Reaction tube and method for producing hydrogen cyanide

Patent metadata

Field	Value
Publication number	US-2016145114-A1
Application number	US-201414896719-A
Country	US
Kind code	A1
Filing date	May 21, 2014
Priority date	Jun 11, 2013
Publication date	May 26, 2016
Grant date	—

Abstract

The reaction tube comprises a cylindrical ceramic tube and a catalyst comprising platinum applied to the inner surface of the tube, wherein the reaction tube has fins on the inner surface which run in the longitudinal direction of the tube, extend into the interior space of the reaction tube and are coated with catalyst. The reaction tube is suitable for preparing hydrogen cyanide by reacting ammonia and at least one aliphatic hydrocarbon having 1 to 4 carbon atoms at a temperature of 1000 to 1400° C.

First claim

1 - 10 . (canceled)

11 . A reaction tube for preparing hydrogen cyanide comprising a cylindrical ceramic tube and a catalyst comprising platinum applied to the inner surface of the tube, wherein the reaction tube has fins on the inner surface which run in the longitudinal direction of the tube, extend into the interior space of the reaction tube and are coated with catalyst.

12 . The reaction tube of claim 11 , wherein the reaction tube has 2 to 6 fins.

13 . The reaction tube of claim 11 , wherein the reaction tube has 3 or 4 fins.

14 . The reaction tube of claim 11 , wherein the fins extend into the interior space of the reaction tube by more than 0.1 times the inner diameter of the tube.

15 . The reaction tube of claim 11 , wherein the fins abut one another in the centre of the reaction tube and divide the interior space of the reaction tube into a plurality of chambers separated from one another.

16 . The reaction tube of claim 11 , wherein the fins have a mean thickness which is 0.25 to 2.5 times the mean thickness of the wall of the reaction tube.

17 . The reaction tube of claim 11 , wherein the thickness of the fins decreases with increasing distance from the inner surface of the reaction tube.

18 . The reaction tube of claim 11 , wherein the reaction tube and the fins are composed of gas-tight sintered aluminium oxide or silicon carbide.

19 . A method for preparing hydrogen cyanide by reacting ammonia and at least one aliphatic hydrocarbon having 1 to 4 carbon atoms in the presence of a catalyst comprising platinum at a temperature of 1000 to 1400° C., wherein:
a) the reaction is carried out in at least one reaction tube comprising a cylindrical ceramic tube and a catalyst comprising platinum applied to the inner surface of the tube; and
b) the reaction tube has fins on the inner surface which run in the longitudinal direction of the tube, extend into the interior space of the reaction tube and are coated with catalyst.

20 . The method of claim 19 , wherein the hydrocarbons are composed of at least 90 vol % of methane.

21 . The method of claim 19 , wherein the reaction tube has 2 to 6 fins.

22 . The method of claim 19 , wherein the reaction tube has 3 or 4 fins.

23 . The method of claim 19 , wherein said fins extend into the interior space of the reaction tube by more than 0.1 times the inner diameter of the tube.

24 . The method of claim 19 , wherein said fins abut one another in the centre of the reaction tube and divide the interior space of the reaction tube into a plurality of chambers separated from one another.

25 . The method of claim 24 , wherein the hydrocarbons are composed of at least 90 vol % of methane.

26 . The method of claim 19 , wherein said fins have a mean thickness which is 0.25 to 2.5 times the mean thickness of the wall of the reaction tube.

27 . The method of claim 19 , wherein the thickness of the fins decreases with increasing distance from the inner surface of the reaction tube.

28 . The method of claim 19 , wherein the reaction tube and the fins are composed of gas-tight sintered aluminium oxide or silicon carbide.

29 . The method of claim 27 , wherein the hydrocarbons are composed of at least 90 vol % of methane.

30 . The method of claim 19 , wherein:
a) the reaction tube has 2 to 6 fins. b) the fins extend into the interior space of the reaction tube by more than 0.1 times the inner diameter of the tube. c) the fins abut one another in the centre of the reaction tube and divide the interior space of the reaction tube into a plurality of chambers separated from one another; and d) the hydrocarbons are composed of at least 90 vol % of methane;

Assignees

• Glöckler Bernd
• Steffan Martin
• Steurenthaler Martin
• Müller Thomas
• Krill Steffen
• Körfer Martin
• Evonik Degussa Gmbh

Inventors

• Glockler Bernd
• Steffan Martin
• Steurenthaler Martin
• Müller Thomas
• Rigot Nicolas
• Krill Steffen
• Körfer Martin

Classifications

• B01J2219/00777

  horizontal · CPC title

• C01C3/0229 Primary

  from hydrocarbons and ammonia in the absence of oxygen, e.g. HMA-process · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• B01J19/2415

  Tubular reactors · CPC title

• B01J19/006

  Baffles · CPC title