Method for producing high-performing and electrically stable semi-conductive metal oxide layers, layers produced according to the method and use thereof
US-2015053966-A1 · Feb 26, 2015 · US
US2016137671A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016137671-A1 |
| Application number | US-201414900890-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jun 6, 2014 |
| Priority date | Jun 25, 2013 |
| Publication date | May 19, 2016 |
| Grant date | — |
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The present invention relates to metal oxide precursors comprising i) at least one metal atom selected from the group consisting of In, Ga, Zn and Sn, ii) at least one non-photocrosslinkable ligand and iii) at least one photocrosslinkable ligand, to liquid coating compositions comprising the precursors, and to their use.
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1 . Metal oxide precursor comprising i) at least one metal atom selected from the group consisting of In, Ga, Zn and Sn, ii) at least one non-photocrosslinkable ligand and iii) at least one photocrosslinkable ligand. 2 . Precursor according to claim 1 , characterized in that the at least one non-photocrosslinkable ligand is selected from the group of radicals consisting of oxo radicals, hydroxyl radicals, alkoxy radicals, nitrate radicals and halide radicals. 3 . Precursor according to claim 2 , characterized in that it comprises as at least one non-photocrosslinkable ligand at least one oxo radical and at least one alkoxy radical. 4 . Precursor according to claim 1 , characterized in that it has as non-photocrosslinkable ligands exclusively oxo radicals, alkoxy radicals and radicals selected from the group consisting of nitrate radicals and halide radicals. 5 . Precursor according to claim 1 , characterized in that the at least one photocrosslinkable ligand is selected from the group of radicals consisting of acrylate radicals, methacrylate radicals and allyl radicals. 6 . Precursor according to claim 1 , characterized in that the at least one atom is In. 7 . Precursor according to claim 1 , characterized in that it has the generic formula [In 6 (μ 6 —O)(μ 2 —OR) 12-x Cl 6 (R′) x ] 2− with R=C 1-10 alkyl, R′=acrylate or methacrylate and x=1-10. 8 . Precursor according to claim 1 , characterized in that it has the generic formula [In 6 (μ 6 —O)(μ 2 —OR) 12-x (NO 3 ) 6 (R′) x ] 2− with R=C 1-10 alkyl, R′=acrylate or methacrylate and x=1-10. 9 . Liquid coating composition comprising a. at least one precursor according to claim 1 and b. at least one solvent. 10 . Coating composition according to claim 9 , characterized in that it further comprises at least one photoinitiator. 11 . Coating composition according to claim 10 , characterized in that the photoinitiator is phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide. 12 . Use of a precursor according to claim 1 for producing structured metal-oxidic layers.
Radiation by light, e.g. photolysis or pyrolysis · CPC title
Metal oxides (C23C18/1212 takes precedence) · CPC title
Coating on selected surface areas, e.g. using masks · CPC title
with photosensitivity-increasing substances, e.g. photoinitiators · CPC title
Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur · CPC title
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