Process for producing pyridazinone compound and production intermediates thereof
US-2015376138-A1 · Dec 31, 2015 · US
US2016102044A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016102044-A1 |
| Application number | US-201414889978-A |
| Country | US |
| Kind code | A1 |
| Filing date | Apr 18, 2014 |
| Priority date | May 8, 2013 |
| Publication date | Apr 14, 2016 |
| Grant date | — |
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A method for producing an ester compound including reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtain the ester compound, wherein the palladium catalyst comprises a palladium complex having a bipyridyl as a ligand.
Opening claim text (preview).
1 . A method for producing an ester compound, comprising: reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtain the ester compound, wherein the palladium catalyst comprises a palladium complex having a bipyridyl as a ligand. 2 . The method for producing an ester compound according to claim 1 , wherein oxygen is used as the oxidizing agent. 3 . The method for producing an ester compound according to claim 2 , wherein a chlorine-containing compound, a copper compound other than a chloride, and a manganese compound other than a chloride are used in combination with the oxidizing agent. 4 . The method for producing an ester compound according to claim 2 , wherein manganese chloride, copper acetate, and manganese acetate are used in combination with the oxidizing agent.
Palladium · CPC title
Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues · CPC title
containing "free" spiro atoms · CPC title
with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine · CPC title
by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of [IMAGE cpc-sch-C07C-0963.gif] groups between different molecules · CPC title
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