Use of peracetic acid/hydrogen peroxide and peroxide-reducing agents for treatment of drilling fluids, frac fluids, flowback water and disposal water

Patent metadata

Field	Value
Publication number	US-2016137535-A1
Application number	US-201615005567-A
Country	US
Kind code	A1
Filing date	Jan 25, 2016
Priority date	Mar 30, 2012
Publication date	May 19, 2016
Grant date	—

Abstract

Methods for the use of peracid compositions having decreased hydrogen peroxide concentration and a UV-blocking agent for various water treatments, including oil- and gas-field operations, and/or other aseptic treatments are disclosed. In numerous aspects, peracetic acid is the preferred peracid and is treated with a peroxide-reducing agent to substantially reduce the hydrogen peroxide content. Methods for using the treated peracid compositions for treatment of drilling fluids, frac fluids, flow back waters and disposal waters are also disclosed for improving water condition, reducing oxidizing damage associated with hydrogen peroxide and/or reducing bacteria infestation

First claim

What is claimed is:

1 . A method of treating waters comprising:
treating a percarboxylic acid composition with a peroxide-reducing enzyme to generate an antimicrobial composition; providing the antimicrobial composition to a water source in need of treatment to form a treated water source, wherein the antimicrobial composition and/or the treated water source further comprises a UV-blocking agent, and wherein the treated water source comprises (i) from up to about 1000 ppm catalase enzyme, (ii) from about 0 wt-% to about 1 wt-% hydrogen peroxide; (iii) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; and (iv) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid, wherein the hydrogen peroxide to peracid ratio is from about 0:100 to about 1:10 by wt; and directing the treated water source into a subterranean environment or disposing of the treated water source having a minimized environmental impact.

2 . The method of claim 1 , wherein the UV-blocking agent is a natural or synthetic dye, and wherein water source in need of treatment is selected from the group consisting of fresh water, pond water, sea water, produced water and combinations thereof.

3 . The method of claim 2 , wherein the UV-blocking agent is a cationic dye, and wherein the water source is at least 1 wt-% produced water and wherein antimicrobial efficacy of the antimicrobial composition on the treated water source is superior to antimicrobial effects of a water source that does not contain produced water.

4 . The method of claim 1 , wherein the treating of the percarboxylic acid composition with the peroxide-reducing agent to generate the antimicrobial composition is not a pretreatment step and occurs within the water source in need of treatment.

5 . The method of claim 1 , wherein the treated water reduces corrosion caused by hydrogen peroxide and reduces microbial-induced corrosion, and wherein the antimicrobial composition does not interfere with friction reducers, viscosity enhancers, other functional ingredients found in the water source, or combinations thereof.

6 . The method of claim 1 , wherein the percarboxylic acid stability is improved through the pretreatment step to minimize hydrogen peroxide concentration within the percarboxylic acid composition from about 0 wt-% to about 0.5 wt-% hydrogen peroxide, and wherein the concentration of the C 1 -C 22 carboxylic acid is from about 0.0001 wt-% to about 5.0 wt-%, and wherein the concentration of the C 1 -C 22 percarboxylic acid is from about 0.0001 wt-% to about 5.0 wt-%.

7 . The method of claim 1 , wherein the percarboxylic acid is peracetic acid, wherein the carboxylic acid is acetic acid, and wherein the UV-blocking agent is methylene blue.

8 . The method of claim 1 , wherein an acidulant is added to the water source in need of treatment before the addition of the antimicrobial composition to a water source.

9 . A method of treating a water source comprising:
adding a percarboxylic acid composition, a peroxide-reducing agent and a UV-blocking agent to a water source to form a treated water source having a hydrogen peroxide to peracid ratio from about 0:100 to about 1:10 by weight, wherein said antimicrobial composition in a use solution with said treated water source comprises (i) less than about 1000 ppm of a catalase enzyme, (ii) from about 0 wt-% to about 1 wt-% hydrogen peroxide; (iii) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; (iv) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid; and (v) from about 0.00001 wt-% to about 5 wt-% of said UV-blocking agent; and wherein the treated water source reduces corrosion caused by hydrogen peroxide and reduces microbial-induced corrosion, and wherein the antimicrobial composition does not interfere with friction reducers, viscosity enhancers, other functional ingredients found in the water source or combinations thereof.

10 . The method of claim 9 , wherein the UV-blocking agent is a natural or synthetic dye, and wherein the water source is fresh water, pond water, sea water, produced water or combinations thereof.

11 . The method of claim 10 , wherein use of said produced water in the water source further includes a first pretreatment of a percarboxylic acid antimicrobial composition with the peroxide-reducing agent, wherein the peroxide-reducing agent is a metal to provide the antimicrobial composition, wherein said composition provides superior antimicrobial efficacy in comparison to a water source that does not contain produced water.

12 . The method of claim 9 , further comprising a first pretreatment step wherein a percarboxylic acid composition is contacted by the peroxide-reducing agent to generate a pretreated antimicrobial composition.

13 . The method of claim 9 , further comprising the step of directing the treated water source into a subterranean environment or disposing of the treated water source having a minimized environmental impact.

14 . The method of claim 9 , wherein the percarboxylic acid stability is improved through the reduction of hydrogen peroxide concentration as a result of the addition of the peroxide-reducing agent.

15 . The method of claim 9 , wherein the percarboxylic acid is peracetic acid, wherein the carboxylic acid is acetic acid, and wherein the UV-blocking agent is methylene blue.

16 . The method of claim 9 , wherein the adding of the percarboxylic acid composition and the peroxide-reducing agent to the water source occurs on an at least every 5 day dosing cycle.

17 . The method of claim 9 , wherein an acidulant is added to the water source in need of treatment before the addition of the percarboxylic acid and peroxide-reducing agent to the water source.

18 . A method of treating a water source comprising:
a first step of either treating a percarboxylic acid composition with a peroxide-reducing agent to generate an antimicrobial composition or adding a percarboxylic acid and peroxide-reducing agent to a water source, wherein said peroxide-reducing agent is an enzyme; obtaining a water source in need of treatment; forming a treated water source, wherein the treated water source comprises (i) from up to about 1000 ppm peroxide-reducing agent, (ii) from about 0 wt-% to about 1 wt-% hydrogen peroxide; (iii) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; (iv) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid; and (v) from about 0.00001 wt-% to about 5 wt-% of a UV-blocking agent, wherein the hydrogen peroxide to peracid ratio is from about 0:100 to about 1:10 by wt; and directing the treated water source into a subterranean environment or disposing of the treated water source having a minimized environmental impact, wherein the treated water source reduces corrosion caused by hydrogen peroxide, reduces microbial-induced corrosion, and does not interfere with friction reducers, viscosity enhancers, or other functional ingredients found in the water source.

19 . The method of claim 18 , wherein the UV-blocking agent is a cationic dye and wherein the inorganic peroxide-reducing agent is a metal selected from the group consisting of iron, copper and manganese.

20 . The method of claim 18 , wherein the UV-blocking agent is methylene blue and wherein the inorganic peroxide-reducing agent is a halide.

Assignees

• Ecolab Usa Inc

Inventors

• Keasler Victor
• De Paula Renato
• Li Junzhong
• Mcsherry David D
• Herdt Brandon
• Staub Richard
• Ryther Robert J

Classifications

• C09K2208/32

  Anticorrosion additives · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• C09K8/605

  containing biocides · CPC title

• C02F2103/365

  from petrochemical industry (e.g. refineries) · CPC title

• Y02W10/37

  using solar energy · CPC title