Process for heavy oil upgrading in a double-wall reactor

Patent metadata

Field	Value
Publication number	US-2016145499-A1
Application number	US-201414554209-A
Country	US
Kind code	A1
Filing date	Nov 26, 2014
Priority date	Nov 26, 2014
Publication date	May 26, 2016
Grant date	—

Abstract

A process for reducing coke formation during hydrocarbon upgrading reactions using a double-wall reactor comprising the steps of feeding a heated feed water to a shell-side volume of the double-wall reactor to produce a heat transfer stream, the double-wall reactor comprising an exterior wall and an interior wall, a reaction section volume, a heating element configured to heat the heat transfer stream, wherein heat is transferred from the heat transfer stream to the reaction section volume, feeding the hot water return exiting the shell-side volume through a filter; mixing the filtered water stream with a heated hydrocarbon feedstock; feeding the mixed stream to the reaction section volume in a configuration counter-current to the heat transfer stream; reacting the reaction flow stream at a reaction temperature, wherein the heat transferred to the reaction section volume is operable to maintain the reaction temperature above the critical temperature of water.

First claim

That which is claimed is:

1 . A process for reducing coke formation during hydrocarbon upgrading reactions using a double-wall reactor, the process comprising the steps of:
feeding a heated feed water to a shell-side volume of the double-wall reactor to produce a heat transfer stream, the double-wall reactor comprising:
an exterior wall and an interior wall, the exterior wall and the interior wall defining the shell-side volume disposed between,
a reaction section volume bounded by the interior wall,
a heating element, the heating element adjacent to the exterior wall, wherein the heating element is configured to heat the heat transfer stream to create a hot water return, such that the heat transfer stream is above the critical temperature of water, wherein heat is transferred from the heat transfer stream through the interior wall to the reaction section volume, wherein the hot water return exits the shell-side volume,
wherein the heat transfer stream is at a temperature greater than the critical temperature of water and is at a pressure greater than the critical pressure of water;
feeding the hot water return exiting the shell-side volume of the double-wall reactor through a filter, the filter is configured to remove particulates to form a filtered water stream; mixing the filtered water stream with a heated hydrocarbon feedstock in a mixer to produce a mixed stream, wherein the heated hydrocarbon feedstock is at a pressure greater than the critical pressure of water and at a temperature greater than 50° C.; feeding the mixed stream to the reaction section volume of the double-wall reactor in a flow configuration counter-current to the heat transfer stream to create a reaction flow stream; reacting the reaction flow stream at a reaction temperature in the reaction section volume to produce a reactor effluent, wherein the heat transferred to the reaction section volume from the heat transfer stream is operable to maintain the reaction temperature above the critical temperature of water;
cooling the reactor effluent in a reactor cooler to produce a cooled effluent;
de-pressurizing the cooled effluent in a pressure reducer to produce a depressurized effluent; separating the depressurized effluent in a phase separator to produce a gas phase product and a liquid phase product; and separating the liquid phase product in a product separator to produce a separated water stream and an upgraded hydrocarbon stream.

2 . The process of claim 1 , further comprising the step of:
recycling the separated water stream to combine with a feed water upstream of the double-wall reactor.

3 . The process of claim 1 , wherein the double-wall reactor further comprises:
a shell-side inlet, the shell-side inlet configured to receive the heated feed water; a shell-side outlet, the shell-side outlet configured to eject the heat transfer stream as the hot water return; a reaction inlet, the reaction inlet configured to receive the mixed stream; and a reaction outlet, the reaction outlet configured to eject the reaction flow stream as the reactor effluent,
wherein the shell-side inlet, the shell-side outlet, the reaction inlet, and the reaction outlet are configured to create the flow configuration counter-current between the heat transfer stream and the reaction flow stream.

4 . The process of claim 1 , wherein the double-wall reactor further comprises:
baffles extending from the exterior wall into the shell-side volume, the baffles configured to increase heat transfer from the heating element and the exterior wall to the heat transfer stream.

