Phosphate-garnet solid electrolyte structure

Patent metadata

Field	Value
Publication number	US-2016149267-A1
Application number	US-201514934315-A
Country	US
Kind code	A1
Filing date	Nov 6, 2015
Priority date	Nov 26, 2014
Publication date	May 26, 2016
Grant date	—

Abstract

A composite electrolyte tri-layer structure, including:
a first layer comprising a first ceramic electrolyte, which first electrolyte is stable against contact with lithium metal; a second layer comprising a second ceramic electrolyte, which second electrolyte is stable against aqueous contact; and a third layer comprising a third non-aqueous electrolyte interposed between the first layer and second layer, wherein the first electrolyte, the second electrolyte, and the third electrolyte each have a different relative chemical stability.

Also disclosed is a method of making and using the tri-layer structure, and an energy storage article or device incorporating at least one of the tri-layer structures.

First claim

What is claimed:

1 . A composite electrolyte tri-layer structure, comprising:
a first layer comprising a first ceramic electrolyte, the first electrolyte is stable to contact with lithium metal; a second layer comprising a second ceramic electrolyte, the second electrolyte is stable to aqueous contact; and a third layer comprising a third non-aqueous electrolyte interposed between the first layer and second layer.

2 . The composite electrolyte structure of claim 1 wherein:
the first layer is a solid lithium garnet composition;
the second layer is a solid metal phosphate electrolyte; and
the third layer is selected from at least one of: a liquid, a gel, a solid polymer, or a combination thereof, and is a mixture of an inorganic electrolyte salt and organic solvent, wherein the first electrolyte, the second electrolyte, and the third electrolyte each have a different relative chemical stability.

3 . The composite electrolyte structure of claim 2 wherein:
the solid lithium garnet composition is of the formula Li x A y B z O 12+d where x is greater than or equal to 3, A is a cation selected from at least one of a monovalent cation, a divalent cation, a trivalent cation, a tetravalent cation, or a mixture thereof, B is a cation selected from at least one of a tetravalent cation, a pentavalent cation, a hexavalent cation, or a mixture thereof, and x is greater than 2, y is greater than 2, z is greater than 1, and d is greater than −1 and less than +1;
the solid metal phosphate electrolyte is of the formula Li x M y (PO 4 ) z , where M is an element selected from at least one of a univalent, a divalent, a trivalent, a tetravalent, a pentavalent, a hexavalent, or a mixture of elements thereof, and x is greater than 0.1, y is greater than 1, and z is greater than 2, and the metal phosphate has a NASICON structure; and
the third layer is a liquid electrolyte selected from at least one of: an ionic liquid, a mixture of an inorganic lithium salt and an organic solvent, or a mixture thereof.

4 . The composite electrolyte structure of claim 2 wherein:
the solid lithium garnet composition is Li 7 La 3 Zr 2 O 12 ;
the solid metal phosphate electrolyte is Li 1.4 Al 0.4 Ti 1.6 (PO 4 ) 3 ; and
the third layer mixture of an inorganic electrolyte salt and organic solvent is LiPF 6 in ethylene carbonate and dimethyl carbonate.

5 . The composite electrolyte structure of claim 2 wherein the third layer mixture of an inorganic electrolyte salt and organic solvent is LiPF 6 in an amount of from 1 to 30 wt %, and the organic solvent is in an amount of from 70 to 99 wt %.

6 . The composite electrolyte structure of claim 1 wherein the tri-layer structure isolates the third layer electrolyte from contact with an aqueous phase.

7 . The composite electrolyte structure of claim 1 further comprising:
a seal encompassing the edges of the tri-layer structure;
a lithium metal layer adjacent to the first ceramic electrolyte, wherein the lithium metal layer is either in direct physical contact with the first ceramic electrolyte or in electrical communication with the first ceramic electrolyte; and
a layer containing an aqueous electrolyte adjacent to and in contact with the second ceramic electrolyte.

8 . The composite electrolyte structure of claim 7 wherein the seal is a water insoluble polymer.

