pigment, a filler, or mixtures thereof.

14 . The curable coating composition of claim 11 , wherein the molar ratio of a) total epoxy functionality of the epoxy resin composition to b) total active hydrogen functionality of the curing agent is from 10:1 to 1:2.

15 . The modified epoxy compound of claim 1 , wherein b is from 1 to 3; and R 1 is —C 15 H 25 —, —C 15 H 27 —, or —C 15 H 29 — group.

16 . The epoxy resin composition of claim 6 , wherein the total combined concentration of the modified epoxy compound and the second epoxy compound is from 15 to 60 weight percent, based on the total weight of the epoxy resin composition.

17 . The curable coating composition of claim 12 , wherein further comprising solvent, an accelerator, a curing catalyst, an inorganic extender and/or pigment, a filler, or mixtures thereof

18 . The epoxy resin composition of claim 6 , wherein the total combined concentration of the modified epoxy compound and the second epoxy compound is from 25 to 55 weight percent, based on the total weight of the epoxy resin composition.

19 . The epoxy resin composition of claim 6 , wherein the third epoxy compound has an epoxide equivalent weight of from 150 to 210.

20 . The epoxy resin composition of claim 6 , wherein the epoxy resin composition has an epoxide equivalent weight of from 200 to 300.

Assignees

• Blue Cube Ip Llc

Inventors

• Chen Chen
• Wu Yan
• Shen Yue
• Yang Yurun

Classifications

• C08G59/245 Primary

  aromatic · CPC title

• C09D163/00

  Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins · CPC title

• C08G59/504

  containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen · CPC title

• C07D303/26

  having one or more free hydroxyl radicals · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title