Scintillator crystal and radiation detector using the same

Patent metadata

Field	Value
Publication number	US-2016154123-A1
Application number	US-201514947728-A
Country	US
Kind code	A1
Filing date	Nov 20, 2015
Priority date	Nov 28, 2014
Publication date	Jun 2, 2016
Grant date	—

Abstract

A scintillator crystal includes a plurality of first crystal phases, and a second crystal phase covering respective side surfaces of the first crystal phases. Each of the plurality of first crystal phases is a columnar crystal that includes a perovskite type oxide material containing both Gd and Tb, and emits light by being excited by radiation. The second crystal phase includes alumina. Assuming that a, b, and c respectively represent Gd, Al, and Tb in an element ratio among them that are contained in a total amount of substance of the scintillator crystal, the element ratio is within a range defined by (a, b, c)=(0.174, 0.795, 0.031), (0.207, 0.756, 0.037), (0.213, 0.775, 0.012), and (0.194, 0.795, 0.011) as vertexes in a ternary composition diagram.

First claim

What is claimed is:

1 . A scintillator crystal comprising:
a plurality of first crystal phases; and a second crystal phase covering respective side surfaces of the first crystal phases, wherein each of the plurality of first crystal phases is a columnar crystal that includes a perovskite type oxide material containing both Gd and Tb, and emits light by being excited by radiation, wherein the second crystal phase includes alumina, and wherein, assuming that a, b, and c respectively represent Gd, Al, and Tb in an element ratio among them that are contained in a total amount of substance of the scintillator crystal, the element ratio is within a range defined by (a, b, c)=(0.174, 0.795, 0.031), (0.207, 0.756, 0.037), (0.213, 0.775, 0.012), and (0.194, 0.795, 0.011) as vertexes in a ternary composition diagram.

2 . A scintillator crystal comprising:
a plurality of first crystal phases; and a second crystal phase covering respective side surfaces of the first crystal phases, wherein each of the plurality of first crystal phases is a columnar crystal that includes a perovskite type oxide material containing both Gd and Eu, and emits light by being excited by radiation, wherein the second crystal phase includes alumina, and wherein, assuming that d, e, f respectively represent Gd, Al, and Eu in an element ratio among them that are contained in a total amount of substance of the scintillator crystal, the element ratio is within a range defined by (d, e, f)=(0.189, 0.795, 0.016), (0.235, 0.745, 0.020), (0.250, 0.745, 0.005), and (0.201, 0.795, 0.004) as vertexes in a ternary composition diagram.

3 . The scintillator crystal according to claim 1 , wherein Ce 3+ is added to each of the plurality of first crystal phases.

4 . The scintillator crystal according to claim 3 , wherein a concentration of the Ce 3+ is 0.001 mol % or higher to 1.0 mol % or lower with respect to the columnar crystal in each of the plurality of first crystal phases.

5 . The scintillator crystal according to claim 1 , wherein the scintillator crystal is a eutectic of the first crystal phases and the second crystal phase.

6 . The scintillator crystal according to claim 1 , wherein an average value of diameters of the plurality of columnar crystals is 300 nm or larger to 30 μm or smaller.

7 . The scintillator crystal according to claim 1 , wherein the plurality of first crystal phases is exposed at a first surface of the scintillator crystal and a second surface of the scintillator crystal that is different from the first surface.

8 . The scintillator crystal according to claim 7 , wherein the second surface is a surface opposite from the first surface.

9 . The scintillator crystal according to claim 2 , wherein the scintillator crystal is a eutectic of the first crystal phases and the second crystal phase.

10 . The scintillator crystal according to claim 2 , wherein an average value of diameters of the plurality of columnar crystals is 300 nm or larger to 30 μm or smaller.

11 . The scintillator crystal according to claim 2 , wherein the plurality of first crystal phases is exposed at a first surface of the scintillator crystal and a second surface of the scintillator crystal that is different from the first surface.

12 . The scintillator crystal according to claim 11 , wherein the second surface is a surface opposite from the first surface.

13 . A radiation detector comprising:
a photo detector; and a scintillator crystal, the scintillator crystal comprising a plurality of first crystal phases, and a second crystal phase covering respective side surfaces of the first crystal phases, wherein each of the plurality of first crystal phases is a columnar crystal that includes a perovskite type oxide material containing both Gd and Tb, and emits light by being excited by radiation, wherein the second crystal phase includes alumina, wherein, assuming that a, b, and c respectively represent Gd, Al, and Tb in an element ratio among them that are contained in a total amount of substance of the scintillator crystal, the element ratio is within a range defined by (a, b, c)=(0.174, 0.795, 0.031), (0.207, 0.756, 0.037), (0.213, 0.775, 0.012), and (0.194, 0.795, 0.011) as vertexes in a ternary composition diagram, wherein the plurality of first crystal phases is exposed, and wherein the scintillator crystal is disposed in such a manner that a surface that intersects with two directions in which the plurality of first crystal phases is arrayed is located opposite from the photo detector.

Assignees

• Canon Kk

Inventors

• Ohashi Yoshihiro
• Yasui Nobuhiro
• Den Toru

Classifications

• G01T1/2008

  using a combination of different types of scintillation detectors, e.g. phoswich · CPC title

• G01T1/2023 Primary

  Selection of materials · CPC title

• G01T1/2018

  Scintillation-photodiode combinations · CPC title