Crystallized polymer film and method for producing the same

Patent metadata

Field	Value
Publication number	US-2016130388-A1
Application number	US-201414896821-A
Country	US
Kind code	A1
Filing date	Jul 17, 2014
Priority date	Jul 19, 2013
Publication date	May 12, 2016
Grant date	—

Abstract

A crystallized polymer film including a polymer (A) that has a weight-average molecular weight of from 50,000 to 1,000,000 and a crystallization half time at the temperature at which the polymer crystallizes fastest in a range of from 180 seconds to 900 seconds; having a crystallinity of from 20% to 80% as obtained by a DSC method; and having a difference between a total haze and an internal haze of 0.8% or less in a case in which the total haze and the internal haze are measured at 25° C. in accordance with JIS-K7105.

First claim

1 . A crystallized polymer film comprising a polymer (A) that has a weight-average molecular weight of from 50,000 to 1,000,000 and a crystallization half time at the temperature at which the polymer crystallizes fastest in a range of from 180 seconds to 900 seconds,
having a crystallinity of from 20% to 80% as obtained by a DSC method, and having a difference between a total haze and an internal haze of 0.8% or less in a case in which the total haze and the internal haze are measured at 25° C. in accordance with JIS-K7105.

2 . The crystallized polymer film according to claim 1 , the film having a total haze of 40% or less.

3 . The crystallized polymer film according to claim 1 , the film having a ratio of the maximum tensile elastic modulus Emax of an tensile elastic modulus (TD) in the TD direction and an tensile elastic modulus (MD) in the MD direction to the minimum tensile elastic modulus Emin of from 1.30 to 2.50,
in a case in which the tensile elastic modulus (TD) and the tensile elastic modulus (MD) are measured in accordance with JIS-K-7127.

4 . The crystallized polymer film according to claim 1 , the film having an internal haze of 20% or less and a piezoelectric constant d 14 of 1 pC/N or more as measured at 25° C. using a stress-charge method.

5 . The crystallized polymer film according to claim 1 , the film having an internal haze of 1% or less.

6 . The crystallized polymer film according to claim 1 , wherein the polymer (A) is a polylactic acid-type polymer that has a main chain having a repeating unit represented by the following Formula (1):

7 . The crystallized polymer film according to claim 1 , wherein the polymer (A) has an optical purity of 95.00% ee or more.

8 . The crystallized polymer film according to claim 1 , the film comprising the polymer (A) in an amount of 80% by mass or more.

9 . The crystallized polymer film according to claim 1 , the film being obtained by contacting a principal plane of the film that includes the polymer (A) with a surface of a heating member that permits releasability of the film to heat the film.

10 . A method for producing the crystallized polymer film according to claim 1 , the method comprising:
a step of preparing a film that includes the polymer (A), and a crystallization step of heating the film at a temperature T (° C.) that satisfies the following Formula (a) by contacting a principal plane of the film with a surface of a heating member that permits releasability of the film to obtain the crystallized polymer film:
Tg+ 30< T<Tm− 20   Formula (a):

[wherein Tg represents the glass transition temperature (° C.) of the polymer (A) as measured by a DSC method, and Tm represents the melting point of the polymer (A)].

11 . The method for producing the crystallized polymer film according to claim 10 , wherein the heating member has a surface layer that comprises a fluororesin and that is in contact with the principal plane.

12 . The method for producing a crystallized polymer film according to claim 10 , wherein the surface of the heating member has a maximum height Rz of 0.20 μm or more.

13 . The method for producing the crystallized polymer film according to claim 10 , wherein the surface of the heating member has an arithmetic mean roughness Ra of 0.05 μm or more.

14 . The method for producing the crystallized polymer film according to claim 10 , wherein the preparation step is to prepare a film that includes the polymer (A) and that is stretched mainly in a uniaxial direction.

15 . The method for producing the crystallized polymer film according to claim 10 , wherein the preparation step is to prepare a pre-crystallized film that includes the polymer (A).

16 . The method for producing the crystallized polymer film according to claim 10 , wherein the preparation step comprises a step of obtaining a pre-crystallized film that includes the polymer (A) and a step of stretching the pre-crystallized film mainly in a uniaxial direction.

Assignees

• Mitsui Chemicals Inc

Inventors

• Nishikawa Shigeo
• Yoshida Mitsunobo

Classifications

• C08J2367/04

  Polyesters derived from hydroxy carboxylic acids, e.g. lactones (C08J2367/06 takes precedence) · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08G63/08 Primary

  Lactones or lactides · CPC title