Mesoporous Structure Solar Cell with Siloxane Barrier
US-2015380170-A1 · Dec 31, 2015 · US
US2016104847A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016104847-A1 |
| Application number | US-201514838874-A |
| Country | US |
| Kind code | A1 |
| Filing date | Aug 28, 2015 |
| Priority date | Oct 13, 2014 |
| Publication date | Apr 14, 2016 |
| Grant date | — |
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This invention discloses a novel multicomponent system or a single compound that is capable of performing triplet-triplet annihilation up conversion process. (TTA-UC) A solution or solid film that comprises this TTA-UC system or compound is provided. This system or compound can be used in an optical or optoelectronic device.
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1 . A formulation comprising a mixture of: a sensitizer; an acceptor; and an emitter; wherein the acceptor has a first triplet energy lower than a first triplet energy of the sensitizer; wherein the emitter has a first singlet energy lower than a first singlet energy of the acceptor; and wherein the sensitizer, the acceptor, and the emitter are jointly capable of performing triplet-triplet annihilation upconversion of light incident on the formulation to emit a luminescent radiation comprising a radiation component from the first singlet energy of the emitter. 2 . The formulation of claim 1 , wherein the emitter has a first triplet energy higher than the first triplet energy of the acceptor 3 . The formulation of claim 1 , wherein the emitter has the first triplet energy higher than the first triplet energy of the sensitizer; and wherein the emitter has the first singlet energy higher than the first singlet energy of the sensitizer. 4 . The formulation of claim 1 , wherein the sensitizer is selected from the group consisting of: an iridium complex, an osmium complex, a platinum complex, a palladium complex, a rhenium complex, a ruthenium complex, and a gold complex. 5 . The formulation of claim 1 , wherein the sensitizer is selected from the group consisting of: 6 . The formulation of claim 1 , wherein the acceptor comprises a fused aromatic group. 7 . The formulation of claim 1 , wherein the acceptor comprises a group selected from the group consisting of: naphthalene, anthracene, tetracene, pyrene, chrysene, perylene, and combinations thereof. 8 . The formulation of claim 1 , wherein the acceptor is selected from the group consisting of: 9 . The formulation of claim 1 , wherein the emitter comprises a group selected from the group consisting of: fluoranthene, pyrene, triarylamine, and combinations thereof. 10 . The formulation of claim 1 , wherein the emitter is selected from the group consisting of:
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