System and method for conventional particle rounding utilizing continuous emulsion-aggregation (ea) technology

Patent metadata

Field	Value
Publication number	US-2016124331-A1
Application number	US-201414534058-A
Country	US
Kind code	A1
Filing date	Nov 5, 2014
Priority date	Nov 5, 2014
Publication date	May 5, 2016
Grant date	—

Abstract

In an exemplary embodiment of the invention, a continuous process for rounding conventional toner particles includes forming a conventional toner particle slurry by mixing a dispersant and/or a liquid with dry toner particles, heating the conventional toner particle slurry to a first temperature beyond its glass transition temperature to form a coalesced toner particle slurry, quenching the coalesced toner particle slurry to a second temperature below the glass transition temperature after a residence time has elapsed, and recovering the quenched particle slurry at an outlet wherein the circularity of the conventional toner particles in the quenched toner particle slurry is from approximately 0.940 to 0.999 and the time frame for the heating, quenching and recovering steps is less than 20 minutes. An apparatus for practicing the novel continuous coalescence of toner particles, includes an inlet passage, a first heat exchanger coupled to the inlet passage, a residence time coil coupled to the first heat exchanger, a cooling device coupled to the residence time coil; and an outlet passage coupled to the cooling device.

First claim

1 . A continuous process for rounding conventional toner particles comprising;
forming a conventional toner particle slurry by mixing a dispersant and/or a liquid with dry toner particles; heating, in a first heat exchanger, the conventional toner particle slurry to a first temperature beyond its glass transition temperature to form a coalesced toner particle slurry; quenching the coalesced toner particle slurry to a second temperature below the glass transition temperature after a residence time; and recovering the quenched particle slurry at an outlet, wherein the circularity of the conventional toner particles in the quenched toner particle slurry is from approximately 0.940 to 0.999 and the time frame for the heating, quenching and recovering steps is less than 20 minutes.

2 . The continuous process of claim 1 , wherein an internal structure of the conventional toner particles is minimally disturbed by the continuous process for rounding conventional toner particles.

3 . The process of claim 1 , wherein the toner particle slurry has a starting temperature of from ambient to about 65° C. prior to entering the first heat exchanger.

4 . The process of claim 1 , wherein the toner particle slurry is preheated and has a starting temperature from about 5 degrees greater than Tg to about 30 degrees greater than Tg prior to entering the first heat exchanger:

5 . The process of claim 1 , wherein the first temperature is from about 70 to about 110° C.

6 . The process of claim 1 , wherein the quenching occurs in a coil, a second heat exchanger, or in a cooled receiving tank.

7 . The process of claim 1 , wherein the pressure of the first heat exchanger is from about 1% to about 20% greater than the vapor pressure of water at the first temperature.

8 . The process of claim 1 , wherein the heated toner particle slurry exits the first heat exchanger and coalesces in a residence time reactor to form the coalesced particle slurry, before being quenched.

9 . The process of claim 1 , wherein the toner particle slurry is drawn into the first heat exchanger by a pump at the outlet.

10 . The process of claim 1 , wherein the toner particle slurry has a pH of about 6 to about 10 prior to entering the first heat exchanger.

11 . The process of claim 1 , further comprising lowering the pH of the toner particle slurry prior to flowing the toner particle slurry through the residence time coil.

12 . The process of claim 11 , wherein the pH of the toner particle slurry is lowered/raised to a value from about 5 to 8 prior to entering the first heat exchanger.

13 . The process of claim 11 , wherein the pH of the toner particle slurry is lowed by addition of a buffer solution or an acidic solution.

14 . The process of claim 11 , wherein the toner particle is a magnetic ink character recognition toner particle.

15 . The process of claim 1 , wherein the residence time is from about 10 seconds to about 15 minutes.

16 . The process of claim 1 , wherein heat energy captured prior to quenching the coalesced toner slurry in the second heat exchanger is transferred to the toner particle slurry prior to coalescence in later flows of the toner particle slurry.

17 . An apparatus for continuous coalescence of toner particles, comprising:
an inlet passage; a first heat exchanger coupled to the inlet passage; a residence time coil coupled to the first heat exchanger; a cooling device coupled to the residence time coil; and an outlet passage coupled to the cooling device, wherein a toner particle slurry is transferred from the inlet passage to the first heat exchanger and to the residence time coil to become a coalesced toner particle slurry and the coalesced toner particle slurry is transferred to the cooling device to become the quenched toner particle slurry and then transferred to the outlet passage, wherein the circularity of the conventional toner particles in the quenched toner particle slurry is from approximately 0.940 to 0.999 and the time frame for the heating, quenching and recovering steps is less than 20 minutes.

18 . The apparatus of claim 17 , wherein the cooling device is a second heat exchanger or a cooled receiving tank.

19 . The apparatus of claim 17 , further comprising a recycle loop wherein heat energy is captured between the residence time coil and the cooling device and the heat energy is transferred to fluid upstream of the residence time coil.

20 . The apparatus of claim 19 , the recycle loop comprising a third heat exchanger located between the residence time coil and the cooling device, and a fourth heat exchanger located upstream of the first heat exchanger, wherein a heat transfer fluid flows in a loop between the third heat exchanger and the fourth heat exchanger.

Assignees

• Xerox Corp

Inventors

• Malachowski Steven M
• Young Eric Joseph
• Jan Linda
• Godshall Eric David
• Marion Brian J
• Cheng Chieh-Min

Classifications

• G03G9/0815

  Post-treatment · CPC title

• G03G9/0804

  whereby the components are brought together in a liquid dispersing medium · CPC title

• G03G9/081 Primary

  by mixing the toner components in a liquefied state; melt kneading; reactive mixing · CPC title