5 . The process of claim 1 , further comprising the step of:
feeding the hot water return to a mixer pre-heater, the mixer pre-heater configured to increase the temperature of the hot water return to produce a hot mixer feed; and feeding the hot mixer feed to the filter to produce the filtered water stream.

6 . The process of claim 1 , further comprising the step of:
feeding the heated feed water to a water super heater, the water super heater configured to increase the temperature of the heated feed water to produce a hot water supply; and feeding the hot water supply to the shell-side volume of the double-wall reactor.

7 . The process of claim 1 , further comprising the steps of:
feeding the reactor effluent to a supercritical water reactor, the supercritical water reactor configured to upgrade hydrocarbons present in the reactor effluent, wherein the temperature of the supercritical water reactor is greater than the critical temperature of water, wherein the pressure of the supercritical water reactor is greater than the critical pressure of water; reacting the reactor effluent to produce a product stream; and feeding the product stream to the reactor cooler.

8 . The process of claim 1 , wherein liquid yield is greater than 98% by volume.

9 . The process of claim 1 , wherein the upgraded hydrocarbon stream has reduced amounts of asphaltene, sulfur, and other impurities.

10 . The process of claim 1 , wherein a residence time of the reaction flow stream in the double-wall reactor is greater than 10 seconds.

11 . A supercritical water plant to upgrade hydrocarbons with reduced coke formation, the supercritical water plant comprising:
a hydrocarbon feedstock pump, the hydrocarbon feedstock pump configured to pressurize a hydrocarbon feedstock to a pressure above the critical pressure of water to produce a pressurized hydrocarbon feedstock; a hydrocarbon feedstock heater fluidly connected to the hydrocarbon feedstock pump, the hydrocarbon feedstock heater configured to heat the pressurized hydrocarbon feedstock to a temperature greater than 50° C. to produce a heated hydrocarbon feedstock; a feed water pump, the feed water pump configured to pressurize a feed water to a pressure above the critical pressure of water to produce a pressurized feed water; a feed water heater fluidly connected to the feed water pump, the feed water pump configured to heat the pressurized feed water to a temperature above the critical temperature of water to produce a heated feed water; a double-wall reactor, the double-wall reactor configured to upgrade the hydrocarbons with upgrading reactions, the double-wall reactor further configured to limit coke formation during the upgrading reactions, the double-wall reactor comprising:
a shell-side inlet fluidly connected to the feed water heater, the shell-side inlet configured to receive the heated feed water to produce a heat transfer stream in a shell-side volume;
an exterior wall and an interior wall, the exterior wall and the interior wall defining the shell-side volume disposed between, the shell-side volume configured to receive the heat transfer stream;
a reaction section volume bounded by the interior wall;
a shell-side outlet fluidly connected to the shell-side volume, the shell-side outlet configured to eject the heat transfer stream to produce a hot water return; and
a heating element, the heating element adjacent to the exterior wall, wherein the heating element is configured to heat the heat transfer stream, such that the heat transfer stream is above the critical temperature of water, wherein heat is transferred from the heat transfer stream through the interior wall to the reaction section volume;
a filter fluidly connected to the shell-side outlet, the filter configured to remove particulates from the hot water return to form a filtered water stream; a mixer fluidly connected to the filter, the mixer configured to mix the filtered water stream and the heated hydrocarbon feedstock to produce a mixed stream, wherein the mixed stream is supplied to the reaction section volume o

Assignees

• Saudi Arabian Oil Co

Inventors

• Choi Ki-Hyouk
• Lee Joo-Hyeong
• Alabdulhadi Abdullah T

Classifications

• C10G45/26

  Steam or water · CPC title

• B01J2219/00135

  Electric resistance heaters · CPC title

• B01J2219/00094

  Jackets · CPC title

• C10G55/04

  including at least one thermal cracking step · CPC title

• B01D2259/4525

  for storage and dispensing systems · CPC title