Process for production of poly(arylene sulfide)

Patent metadata

Field	Value
Publication number	US-2016145393-A1
Application number	US-201414550630-A
Country	US
Kind code	A1
Filing date	Nov 21, 2014
Priority date	Nov 21, 2014
Publication date	May 26, 2016
Grant date	—

Abstract

A process for producing a poly(arylene sulfide) polymer comprising (a) polymerizing reactants in a reaction vessel to produce a poly(arylene sulfide) reaction mixture, (b) processing at least a portion of the poly(arylene sulfide) reaction mixture to obtain a poly(arylene sulfide) reaction mixture downstream product, and (c) contacting a by-product treatment additive with at least a portion of the poly(arylene sulfide) reaction mixture and/or downstream product thereof, and (d) processing at least a portion of the poly(arylene sulfide) reaction mixture downstream product to yield salt solids particulates, wherein the by-product treatment additive reduces agglomeration of the salt solids particulates.

First claim

What is claimed is:

1 . A process for producing a poly(arylene sulfide) polymer comprising:
(a) polymerizing reactants in a reaction vessel to produce a poly(arylene sulfide) reaction mixture; (b) processing at least a portion of the poly(arylene sulfide) reaction mixture to obtain a poly(arylene sulfide) reaction mixture downstream product; and (c) contacting a by-product treatment additive with at least a portion of the poly(arylene sulfide) reaction mixture and/or downstream product thereof; and (d) processing at least a portion of the poly(arylene sulfide) reaction mixture downstream product to yield salt solids particulates, wherein the by-product treatment additive reduces agglomeration of the salt solids particulates.

2 . The process of claim 1 , wherein (b) processing the poly(arylene sulfide) reaction mixture comprises quenching the reaction mixture by adding a quench liquid thereto, wherein the quench liquid comprises the by-product treatment additive.

3 . The process of claim 1 , wherein (b) processing the poly(arylene sulfide) reaction mixture comprises washing the at least a portion of the poly(arylene sulfide) reaction mixture with a polar organic compound and/or water to obtain a washed poly(arylene sulfide) polymer and a first slurry.

4 . The process of claim 3 , wherein the by-product treatment additive is contacted with the poly(arylene sulfide) reaction mixture concurrent with washing the poly(arylene sulfide) reaction mixture with the polar organic compound and/or water.

5 . The process of claim 3 , wherein the by-product treatment additive is contacted with at least a portion of the first slurry, and wherein the first slurry has a pH of from about 4 to about 11 after contacting with the by-product treatment additive.

6 . The process of claim 3 , further comprising evaporating at least a portion of the first slurry to obtain a by-product slurry, wherein the by-product slurry comprises poly(arylene sulfide) polymer impurities, and wherein at least a portion of the by-product slurry is evaporated to yield the salt solids particulates.

7 . The process of claim 6 , wherein the by-product treatment additive is contacted with at least a portion of the by-product slurry.

8 . The process of claim 6 , wherein the poly(arylene sulfide) polymer impurities comprise poly(arylene sulfide) polymer fines, poly(arylene sulfide) oligomers, poly(arylene sulfide) low molecular weight polymers, polymerization reaction side-products, polymerization reaction by-products, or combinations thereof.

9 . The process of claim 6 , wherein the by-product treatment additive decreases the degradation of the poly(arylene sulfide) polymer impurities.

10 . The process of claim 6 , wherein a weight average molecular weight of the poly(arylene sulfide) polymer impurities is by from about 1.01 times greater to about 40 times greater than a weight average molecular weight of poly(arylene sulfide) polymer impurities of an otherwise similar by-product slurry in the absence of treatment with the by-product treatment additive.

11 . The process of claim 6 , wherein evaporating the by-product slurry to yield salt solids particulates further comprises introducing the by-product slurry to a dryer, wherein the dryer comprises a dryer motor that imparts a rotational motion to one or more internal elements of the dryer.

12 . The process of claim 11 , wherein a torque of the dryer motor is reduced by from about 20% to about 100% when compared to a torque of the dryer motor used for evaporating an otherwise similar by-product slurry in the absence of treatment with the by-product treatment additive.

