Graphene dispersions

Patent metadata

Field	Value
Publication number	US-2016115293-A1
Application number	US-201414890856-A
Country	US
Kind code	A1
Filing date	May 14, 2014
Priority date	May 14, 2013
Publication date	Apr 28, 2016
Grant date	—

Abstract

Method of making a composition comprising graphene sheets and at least one solvent, comprising dispersing a mixture of graphene sheets and graphite particles in a solvent, wherein the graphite particles have more than about 50 layers, separating the graphene sheets and the graphite particles to obtain a dispersion of graphene sheets that contains no more than 25% of graphite particles having more than about 50 layers, based on the total number of graphite particles and graphene sheets, and flocculating the dispersion of graphene sheets. The flocculated dispersion can be added to a polymer matrix to make a composite. The composite can be formed into articles.

First claim

1 . A method of making a composition comprising graphene sheets and at least one solvent, comprising dispersing a mixture of graphene sheets and graphite particles in a solvent, wherein the graphite particles have more than about 50 layers, separating the graphene sheets and the graphite particles to obtain a dispersion of graphene sheets that contains no more than 25% of graphite particles having more than about 50 layers, based on the total number of graphite particles and graphene sheets, and flocculating the dispersion of graphene sheets.

2 . The method of claim 1 , further comprising the step of concentrating the flocculated dispersion of graphene sheets.

3 . The method of claim 1 , wherein the graphene sheets have a surface area of at least about 200 m 2 /g.

4 . The method of claim 1 , wherein the graphite sheets have a surface area of at least about 300 m 2 /g.

5 . The method of claim 1 , wherein the dispersion of graphene sheets contains no more than about 20% of particles having more than about 10 layers.

6 . The method of claim 1 , wherein the dispersion of graphene sheets contains no more than about 10% of particles having more than about 10 layers.

7 . The method of claim 1 , wherein the dispersion of graphene sheets contains no more than about 10% of particles having more than about 5 layers.

8 . The method of claim 1 , wherein the dispersion of graphene sheets contains no more than about 5% of particles having more than about 5 layers

9 . A method of making a polymer composite material, comprising dispersing a mixture of graphene sheets and graphite particles into a solvent, wherein the graphite particles have more than about 50 layers, separating the graphene sheets and the graphite particles to obtain a dispersion of graphene sheets that contains no more than 25% of graphite particles having more than about 50 layers, based on the total number of graphite particles and graphene sheets, separating the graphene sheets and the graphite particles to obtain a dispersion of graphene sheets that contains no more than about 25% of particles having more than about 50 layers, based on the total number of graphite particles and graphene sheets; flocculating the dispersion of graphene sheets; and adding the flocculated dispersion to a polymer matrix.

10 . The method of claim 9 , wherein the flocculated dispersion is concentrated before it is added to the polymer matrix.

11 . The method of claim 9 , wherein the polymer matrix comprises one or more polymers selected from the groups consisting of polyesters, polyamides, polyethylenes, rayons, and aramids.

12 . The method of claim 9 , wherein the graphene sheets have a surface area of at least about 200 m 2 /g.

13 . The method of claim 9 , wherein the graphene sheets have a surface area of at least about 300 m 2 /g.

14 . The method of claim 9 , wherein the dispersion of graphene sheets contains no more than about 20% of particles having more than about 10 layers.

15 . The method of claim 9 , wherein the dispersion of graphene sheets contains no more than about 10% of particles having more than about 5 layers

16 . A method of making a polymeric article, comprising forming a polymer composite material by dispersing a mixture of graphene sheets and graphite particles into a solvent, wherein the graphite particles have more than about 50 layers, separating the graphene sheets and the graphite particles to obtain a dispersion of graphene sheets that contains no more than 25% of graphite particles having more than about 50 layers, based on the total number of graphite particles and graphene sheets, separating the graphene sheets and the graphite particles to obtain a dispersion of graphene sheets that contains no more than about 25% of particles having more than about 50 layers, based on the total number of graphite particles and graphene sheets; flocculating the dispersion of graphene sheets; adding the flocculated dispersion to a polymer matrix to form the polymer composite material; and forming the polymer composite material into an article.

17 . The method of claim 16 , wherein the polymer matrix comprises one or more polymers selected from the groups consisting of polyesters, polyamides, polyethylenes, rayons, and aramids.

18 . The method of claim 16 , wherein the article is a molded article.

19 . The method of claim 16 , wherein the article is formed by spinning.

20 . The method of claim 16 , wherein the article is a at least one fiber.

21 . The method of claim 16 , wherein the dispersion of graphene sheets contains no more than about 10% of particles having more than about 5 layers

Assignees

• Vorbeck Materials Corp
• Univ Princeton
• Kordsa Global

Inventors

• Aksay Ilhan
• Korkut Sibel
• Kaczmarczyk Jeffrey
• Gurdag Sezen
• Korkmaz Deniz

Classifications

• C08K3/04 Primary

  Carbon · CPC title

• C09D7/1216

  Chemistry & Metallurgy · mapped topic

• C01B2204/32

  Size or surface area · CPC title

• C01B2204/20

  Graphene characterized by its properties · CPC title

• C01B2204/04

  Specific amount of layers or specific thickness · CPC title