Methods and systems for upgrading mixed pyrolysis oil to light aromatics over mixed metal oxide catalysts
US-2024010934-A1 · Jan 11, 2024 · US
US2016101403A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016101403-A1 |
| Application number | US-201514973443-A |
| Country | US |
| Kind code | A1 |
| Filing date | Dec 17, 2015 |
| Priority date | Sep 29, 2014 |
| Publication date | Apr 14, 2016 |
| Grant date | — |
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A lean MEG stream having a first pH level is contacted with a CO 2 -rich gas stream to yield a lean MEG product having a second different and lower pH level preferably in a range of 6.5 to 7.0. The system and method can be readily incorporated into a slipstream MEG recovery package, with a source of the lean MEG stream being a MEG regeneration section of the package. The CO 2 -rich gas could be a vented CO 2 stream from the MEG reclamation section of the package. Unlike hydrochloric and acetic acid overdosing, CO 2 overdosing of the lean MEG stream does not lead to rapid acidification of the lean MEG product to be stored or injected.
Opening claim text (preview).
What is claimed: 1 . A system for adjusting a pH level of a MEG stream, the system comprising: a vessel having an inlet to receive a MEG stream and ported to receive a CO 2 -rich gas, the MEG stream and CO 2 -rich gas coming into contact with one another within the vessel. 2 . A system according to claim 1 , the MEG stream having a first pH level when entering the vessel and, after coming into contact with the CO 2 -rich gas, having a second different pH level when exiting the vessel. 3 . A system according to claim 2 wherein an amount of the CO 2 -rich gas is at least equal to a stoichiometric quantity effective for achieving a desired second lower pH level. 4 . A system according to claim 3 wherein the amount of CO 2 -rich gas exceeds the stoichiometric quantity. 5 . A system according to claim 2 wherein the second different pH level is at least 6. 6 . A system according to claim 2 wherein the second different pH level is 7. 7 . A system according to claim 1 further comprising a source of the CO 2 -rich gas is a vented CO 2 stream from a MEG reclamation unit. 8 . A system according to claim 1 wherein the MEG stream is mixed with a second MEG stream having a different pH level than a pH level of the MEG stream. 9 . A system according to claim 8 further comprising a source of the second MEG stream is a MEG reclamation unit. 10 . A system according to claim 8 wherein the second MEG stream has a pH level of 7. 11 . A system according to claim 1 further comprising a source of the MEG stream is a MEG regeneration unit. 12 . A system according to claim 11 wherein a portion of the MEG stream exiting the regeneration unit is routed to a reclamation unit.
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