13 . The process of claim 11 , wherein a size of the salt solids particulates is reduced by from about 5% to about 95% when compared to a size of the salt solids particulates obtained by evaporating an otherwise similar by-product slurry in the absence of treatment with the by-product treatment additive.

14 . The process of claim 11 , wherein the by-product treatment additive is contacted with the poly(arylene sulfide) reaction mixture and/or downstream product thereof in an amount effective to reduce a torque of the dryer motor used for evaporating at least a portion of the by-product slurry by from about 20% to about 100% when compared to a torque of the dryer motor used for evaporating an otherwise similar by-product slurry in the absence of treatment with the by-product treatment additive.

15 . The process of claim 6 , wherein the by-product treatment additive is contacted with the poly(arylene sulfide) reaction mixture and/or downstream product thereof in an amount effective to reduce a size of the salt solids particulates obtained by evaporating at least a portion of the by-product slurry by from about 5% to about 95% when compared to a size of the salt solids particulates obtained by evaporating an otherwise similar by-product slurry in the absence of treatment with the by-product treatment additive.

16 . The process of claim 1 , wherein the by-product treatment additive is contacted with the poly(arylene sulfide) reaction mixture and/or downstream product thereof in an amount effective to yield a pH of a first slurry of from about 4 to about 11.

17 . The process of claim 1 , wherein the by-product treatment additive comprises an acid, a non-oxidizing acid, an organic acid, a mineral acid, an acid precursor, a salt, or combinations thereof.

18 . The process of claim 1 , wherein the by-product treatment additive comprises acetic acid, propionic acid, formic acid, hydrochloric acid, carbon dioxide, dry ice, sodium carbonate, sodium bicarbonate, potassium carbonate, potassium bicarbonate, sodium acetate, potassium acetate, acid containing clays, silica, or combinations thereof.

19 . A process for producing a poly(arylene sulfide) polymer comprising:
(a) polymerizing reactants in a reaction vessel to produce a poly(arylene sulfide) reaction mixture; (b) washing at least a portion of the poly(arylene sulfide) reaction mixture with a polar organic compound and/or water to obtain a poly(arylene sulfide) polymer and a first slurry; (c) contacting at least a portion of the first slurry with a by-product treatment additive to yield a treated first slurry having a pH of from about 4 to about 11; (d) evaporating at least portion of the treated first slurry to obtain a by-product slurry comprising poly(arylene sulfide) polymer impurities, wherein a weight average molecular weight of the poly(arylene sulfide) polymer impurities is by from about 1.01 times greater to about 40 times greater than a weight average molecular weight of poly(arylene sulfide) polymer impurities of an otherwise similar by-product slurry in the absence of treatment with the by-product treatment additive; and (e) evaporating at least portion of the by-product slurry to yield salt solids particulates, wherein the by-product treatment additive reduces agglomeration of the salt solids particulates.

20 . A process for producing a poly(arylene sulfide) polymer comprising:
(a) polymerizing reactants in a reaction vessel to produce a poly(arylene sulfide) reaction mixture; (b) contacting at least a portion of the poly(arylene sulfide) reaction mixture with a by-product treatment additive to yield a treated poly(arylene sulfide) reaction mixture; (c) washing at least a portion of the treated poly(arylene sulfide) reaction mixture with a polar organic compound and/or water to obtain a poly(arylene sulfide) polymer and a first slurry having a pH of from about 4 t

Assignees

• Chevron Phillips Chemical Co

Inventors

• Childress R Shawn
• Fodor Jeffrey S
• Soules David A
• Swan Jeffrey L
• Clark Thomas M

Classifications

• C08G75/0213

  containing elements other than carbon, hydrogen or sulfur · CPC title

• C08G75/0281

  Recovery or purification · CPC title

• C08G75/0254

  using metal sulfides · CPC title

• C08L81/00 Primary

  Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers · CPC title

• C08G75/14 Primary

  Polysulfides · CPC title