Polymer Composition with Improved Flammability Performance

Patent metadata

Field	Value
Publication number	US-2016152801-A1
Application number	US-201514951826-A
Country	US
Kind code	A1
Filing date	Nov 25, 2015
Priority date	Dec 1, 2014
Publication date	Jun 2, 2016
Grant date	—

Abstract

A polymer composition for use in a molded part is provided. The composition comprises a highly flowable, liquid crystalline polymer blended with a relatively small amount of an inorganic filler (e.g., glass fibers, mineral filler, etc.). Although the composition contains only a small amount of the filler, the resulting molded part can still exhibited improved flammability performance. More particularly, the present inventors have surprisingly discovered that the use of an organophosphorous compound within a certain concentration can improve the flammability properties of the composition without sacrificing other properties of the part, such as blister resistance.

First claim

What is claimed is:

1 . A polymer composition comprising a liquid crystalline polymer having a melt viscosity of about 50 Pa-s or less as determined in accordance with ISO Test No. 11443 at a shear rate of 1000 seconds −1 and temperature that is 15° C. above the melting temperature of the polymer, wherein the polymer is melt blended with an inorganic filler in an amount of from about 0.1 to about 35 parts per 100 parts of the polymer and an organophosphorous compound in an amount of from about 0.01 to about 5 parts per 100 parts of the polymer.

2 . The polymer composition of claim 1 , wherein the polymer composition has a melt viscosity of about 80 Pa-s or less, as determined in accordance with ISO Test No. 11443 at a shear rate of 1000 seconds −1 and temperature that is 15° C. above the melting temperature of the composition.

3 . The polymer composition of claim 1 , wherein the polymer has a total amount of repeating units derived from naphthenic hydroxcarboxylic and/or naphthenic dicarboxylic acids of more than 15 mol. %.

4 . The polymer composition of claim 3 , wherein the polymer contains monomer units derived from 2,6-naphthalenedicarboxylic acid.

5 . The polymer composition of claim 3 , wherein the polymer contains monomer units derived from 4-hydroxybenzoic acid, terephthalic acid, isophthalic acid, hydroquinone, 4,4′-biphenol, acetaminophen, or a combination thereof.

6 . The polymer composition of claim 1 , wherein the filler includes glass fibers, a mineral filler, or a combination thereof.

7 . The polymer composition of claim 1 , wherein the organophosphorous compound includes a phosphite, phosphonite, or a combination thereof.

8 . The polymer composition of claim 7 , wherein the compound includes an aryl phosphonite that contains C 1 to C 10 alkyl substituents.

9 . The polymer composition of claim 8 , wherein the aryl phosphonite has the following general formula (I):

wherein,
m is 0 or 1;
n is 0 or 1;
R 10 and R 11 are independently an aliphatic, alicyclic or aromatic group of 1 to 24 carbon atoms, optionally further substituted, or both groups R 10 and/or R 11 form a cyclic group with a single phosphorus atom;
Y is —O—, —S—, —CH(R 15 )— or —C 6 H 4 —, where R 15 is hydrogen, C 1-6 alkyl, or COOR 6 and R 6 is C 1-18 alkyl.

10 . The polymer composition of claim 8 , wherein the aryl phosphonite has the following general formula (x):

wherein R 10 and R 11 are independently a linear, branched or cyclic C 1-24 aliphatic groups or aromatic groups, optionally substituted with from 1 to 4 C 1-12 alkyl or aryl groups.

11 . The polymer composition of claim 10 , wherein R 10 and/or R 11 are 2,4-di-tert-butylphenyl.

12 . The polymer composition of claim 1 , wherein the composition further comprises a mineral filler.

13 . The polymer composition of claim 1 , wherein the composition is generally free of polytetrafluoroethylene.

14 . A molded part comprising the polymer composition of claim 1 .

15 . The molded part of claim 14 , wherein the part exhibits a total flame time of about 50 seconds or less, as determined in accordance with UL94 at a thickness of 0.8 mm after conditioning for 48 hours at 23° C. and 50% relative humidity.

16 . The molded part of claim 14 , wherein the part exhibits a total number of drips of 3 or less, as determined in accordance with UL94 at a thickness of 0.8 mm after conditioning for 48 hours at 23° C. and 50% relative humidity.

17 . The molded part of claim 14 , wherein the part exhibits a V0 rating as determined in accordance with UL94 after conditioning for 48 hours at 23° C. and 50% relative humidity.

18 . The molded part of claim 14 , wherein the part exhibits a blister free temperature of about 240° C. or greater.

19 . The molded part of claim 14 , wherein the part has at least one dimension of about 500 micrometers or less.

20 . An electrical connector that comprises opposing walls between which a passageway is defined for receiving a contact pin, wherein at least one of the walls contains the molded part of claim 14 .

21 . A camera module that comprises the molded part of claim 14 .

Assignees

• Ticona Llc

Inventors

• Yu Yuehua
• Tyler Mark Allen

Classifications

• C08K3/22 Primary

  of metals · CPC title

• C08K7/14 Primary

  Glass · CPC title

• C08J5/00

  Manufacture of articles or shaped materials containing macromolecular substances (manufacture of semi-permeable membranes B01D67/00 - B01D71/00) · CPC title

• C08J2300/00

  Characterised by the use of unspecified polymers · CPC title

• C08K5/13

  Phenols; Phenolates · CPC title