Anode material for lithium ion battery and lithium ion battery including the same

Patent metadata

Field	Value
Publication number	US-2016118652-A1
Application number	US-201514923450-A
Country	US
Kind code	A1
Filing date	Oct 27, 2015
Priority date	Oct 27, 2014
Publication date	Apr 28, 2016
Grant date	—

Abstract

Provided is an anode material for a lithium ion battery including an anode active material, an organic modified layer, and a lithium-containing inorganic layer. The organic modified layer is disposed on the anode active material. The lithium-containing inorganic layer is disposed on the organic modified layer. Moreover, based on 100 parts by weight of the anode active material, the organic modified layer accounts for about 0.1 to 5 parts by weight, and the lithium-containing inorganic layer accounts for about 0.1 to 20 parts by weight. A lithium ion battery including the anode material is further provided.

First claim

What is claimed is:

1 . An anode material for a lithium ion battery, comprising:
an anode active material; an organic modified layer disposed on the anode active material; and a lithium-containing inorganic layer disposed on the organic modified layer, wherein based on 100 parts by weight of the anode active material, the organic modified layer accounts for 0.1 to 5 parts by weight, and the lithium-containing inorganic layer accounts for 0.1 to 20 parts by weight.

2 . The anode material of claim 1 , wherein chemical bonding occurs between the anode active material and the organic modified layer.

3 . The anode material of claim 1 , wherein chemical bonding does not occur between the anode active material and the organic modified layer.

4 . The anode material of claim 1 , wherein the organic modified layer comprises maleimide, furan, thiophene, pyrrole, alkyne, alkene, cycloalkene, a derivative thereof, or a combination thereof.

5 . The anode material of claim 1 , wherein the organic modified layer comprises N,N′-(4,4′-diphenylmethane)bismaleimide, N-phenyl maleimide, N,N′,N″-(4,4′,4″-phenylmethane)maleimide, N,N′-(4,4′-diphenyl ether)bismaleimide, or a combination thereof.

6 . The anode material of claim 1 , wherein the organic modified layer comprises polymaleimide having a weight-average molecular weight of 100,000 to 1,000,000 or a derivative thereof.

7 . The anode material of claim 1 , wherein a thickness of the organic modified layer is from 15 nm to 20 nm.

8 . The anode material of claim 1 , wherein the lithium-containing inorganic layer comprises at least one of lithium, lithium fluoride (LiF), lithium phosphate (Li 3 PO 4 ), lithium disilicate (Li 2 Si 2 O 5 ), lithium metasilicate (Li 2 SiO 3 ), lithium orthosilicate (Li 4 SiO 4 ), lithium oxosilicate (Li 8 SiO 6 ), lithium oxide (Li 2 O), and lithium carbonate (Li 2 CO 3 ).

9 . The anode material of claim 1 , wherein the anode active material comprises graphite, graphene, hard carbon, soft carbon, single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), carbon fiber, carbon alloy, carbon metal oxide, a Si/C composite material, mesocarbon micro beads (MCMB), mesophase graphite, mesoporous graphite, or a combination thereof.

10 . The anode material of claim 1 , wherein when the anode active material consists mainly of a carbon material, based on 100 parts by weight of the anode active material, the organic modified layer accounts for 0.5 to 1 parts by weight, and the lithium-containing inorganic layer accounts for 3 to 6 parts by weight.

11 . The anode material of claim 1 , wherein when the anode active material consists mainly of a carbon material and a silicon material, based on 100 parts by weight of the anode active material, the organic modified layer accounts for 1 to 5 parts by weight, and the lithium-containing inorganic layer accounts for 15 to 20 parts by weight.

12 . A lithium ion battery, comprising the anode material of claim 1 .

13 . An anode material for a lithium ion battery, comprising:
a core consisting mainly of an anode active material; a first shell layer covering the core and consisting mainly of an organic material; and a second shell layer disposed on the first shell layer and comprising at least one of lithium, lithium fluoride (LiF), lithium phosphate (Li 3 PO 4 ), lithium disilicate (Li 2 Si 2 O 5 ), lithium metasilicate (Li 2 SiO 3 ), lithium orthosilicate (Li 4 SiO 4 ), lithium oxosilicate (Li 8 SiO 6 ), lithium oxide (Li 2 O), and lithium carbonate (Li 2 CO 3 ).

14 . The anode material of claim 13 , wherein chemical bonding occurs between the core and the first shell layer.

15 . The anode material of claim 13 , wherein chemical bonding does not occur between the core and the first shell layer.

16 . The anode material of claim 13 , wherein based on 100 parts by weight of the core, the first shell layer accounts for 0.1 to 5 parts by weight and the second shell layer accounts for 0.1 to 20 parts by weight.

17 . The anode material of claim 13 , wherein the organic material comprises maleimide, furan, thiophene, pyrrole, alkyne, alkene, cycloalkene, or a combination thereof.

18 . The anode material of claim 13 , wherein the organic material comprises polymaleimide having a weight-average molecular weight of 100,000 to 1,000,000 or a derivative thereof.

19 . The anode material of claim 13 , wherein a thickness of the first shell layer is from 15 nm to 20 nm.

20 . The anode material of claim 13 , wherein the core comprises graphite, graphene, hard carbon, soft carbon, single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), carbon fiber, carbon alloy, carbon metal oxide, a Si/C composite material, mesocarbon micro beads (MCMB), mesophase graphite, mesoporous graphite, or a combination thereof.

Assignees

• Ind Tech Res Inst

Inventors

• Wu Wei-Hsin
• Lin Yueh-Wei
• Fang Chia-Chen
• Lee Jen-Jeh

Classifications

• H01M4/582

  Halogenides · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/366 Primary

  as layered products · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title