Process for production of oxymethylene copolymer
US-10138321-B2 · Nov 27, 2018 · US
US2016145383A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016145383-A1 |
| Application number | US-201414903366-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jul 3, 2014 |
| Priority date | Jul 12, 2013 |
| Publication date | May 26, 2016 |
| Grant date | — |
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The present invention provides a method for producing a polydioxolane, which includes polymerizing a 1,3-dioxolane compound represented by the formula (1) in the presence of a cationic catalyst and a sterically hindered phenol in an amount of 10 to 1,500 ppm, based on the 1,3-dioxolane compound. In the formula (1), R1 to R6 are the same or difference and each independently represents a hydrogen atom, an alkyl group, an aryl group, a hydroxyalkyl group, an alkyloxy group, or an aryloxy group.
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1 . A method for producing a polydioxolane, the method comprising: polymerizing a 1,3-dioxolane compound represented by formula (1) in the presence of a cationic catalyst and a sterically hindered phenol in an amount of 10 to 1,500 ppm, based on the 1,3-dioxolane compound, wherein R1 to R6 are the same or different and each independently represents a hydrogen atom, an alkyl group, an aryl group, a hydroxyalkyl group, an alkyloxy group, or an aryloxy group. 2 . The method for producing a polydioxolane according to claim 1 , wherein the sterically hindered phenol is present in an amount of 200 to 800 ppm, based on the 1,3-dioxolane compound. 3 . The method for producing a polydioxolane according to claim 1 , wherein R1 to R6 in the formula (1) is each a hydrogen atom. 4 . The method for producing a polydioxolane according to claim 1 , wherein the sterically hindered phenol is triethylene glycol-bis-3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionate. 5 . The method for producing a polydioxolane according to claim 1 , wherein the cationic catalyst is at least one selected from the group consisting of a heteropolyacid, an isopolyacid, a perfluoroalkylsulfonic acid, and a derivatives thereof, and wherein the cationic catalyst is present in an amount of 10 to 1,000 ppm, based on the total mass of the all monomers.
Catalysts (Catalysts in general B01J) · CPC title
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