Water-based anti-soiling agent, anti-soiling layer, layered body, and solar battery module

Patent metadata

Field	Value
Publication number	US-2016130447-A1
Application number	US-201615001258-A
Country	US
Kind code	A1
Filing date	Jan 20, 2016
Priority date	Jul 24, 2013
Publication date	May 12, 2016
Grant date	—

Abstract

An object of the invention is to provide a coating layer that can suppress the attachment of contaminants at the time of fine weather or drying, in addition to the ability to be cleaned by washing with water. The invention relates to a water-based anti-soiling agent including, in a mixed manner, a siloxane oligomer expressed by General Formula (1) below; a water component; an antistatic agent; and silica fine particles, in which a component exhibiting surface activity is 0.01% by mass or greater is included in the water-based anti-soiling agent, and
in General Formula (1), each of R 1 to R 3 independently represents an organic group having 1 to 6 carbon atoms, R 4 represents an alkyl group having 1 to 6 carbon atoms, and n represents an integer of 2 to 20.

First claim

What is claimed is:

1 . A water-based anti-soiling agent comprising, in a mixed manner:
a siloxane oligomer expressed by General Formula (1) below; a water component; an antistatic agent; and silica fine particles, wherein a component exhibiting surface activity is 0.01% by mass or greater is included in the water-based anti-soiling agent, and

wherein, in General Formula (1), each of R 1 to R 4 independently represents an organic group having 1 to 6 carbon atoms, and n represents an integer of 2 to 20.

2 . The water-based anti-soiling agent according to claim 1 , further comprising:
a catalyst that promotes condensation of a siloxane oligomer.

3 . The water-based anti-soiling agent according to claim 1 , further comprising:
a component exhibiting ionic surface activity.

4 . The water-based anti-soiling agent according to claim 1 , further comprising:
a component exhibiting nonionic surface activity.

5 . The water-based anti-soiling agent according to claim 3 ,
wherein a content of the component exhibiting ionic surface activity is 1.0% by mass or less with respect to a total mass of the water-based anti-soiling agent.

6 . The water-based anti-soiling agent according to claim 1 ,
wherein the antistatic agent includes metal oxide fine particles.

7 . The water-based anti-soiling agent according to claim 1 ,
wherein a ratio of carbon in a total solid content in the water-based anti-soiling agent is 3% by mass or less.

8 . The water-based anti-soiling agent according to claim 6 ,
wherein a primary particle diameter of metal oxide fine particles is 100 nm or less.

9 . The water-based anti-soiling agent according to claim 1 ,
wherein a content of an organic compound having a molecular weight of 1,100 or greater included in the water-based anti-soiling agent is 0.2% by mass or less.

10 . An anti-soiling coating layer that is formed by coating and drying the water-based anti-soiling agent according to claim 1 .

11 . The anti-soiling coating layer according to claim 10 ,
wherein a surface electrical resistance is 1×10 12 co/square or less.

12 . The anti-soiling coating layer according to 10,
wherein a water contact angle on a surface is 40° or less.

13 . The anti-soiling coating layer according to claim 10 ,
wherein an average integrating sphere transmittance in a wavelength of 300 nm to 1,200 nm is 95% or greater.

14 . A layered body obtained by laminating the anti-soiling coating layer according to claim 10 , as a glass layer.

15 . A solar battery module having a layered body according to claim 14 .

Assignees

• Fujifilm Corp

Inventors

• Kaneiwa Hideki

Classifications

• C09D5/1675 Primary

  Polyorganosiloxane-containing compositions · CPC title

• C08K3/36

  Silica · CPC title

• B32B2367/00

  Polyesters, e.g. PET, i.e. polyethylene terephthalate · CPC title

• B32B17/10018

  comprising only one glass sheet · CPC title

• C08G77/045

  containing less than 25 silicon atoms · CPC title