Phosphor, light emitting device, surface light source device, display device and illumination device
US-9200200-B2 · Dec 1, 2015 · US
US2016149092A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016149092-A1 |
| Application number | US-201514980027-A |
| Country | US |
| Kind code | A1 |
| Filing date | Dec 28, 2015 |
| Priority date | Jul 12, 2010 |
| Publication date | May 26, 2016 |
| Grant date | — |
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An optoelectronic component includes a semiconductor chip that emits a primary radiation in the short-wave blue spectral range at a dominant wavelength of less than approximately 465 nm; and a phosphor that converts at least part of the primary radiation into a longer-wave secondary radiation in the green spectral range at a dominant wavelength of between approximately 490 nm and approximately 550 nm and at least partly surrounds the semiconductor chip, wherein a mixed light composed of primary radiation and secondary radiation has a dominant wavelength at wavelengths of approximately 460 nm to approximately 480 nm such that a luminous flux of the mixed light is up to 130% greater than a luminous flux in an optoelectronic component without a phosphor having the same dominant wavelength in a range of 460 nm to 480 nm, and the phosphor is arranged in a lamina that bears directly on the semiconductor chip.
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1 . An optoelectronic component comprising: a semiconductor chip that emits a primary radiation in the short-wave blue spectral range at a dominant wavelength of less than approximately 465 nm; and a phosphor that converts at least part of the primary radiation into a longer-wave secondary radiation in the green spectral range at a dominant wavelength of between approximately 490 nm and approximately 550 nm and at least partly surrounds the semiconductor chip, wherein a mixed light composed of primary radiation and secondary radiation has a dominant wavelength at wavelengths of approximately 460 nm to approximately 480 nm such that a luminous flux of the mixed light is up to 130% greater than a luminous flux in an optoelectronic component without a phosphor having the same dominant wavelength in a range of 460 nm to 480 nm, and the phosphor is arranged in a lamina that bears directly on the semiconductor chip. 2 . The optoelectronic component according to claim 1 , wherein the lamina comprises a matrix material into which the phosphor is introduced at a concentration of 5% by weight to 50% by weight. 3 . The optoelectronic component according to claim 2 , wherein the lamina has a thickness of 30 micrometers to 200 micrometers. 4 . The optoelectronic component according to claim 1 , wherein the lamina is ceramic and has a phosphor concentration of 10% by weight to 80% by weight. 5 . The optoelectronic component according to claim 1 , wherein the color loci of the mixed light composed of the primary radiation emitted by the semiconductor chip with a dominant wavelength of approximately 440 nm to approximately 455 nm and composed of secondary radiation emerging from the phosphor with a dominant wavelength of approximately 490 nm to approximately 550 nm lie in the CIE diagram so close to one another that, given uniform phosphor concentration, the dominant wavelengths of the mixed light lie within a wavelength range of approximately 2 to 4 nm. 6 . The optoelectronic component according to claim 5 , wherein the color locus of the optoelectronic component that emits mixed light lies in the CIE diagram on the areas spanned by different blue standards EN 12966 C1 (VMS) and EN 12966 C2 (VMS). 7 . The optoelectronic component according to claim 1 , wherein the phosphor comprises one of: an europium-activated blue-green silicate which is a chlorosilicate having empirical formula Ca 8-x-y Eu x Mn y Mg(SiO 4 ) 4 C1 2 , wherein y≧0.03 and x=0.005 and x=1.5, an europium-activated orthosilicate having empirical formula (Ca,Sr,Ba) 2 SiO 4 :EU, an europium-activated thiogallate having empirical formula (Mg,Ca,Sr,Ba)Ga 2 S 4 :EU, an europium-activated SiON having empirical formula Ba 3 Si 6 O 12 N 2 :EU, and a beta-SiAlON. 8 . The optoelectronic component according to claim 1 , wherein the phosphor has a quantum efficiency of up to 70%. 