9 . The composite electrolyte structure of claim 7 wherein the structure hermetically isolates the aqueous electrolyte containing layer and prevents contact of the aqueous electrolyte with the lithium metal layer.

10 . The composite electrolyte structure of claim 1 wherein:
the first layer is flat and has an average thickness of from 1 to 50 microns;
the second layer is flat and has an average thickness of from 1 to 50 microns; and
the third layer has an average thickness of from 0.1 to 50 microns.

11 . The composite electrolyte tri-layer structure of claim 1 further comprising at least two tri-layer structures.

12 . The composite electrolyte structure of claim 11 wherein the at least two trilayer structures comprise a structure according to:
a first anode ( 210 ) including a first lithium metal anode ( 120 ) bonded to a first anode current collector ( 212 );
a first trilayer electrolyte structure ( 100 ) including a first solid lithium garnet composition ( 110 ) in contact with the first lithium metal anode ( 120 ), a first non-aqueous electrolyte layer ( 140 ), a first LMP layer ( 130 ), and first edge seal ( 160 );
a first cathode structure ( 220 ) including:
a first aqueous catholyte ( 150 ) in contact with the first LMP layer ( 130 ) and a first porous solid cathode layer ( 222 );
a second aqueous catholyte ( 150 ) in contact with a second LMP layer ( 130 ) and a second porous solid cathode layer ( 222 );
a cathode current collector ( 235 ) disposed between the first aqueous catholyte ( 150 ) and the second aqueous catholyte ( 150 ); and
an internal containment member ( 230 ), which isolates the first cathode structure ( 220 ) from the environment within the composite electrolyte structure;

a second trilayer electrolyte structure ( 100 ) including a second LMP layer ( 130 ) in contact with the second aqueous catholyte ( 150 ), a second non-aqueous electrolyte layer ( 140 ), a second solid lithium garnet composition ( 110 ), and second edge seal ( 160 );
a second anode ( 210 ) including a second lithium metal anode ( 120 ) in contact with the second solid lithium garnet composition ( 110 ) and bonded to a second anode current collector ( 212 ); and
an external container ( 250 ).

13 . The composite electrolyte structure of claim 12 further comprising a seal member for each tri-layer structure, and an internal containment structure for each cathode structure.

14 . The composite electrolyte structure of claim 12 further comprising an external containment structure.

15 . A method of making the composite tri-layer electrolyte structure of claim 1 , comprising:
tape casting and sintering the first ceramic electrolyte; tape casting and sintering the second ceramic electrolyte; and disposing the third layer comprising a third non-ceramic electrolyte between the first and second ceramic electrolytes, to form the composite tri-layer electrolyte structure.

16 . The method of claim 15 wherein the disposing is accomplished with vacuum or pressure to remove entrapped gas bubbles from the third electrolyte.

17 . The method of claim 15 further comprising sealing the edges of the tri-layer structure with a non-conductive substance.

18 . The method of claim 15 further comprising:
attaching a lithium metal layer adjacent to and in contact with the first ceramic electrolyte and separated from the third non-ceramic electrolyte; and
contacting an aqueous electrolyte containing layer adjacent to the second ceramic electrolyte and separated from the third non-ceramic electrolyte.

19 . The method of claim 15 further comprising combining two or more composite tri-layer electrolyte structures.

20 . A lithium-ion battery comprising:
internal components comprising and structured in the order listed:
an anode comprising lithium metal;
a ceramic electrolyte adjacent to the anode;
a cathode comprising an aqueous catholyte adjacent to the ceramic electrolyte, wherein the cathode includes an interior seal that contains the aqueous catholyte and isolates the aqueous catholyte from the anode; and
a container that contains and isolates the internal components from the external a

Assignees

• Corning Inc

Inventors

• Badding Michael Edward
• Johnson Paul Oakley
• Liu Xinyuan

Classifications

• H01M2300/0002

  Aqueous electrolytes · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M2300/0094

  in the form of layered products, e.g. coatings · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M4/382 Primary

  Lithium (H01M4/405 takes precedence) · CPC title