9 . An optoelectronic component comprising: a semiconductor chip that emits a primary radiation in the short-wave blue spectral range at a dominant wavelength of less than approximately 465 nm; and a phosphor that converts at least part of the primary radiation into a longer-wave secondary radiation in the green spectral range at a dominant wavelength of between approximately 490 nm and approximately 550 nm and at least partly surrounds the semiconductor chip, wherein a mixed light composed of primary radiation and secondary radiation has a dominant wavelength at wavelengths of approximately 460 nm to approximately 480 nm such that a luminous flux of the mixed light is up to 130% greater than a luminous flux in an optoelectronic component without a phosphor having the same dominant wavelength in a range of 460 nm to 480 nm, and the phosphor comprises an electrophoretically deposited phosphor layer applied on a radiation exit area of the semiconductor chip, said phosphor layer having a thickness of 5 micrometers to 50 micrometers. 10 . The optoelectronic component according to claim 9 , wherein the color loci of the mixed light composed of the primary radiation emitted by the semiconductor chip with a dominant wavelength of approximately 440 nm to approximately 455 nm and composed of secondary radiation emerging from the phosphor with a dominant wavelength of approximately 490 nm to approximately 550 nm lie in the CIE diagram so close to one another that, given uniform phosphor concentration, the dominant wavelengths of the mixed light lie within a wavelength range of approximately 2 to 4 nm. 11 . The optoelectronic component according to claim 10 , wherein the color locus of the optoelectronic component that emits mixed light lies in the CIE diagram on the areas spanned by different blue standards EN 12966 C1 (VMS) and EN 12966 C2 (VMS). 12 . The optoelectronic component according to claim 9 , wherein the phosphor comprises one of: an europium-activated blue-green silicate which is a chlorosilicate having empirical formula Ca 8-x-y Eu x Mn y Mg(SiO 4 ) 4 C1 2 , wherein y≧0.03 and x=0.005 and x=1.5, an europium-activated orthosilicate having empirical formula (Ca,Sr,Ba) 2 SiO 4 :EU, an europium-activated thiogallate having empirical formula (Mg,Ca,Sr,Ba)Ga 2 S 4 :EU, an europium-activated SiON having empirical formula Ba 3 Si 6 O 12 N 2 :EU, and a beta-SiAlON. 13 . The optoelectronic component according to claim 9 , wherein the phosphor has a quantum efficiency of up to 70%. 14 . An optoelectronic component comprising: a semiconductor chip that emits a primary radiation in the short-wave blue spectral range at a dominant wavelength of less than approximately 465 nm; and a phosphor that converts at least part of the primary radiation into a longer-wave secondary radiation in the green spectral range at a dominant wavelength of between approximately 490 nm and approximately 550 nm and at least partly surrounds the semiconductor chip, wherein a mixed light composed of primary radiation and secondary radiation has a dominant wavelength at wavelengths of approximately 460 nm to approximately 480 nm such that a luminous flux of the mixed light is up to 130% greater than a luminous flux in an optoelectronic component without a phosphor having the same dominant wavelength in a range of 460 nm to 480 nm, and the phosphor is arranged at and/or in an exit window terminating the optoelectronic component around the semiconductor chip. 15 . The optoelectronic component according to the claim 14 , wherein the phosphor concentration in the exit window is 2% by weight to 10% by weight. 16 . The optoelectronic component according to claim 14 , wherein the color loci of the mixed light composed of the primary radiation emitted by the semiconductor chip with a dominant wavelength of approximately 440 nm to approximately 455 nm and composed of secondary radiation emerging from the phosphor with a dominant wavelength of approximately 490 nm to approximately 550 nm lie in the CIE diagram so close to one another that, given uniform phosphor concentration, the dominant wavelengths of the mixed light lie within a wavelength range of approximately 2 to 4 nm. 17 . The optoelectronic component according to claim 16 , wherein the color locus of the optoelectronic component that emits mixed light lies in the CIE diagram on the areas spanned by different blue standards EN 12966 C1 (VMS) and EN 12966 C2 (VMS). 18 . The optoelectronic component according to claim 14 , wherein the phosphor comprises one of: an europium-activated blue-green silicate which is a chlorosilicate having empirical formula Ca 8-x-y Eu x Mn y Mg(SiO 4 ) 4 C1 2 ,
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